Research Progress of High Performance Polyimides Based on Molecular Structure Design
LIU Zizhen1, JIN Xin1, WANG Wenyu2, NIU Jiarong2
1 School of Materials Science and Engineering, Tiangong University, Tianjin 300387, China 2 School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
Abstract: With the rapid development of science and technology, the materials needed in the fields of photovoltaic cells need not only good high temperature resistance, but also high light transmittance. Although polyimide (PI) material has superior high-temperature resistance than other polymers, its highly conjugated rigid molecular chains are prone to form charge transfer complex (CTC), which makes its high-temperature resistance and light transmittance become two contradictory properties. By designing the molecular structure of PI, the generation of CTC can be effectively reduced. As a result, the two kinds of contradictory properties can be balanced and the comprehensive performance of PI material can be maximized. The research of enhancing the comprehensive performance of PI materials by molecular structure design has been widely concerned by researchers at home and abroad. In this paper, the relationships between the main chain, side group, nonplanar structure and end group of PI and its performance are reviewed based on the most representative high temperature resistance and light transmission capacity of PI. The law and relation between different structures and properties are analyzed. Finally, the future development trend of PI materials is prospected.
刘子甄, 金欣, 王闻宇, 牛家嵘. 基于分子结构设计的高性能聚酰亚胺的研究进展[J]. 材料导报, 2021, 35(z2): 600-611.
LIU Zizhen, JIN Xin, WANG Wenyu, NIU Jiarong. Research Progress of High Performance Polyimides Based on Molecular Structure Design. Materials Reports, 2021, 35(z2): 600-611.
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