Research Progress of Atomic Oxygen Resistant Polyimide Materials
WANG Ruihan1,*, ZHAO Ruohong1,*, ZOU Wanyan1, WANG Min1, ZHOU Bo2, QI Shengli1,*, LIU Gang2,*, Wu Dezhen1,3
1 State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China; 2 Shanghai Institute of Spacecraft Equipment, Shanghai 200240, China; 3 Changzhou Institute of Advanced Materials, Beijing University of Chemical Technology, Changzhou 213164, China
Abstract: Since 21st century, the rapid development of aerospace has provided important technical support means for human daily communication, observation of astronomical gas phase, and exploration of the universe. Polyimide (PI) has become one of the indispensable spacecraft materials by virtue of its excellent high and low temperature resistance, mechanical properties, radiation resistance, electrical properties, and solvent resistance. It’s widely used as flexible substrate for solar cell arrays, multi?layer thermal insulation blanket and insulating protective layer for circuit systems of the spacecraft.
However, the spacecraft works in low earth orbit containing atomic oxygen (AO). High?throughput AO with strong oxidizing properties can ra?pidly erode the main thermal control material PI on the surface of the spacecraft, degrading its optical, electrical, mechanical and other important properties, resulting in decreased efficiency and shortened service life of the spacecraft,which leads to the failure of the system’s targets and seriously hinders the development of the space industry.
Over the years, researchers proposed a variety of solutions to the above problems and made great progress. Among them, the method of applying a protective coating on the surface of the material can not only protect the substrate from atomic oxygen erosion, but also maintain the original performance of the base material. It’s suitable for making a variety of different surfaces, has a simple process, a wide range of applications as well. As for the new material of atomic polyimide resistant polyimide, researchers have also overcome difficulties and developed new materials with better performance and longer service life. In addition, due to the limitations of special test conditions, the development of atomic oxygen?resistant ground simulation experiments has developed rapidly. So far, a variety of simulation theories have been proposed and simulators have been manufactured to assist in research.
This article compares the resistance to atomic oxygen of polyimide materials that are currently commercially available, introduces the principles and classification of ground simulation test methods for atomic oxygen resistance, summarizes the types of polyimide materials against atomic oxygen, including protective coating and novel atomic oxygen resistant polyimide material, and made a reasonable judgment on the advantages and disadvantages of various types of protection methods. At the same time, it also points out the development direction and prospect of atomic oxygen resistant polyimide materials in the future.
Watson K A, Palmieri F L, Connell J W. Macromolecules,2002,35,4968.
2
Qi H, Qian Y, Xu J, et al. Corrosion Science,2017,124,56.
3
Duo S W, Liu T Z, Zou X P, et al. Rare Metal Materials and Enginee?ring,2009,38(S2),743(in Chinese).
多树旺,刘庭芝,邹小平,等.稀有金属材料与工程,2009,38(S2),743.
4
Zhang X, Wu Y, He S, et al. Materials Chemistry and Physics,2009,114(1),179.
5
Liu K, Mu H, Shu M, et al. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2017,529,356.
6
Gotlib?Vainstein K, Gouzman I, Girshevitz O, et al. ACS Applied Mate?rials & Interfaces,2015,7(6),3539.
7
Minton T K, Wu B, Zhang J, et al. ACS Applied Materials & Interfaces,2010,2(9),2515.
8
Truscott P, Lei F, Dyer C, et al. In: 2000 IEEE Radiation Effects Data Workshop. Reno, USA,2000,pp.147.
9
Wilson J W, Kim M Y, Shinn J L, et al. Solar Cycle Variation and Application to the Space Radiation Environment. NASA TP?209369,1999.
10
Zheng K H,Yang S S,Li Z H,et al. Spacecraft Environment Engineering,2010,27(6),751(in Chinese).
郑阔海,杨生胜,李中华,等.航天器环境工程,2010,27(6),751.
11
Wang J,Zhu L Q,Li W P,et al. Acta Materiae Compositae Sinica,2009,26(4),36(in Chinese).
王静,朱立群,李卫平,等.复合材料学报,2009,26(4),36.
12
Wang X, Li Y, Qian Y, et al. Advanced Materials,2018,30(36),1803854.
13
Carraher J, Charles E. Inorganic and metal?containing polymeric mate?rials, Springer Science & Business Media, Germany,2012.
14
Packirisamy S, Schwam D, Litt M H. Journal of Materials Science,1995,30(2),308.
15
Fewell L L. Journal of Applied Polymer Science,1990,41(1?2),391.
16
Devapal D, Packirisamy S, Nair C P R, et al. Journal of Materials Science,2006,41(17),5764.
17
Duo S W, Li M S, Zhou Y C. In: China Instrument and Instrument So?ciety. Chengde, 2006,pp.506(in Chinese).
多树旺,李美栓,周延春.中国仪器仪表学会.承德,2006,pp.506.
18
Wang J,Li W P,Chen Y C,et al. Journal of Beijing University of Aeronautics and Astronautics,2009,35(7),824(in Chinese).
王静,李卫平,陈贻炽,等.北京航空航天大学学报,2009,35(7),824.
19
Zhang J Z, Wang X, Lu L D, et al. Engineering Plastics Application,2003(1),20(in Chinese).
张金柱,汪信,陆路德,等.工程塑料应用,2003(1),20.
20
Duo S, Li M, Zhu M, et al. Materials Chemistry & Physics,2008,112(3),1093.
21
Dever J, Groh K D, Townsend J, et al. Astronomical Data Analysis Software & Systems XI,1998,2013(1),484.
22
Thompson C M, Smith J G, Watson K A, et al. Polyimides containing pendent phosphine oxide groups for space applications, NASA NASI?97046, USA,2002.
23
Connell J W, Watson K A. High Performance Polymers,2001,13(1),23.
24
Thompson C M, Smith J J G, Connell J W. High Performance Polymers,2003,15(2),181.
25
Connell J W, Watson K A. Polyimides containing fluorine and phosphorus for potential space applications, NASA Langley Technical Report Server,USA,2000.
26
Su Y X, Wang K, Zhan M S. Journal of Beijing University of Aeronautics and Astronautics,2009,35(7),807(in Chinese).
苏英霞,王凯,詹茂盛.北京航空航天大学学报,2009,35(7),807.
27
Song G, Li X, Jiang Q, et al. RSC Advances,2015,5(16),11980.
28
Tomczak S J, Minton T K, Brunsvold A L, et al. In: The Society for the Advancement of Material and Process Engineering. Covina, USA,2007.
29
Brunsvold A L, Minton T K, Gouzman I, et al. High Performance Polymers,2004,16(2),303.
30
Friedrich J, Kühn G, Mix R, et al. Canadian Medical Association Journal,2003,72(2),99.
31
Yang J J. Study on preparation and properties of the poly(imidesiloxane)/polyimide composite film for atomic oxide?resistant. Master's Thesis, Jilin University, China,2006(in Chinese).
杨晶晶.抗原子氧聚酰亚胺硅氧烷/聚酰亚胺复合膜的制备及性能研究.硕士学位论文,吉林大学,2006.
32
Lei X, Qiao M, Tian L, et al. Corrosion Science,2015,98,560.
33
Illingsworth M L, Betancourt J A, Chen Y, et al. Journal of Applied Polymer Science,2009,113(2),1198.
34
Illingsworth M L, Rheingold A L. Cheminform,1988,19(16),4312.
35
Shawn W, Dai H X, Stapleton R A, et al. High Performance Polymers,2006,18(4),399.
36
Illingsworth M L, Wang W, Mccarney J P, et al. Journal of Applied Polymer Science,2010,113(2),1198.
37
Fei X, Kai W, Zhan M. Applied Surface Science,2010,256(24),7384.
38
Wang X, Zhao X, Wang M, et al. Nuclear Instruments & Methods in Physics Research,2006,243(2),320.
39
Mei L, Wang Q, Wang T, et al. Composites Part B Engineering,2015,77,215.
40
Balaji R, Sasikumar M, Elayaperumal A. Polymer Degradation and Stability,2015,114,125.
41
Kushnoore S, Varma G A, Akhil K, et al. International Journal of Mechanical Engineering and Technology (IJMET),2018,9(4),73.
42
Zhang J, Ai L, Li X, et al. Materials Chemistry and Physics,2019,222,384.
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2021, Vol. 35 
