Research Progress of Stimulated Responsive Wettability on Shape-memory Polymer Surfaces
WANG Mian1, ZHANG Quanchao1,*, AO Haiyong1, WAN Yizao1,2
1 Jiangxi Key Laboratory of Nanobiomaterials, Institute of Advanced Materials,East China Jiaotong University, Nanchang 330013, China 2 School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
Abstract: The wettability is an important property of a solid material surface, which can affect various functions of the material. Now, the surfaces with fixed wettability cannot meet the complex and changeable application environment, and thus developing the surfaces with responsive wettability is highly desired. In this context, the stimulated responsive wettability on shape-memory polymer (SMP) surface, which exhibits the advantages of simplicity, convenience and controllability, is potentially used in the fields of droplet directional transmission, bubble collection, and oil-water separation. It is well known that the microstructure of the SMP surface and the shape-memory programming method are the main approaches to control the responsive wettability of the SMP surface. Although many publications have focused on the issues, the systematic and in-depth discussion about how the above two aspects actuated the responsive wettability of SMP surface is still lacking. In this paper, from the viewpoints of the different microstructures on SMP surface (micropillar array, porous structure, wrinkle structure, and binary hybrid structure) and different programming methods (vertical hot pressing, inclined hot pressing, selective hot pressing, and hot stretching), we summarize the latest progress for the stimulated responsive wettability on SMP surface; in which, the influences of programming methods and shape memory recovery parameters on the stimulated responsive wettability of SMP surface are highlighted. Finally, the challenges and development trends of the current SMP based responsive wettability surface are proposed. This paper reviews the latest progress of the influence of microstructure and programming methods on the responsive wettability of SMP surface, which is expected to help researchers in the material field deepen their understanding on SMP based responsive wettability surfaces, andto provide technical and theoretical guidance for developing the smart responsive wettability surface.
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