形状记忆聚合物表面响应性润湿性研究进展

doi:10.11896/cldb.20090319

材料导报

2022, Vol. 36

Issue (21): 20090319-9 https://doi.org/10.11896/cldb.20090319

高分子与聚合物基复合材料

形状记忆聚合物表面响应性润湿性研究进展

王冕¹, 张全超^1,*, 敖海勇¹, 万怡灶^1,2

1 华东交通大学先进材料研究院,江西省纳米生物重点实验室,南昌 330013
2 天津大学材料科学与工程学院,天津 300072

Research Progress of Stimulated Responsive Wettability on Shape-memory Polymer Surfaces

WANG Mian¹, ZHANG Quanchao^1,*, AO Haiyong¹, WAN Yizao^1,2

1 Jiangxi Key Laboratory of Nanobiomaterials, Institute of Advanced Materials,East China Jiaotong University, Nanchang 330013, China
2 School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China

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摘要润湿性是固体材料表面的一种重要性质,会影响材料的各种功能。随着人们对材料性能要求的不断提高,具有固定润湿性能的表面已不能满足复杂多变的应用环境,亟需开发各种具有响应性润湿性的表面。在这种背景下,形状记忆聚合物(SMP)基响应性润湿性表面因具有简单方便及良好的可控性等优点,在液滴定向传输、气泡收集和油水分离等领域具有巨大的应用潜力,引起了人们的广泛关注。
众所周知,调控SMP表面的微结构及形状记忆编程手段是控制SMP表面响应性润湿性的重要方法。虽然众多文献均对此进行了简单探讨,但是二者到底如何影响SMP表面的响应性润湿性,尚缺乏系统而深入的论述。本文基于SMP材料表面不同的微结构(微柱阵列、多孔结构、纹路结构及二元杂化结构),从垂直热压、倾斜热压、选区热压及热拉等编程手段出发,综述了近年来SMP表面响应性润湿性方面的研究进展,并着重介绍了不同的编程及形状记忆回复参数对材料表面响应性润湿性能的影响。最后,指出了当前SMP响应性润湿性表面存在的问题及可能的发展方向。
本文通过梳理表面微结构和编程手段调控SMP表面可控润湿性的最新进展,以期帮助材料领域相关研究人员加深对SMP基响应性润湿性表面的理解,并为智能表面响应性润湿性的研究和开发提供技术及理论指导。

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	王冕
	张全超
	敖海勇
	万怡灶

关键词: 响应性润湿性形状记忆聚合物微结构编程

Abstract: The wettability is an important property of a solid material surface, which can affect various functions of the material. Now, the surfaces with fixed wettability cannot meet the complex and changeable application environment, and thus developing the surfaces with responsive wettability is highly desired. In this context, the stimulated responsive wettability on shape-memory polymer (SMP) surface, which exhibits the advantages of simplicity, convenience and controllability, is potentially used in the fields of droplet directional transmission, bubble collection, and oil-water separation.
It is well known that the microstructure of the SMP surface and the shape-memory programming method are the main approaches to control the responsive wettability of the SMP surface. Although many publications have focused on the issues, the systematic and in-depth discussion about how the above two aspects actuated the responsive wettability of SMP surface is still lacking.
In this paper, from the viewpoints of the different microstructures on SMP surface (micropillar array, porous structure, wrinkle structure, and binary hybrid structure) and different programming methods (vertical hot pressing, inclined hot pressing, selective hot pressing, and hot stretching), we summarize the latest progress for the stimulated responsive wettability on SMP surface; in which, the influences of programming methods and shape memory recovery parameters on the stimulated responsive wettability of SMP surface are highlighted. Finally, the challenges and development trends of the current SMP based responsive wettability surface are proposed.
This paper reviews the latest progress of the influence of microstructure and programming methods on the responsive wettability of SMP surface, which is expected to help researchers in the material field deepen their understanding on SMP based responsive wettability surfaces, andto provide technical and theoretical guidance for developing the smart responsive wettability surface.

Key words: stimulated responsive wettability shape-memory polymer microstructure programming

出版日期: 2022-11-10 发布日期: 2022-11-03

ZTFLH:

TQ317.3

基金资助: 江西省青年自然科学基金(20202BABL214018);江西省教育厅科学技术研究项目(GJJ190352)

通讯作者: * zhangquanchao2006@126.com

作者简介: 王冕,2017年6月毕业于江汉大学文理学院,获得理学学士学位。现为华东交通大学先进材料研究院硕士研究生,在张全超博士的指导下进行研究。目前主要研究领域为形状记忆聚合物。
张全超,博士,华东交通大学讲师、硕士研究生导师。本、硕均就读于四川大学,分别于2009年和2012年获工学学士学位和工学硕士学位。2018年毕业于德国亥姆霍兹吉斯达赫特材料与海洋研究中心(注册大学:波兹坦大学),获工学博士学位。主要研究方向为智能形状记忆高分子及其复合材料。以第一作者及通讯作者发表论文20篇。申请中国国家发明专利10余项,已获授权4项,申请国际专利3项。

引用本文:

王冕, 张全超, 敖海勇, 万怡灶. 形状记忆聚合物表面响应性润湿性研究进展[J]. 材料导报, 2022, 36(21): 20090319-9.
WANG Mian, ZHANG Quanchao, AO Haiyong, WAN Yizao. Research Progress of Stimulated Responsive Wettability on Shape-memory Polymer Surfaces. Materials Reports, 2022, 36(21): 20090319-9.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.20090319 或 http://www.mater-rep.com/CN/Y2022/V36/I21/20090319

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