多孔Ni-Cu-Ti电极的制备及析氢性能

doi:10.11896/cldb.21100074

材料导报

2023, Vol. 37

Issue (13): 21100074-9 https://doi.org/10.11896/cldb.21100074

金属与金属基复合材料

多孔Ni-Cu-Ti电极的制备及析氢性能

吴靓^1,2,3, 周子坤^1,2,3, 姬丽^1,2,3, 肖逸锋^1,2,3,*, 张乾坤^1,2,3

1 湘潭大学机械工程学院,湖南湘潭 411105
2 湘潭大学焊接机器人及应用技术湖南省重点实验室,湖南湘潭 411105
3 湘潭大学复杂轨迹加工工艺及装备教育部工程研究中心,湖南湘潭 411105

Preparation and Hydrogen Evolution Performance of Porous Ni-Cu-Ti Electrode

WU Liang^1,2,3, ZHOU Zikun^1,2,3, JI Li^1,2,3, XIAO Yifeng^1,2,3,*, ZHANG Qiankun^1,2,3

1 School of Mechanical Engineering, Xiangtan University, Xiangtan 411105, Hunan, China
2 Hunan Provincial Key Laboratory of Welding Robot and Application Technology, Xiangtan University, Xiangtan 411105, Hunan, China
3 Complex Track Processing Technology and Equipment Engineering Research Center of the Ministry of Education, Xiangtan University, Xiangtan 411105, Hunan, China

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摘要通过电解水生产氢气是一种理想的方法,而电极材料的催化活性决定了电解水的效率。该研究通过粉末冶金方法制备了多孔Ni-Cu-Ti电极,利用扫描电子显微镜(SEM)、X射线衍射(XRD)等技术对多孔Ni-Cu-Ti电极的微观结构和物相组成进行表征,并通过阴极极化、交流阻抗谱和循环伏安测试技术对电极进行了电化学表征。结果表明,在烧结温度为1 000 ℃、质量比为5.5∶3.5∶1时,多孔Ni-Cu-Ti电极表现出最佳的析氢性能,在1 mol/L的KOH中仅需要79 mV (vs.RHE) 的过电位就能实现10 mA·cm^-2的电流密度,其Tafel斜率为117.07 mV· dec^-1。

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关键词: 多孔材料 Ni-Cu-Ti合金电极粉末冶金析氢反应

Abstract: Hydrogen production by electrolysis of water is an ideal method, and the catalytic activity of the electrode material determines the efficiency of water electrolysis. In this study, a porous Ni-Cu-Ti electrode was prepared by the powder metallurgy method. The microstructure and phase composition of the porous Ni-Cu-Ti electrodes were characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD) techniques. Meanwhile, electrochemical characterization of the electrodes were measured by cathodic polarization, electrochemical impedance spectroscopy, and cyclic voltammetry. The results show that when the sintering temperature was 1 000 ℃ and the mass ratio was 5.5∶3.5∶1, the porous Ni-Cu-Ti electrode exhibited the best hydrogen evolution performance. It only requires an overpotential of 79 mV (vs.RHE) to achieve a current density of 10 mA·cm^-2 in 1 mol/L KOH, and its Tafel slope is 117.07 mV·dec^-1.

Key words: porous material Ni-Cu-Ti alloy electrode powder metallurgy hydrogen evolution reaction

发布日期: 2023-07-10

ZTFLH:

TG146

基金资助: 湖南省自然科学基金(2018JJ3505)

通讯作者: *肖逸锋,湘潭大学机械工程学院材料工程系教授、博士研究生导师。1999年湘潭大学焊接工艺及设备专业本科毕业,2003年湘潭大学材料加工工程硕士毕业后到湘潭大学工作至今,2008年中南大学材料科学与工程博士毕业。目前主要从事粉末冶金新材料、特种焊接材料与工艺和表面改性技术的研究。在国内外期刊发表论文50余篇,授权发明专利20余项,主持国家及省部级课题多项。xiaoyifeng@xtu.edu.cn

作者简介: 吴靓,湘潭大学机械工程学院材料工程系副教授、硕士研究生导师。2008年中南大学粉体材料科学与工程专业本科毕业,2011年中南大学材料学硕士毕业,2014年中南大学材料学博士毕业后到湘潭大学工作至今。目前主要从事粉末冶金技术、多孔材料的制备及应用的研究。在国内外期刊发表论文30余篇,主持国家及省部级课题多项。

引用本文:

吴靓, 周子坤, 姬丽, 肖逸锋, 张乾坤. 多孔Ni-Cu-Ti电极的制备及析氢性能[J]. 材料导报, 2023, 37(13): 21100074-9.
WU Liang, ZHOU Zikun, JI Li, XIAO Yifeng, ZHANG Qiankun. Preparation and Hydrogen Evolution Performance of Porous Ni-Cu-Ti Electrode. Materials Reports, 2023, 37(13): 21100074-9.

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http://www.mater-rep.com/CN/10.11896/cldb.21100074 或 http://www.mater-rep.com/CN/Y2023/V37/I13/21100074

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