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材料导报  2020, Vol. 34 Issue (10): 10201-10205    https://doi.org/10.11896/cldb.19040227
  高分子与聚合物基复合材料 |
聚碳酸酯/聚对苯二甲酸丁二醇酯共混物形态结构对微结构注塑制品性能的影响
吕文强, 辛勇
南昌大学机电工程学院,南昌 330031
Effect of Morphology and Structure of Polycarbonate/Polybutylene Terephthalate Blends on the Properties of Microstructure Injection Molded Products
LYU Wenqiang, XIN Yong
College of Mechanical and Electrical Engineering, Nanchang University, Nanchang 330031, China
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摘要 为了得到综合性能较好的微结构注塑制品,采用熔融共混法制备了聚碳酸酯(PC)/聚对苯二甲酸丁二醇酯(PBT)共混物,并以PC/PBT共混物为原料加工成型微结构注塑制品。研究了PC/PBT共混物的形态结构对微结构制品性能的影响,结果表明:随着PBT含量的增大,注塑制品的缺口冲击强度显著提高,拉伸强度呈下降趋势,当PBT质量分数达到30%时,注塑制品的综合力学性能达到最佳。利用流变仪、非等温结晶测试(DSC)仪研究了微结构制品的流变行为以及结晶行为,随着PBT含量的提高,共混体系的柔性链越来越多,加工流动性得到显著改善,更利于微结构制品的加工。当PBT质量分数达到30%时,微结构制品兼具良好的流变性能与力学性能。DSC测试结果表明,少量PC的存在可以促进共混体系的结晶。
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吕文强
辛勇
关键词:  微结构成型  PC/PBT共混物  形态结构  力学性能  流变行为    
Abstract: In order to obtain microstructure injection products with better comprehensive properties, polycarbonate (PC)/polybutylene terephthalate (PBT) blends were prepared by melt blending method. And a microstructure injection product was made by using PC/PBT blends as raw materials.The influence of the morphology of PC/PBT blends on the properties of microstructural products was studied. The results show that with the increase of PBT content, the notch impact strength of injection molding products is significantly increased, and the tensile strength shows a decreasing trend. When the PBT content reaches 30wt%, the comprehensive mechanical properties of injection molding products reach the best. Rheological behavior and crystallization behavior of microstructure products were studied by rheometer and DSC. With the increase of PBT content, the flexible chain of the blend system becomes more and more, and the processing fluidity is significantly improved, which is more conducive to the processing of microstructure products. When the PBT content reaches 30wt%, the microstructure products both exhib-it good rheological properties and mechanical properties. DSC test results show that the presence of a small amount of PC can promote the crystallization of the blend system.
Key words:  microstructure molding    PC/PBT blends    morphological structure    mechanical properties    rheological behavior
               出版日期:  2020-05-25      发布日期:  2020-04-26
ZTFLH:  TQ320.66  
基金资助: 国家自然科学基金(51365038);江西省高校科技落地项目(KJLD12058)
通讯作者:  辛勇,二级教授、博士研究生导师、工学博士(后),享受国务院特殊津贴专家,主要从事聚合物微纳结构精密成型技术方面的研究。主持了国家自然科学基金2项及省(部)级重点科技项目30余项,荣获省(部)级科技进步奖5项,发表学术论文200余篇。xinyong_sh@sina.com   
作者简介:  吕文强,南昌大学机电工程学院,硕士研究生,主要研究方向为聚合物微结构注塑成型技术。
引用本文:    
吕文强, 辛勇. 聚碳酸酯/聚对苯二甲酸丁二醇酯共混物形态结构对微结构注塑制品性能的影响[J]. 材料导报, 2020, 34(10): 10201-10205.
LYU Wenqiang, XIN Yong. Effect of Morphology and Structure of Polycarbonate/Polybutylene Terephthalate Blends on the Properties of Microstructure Injection Molded Products. Materials Reports, 2020, 34(10): 10201-10205.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19040227  或          http://www.mater-rep.com/CN/Y2020/V34/I10/10201
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