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材料导报  2021, Vol. 35 Issue (2): 2032-2038    https://doi.org/10.11896/cldb.19110085
  无机非金属及其复合材料 |
控温自修复微胶囊的制备及在水合物地层固井水泥浆中的应用
杨国坤, 蒋国盛, 刘天乐, 覃鑫, 余尹飞
中国地质大学(武汉),非常规固井与特种加固实验室,武汉 430074
Analysis on Preparation of Temperature Controlled Self-repairing Microcapsules and Its Application in Cement Slurry for Hydrate Formation
YANG Guokun, JIANG Guosheng, LIU Tianle, QIN Xin, YU Yinfei
Unconventional Cementing & Special Reinforcement Laboratory, China University of Geosciences (Wuhan), Wuhan 430074, China
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摘要 当深海固井遇到天然气水合物地层时,由于水泥浆水化放热剧烈,水合物的相平衡条件发生改变,诱发水合物分解,易导致固井质量下降甚至失效。为了避免此类问题的出现,可向水泥浆中添加具有控温和水泥石开裂自修复作用的相变微胶囊,既可有效降低固井水泥浆的水化温升,又可提高水泥石的自愈性,进而增强水泥石的防渗性和力学强度。基于此,以Na2HPO4·12H2O为控温芯材、硬脂酸为壁材、E-51环氧树脂为水泥石自修复材料和芯壁材粘接剂,利用油相相分离法制备了一种深水固井水泥浆控温自愈合用微胶囊。研究结果表明:当微胶囊芯壁比为1∶1.5时,芯壁间为牢固的化学-物理连接,微胶囊的包封率可达87.5%,相变潜热可达155.8 J/g,控温范围可达30~95 ℃。随着微胶囊含量的增加,固井水泥浆的流动性有小幅度提高,抗压强度最高可提升47.1%,抗折强度最高可提升52.2%,渗透率最多可降低61.1%。水泥浆放热峰值温度最多可降低1.8 ℃,峰值温度出现的时间最多可滞后520 min。
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杨国坤
蒋国盛
刘天乐
覃鑫
余尹飞
关键词:  深水固井  水合物地层  水泥浆水化热  控温微胶囊  水泥石自修复    
Abstract: Deepwater cementing in natural gas hydrate formations, due to the intense hydration of cement slurry, the phase equilibrium conditions of hydrates change, and the decomposition of hydrates is induced, which easily leads to the decline or even failure of cementing quality. To avoid such problems, the phase change reinforcing microcapsule materials can be added into the cement slurry to slow down the heat release of it du-ring the cementing process. And it can also improve the self-healing property of cement slurry while enhancing the impermeability and mechanical strength of it. In the experiment, Na2HPO4·12H2O works as the temperature-control core material while stearic acid as the wall material, and the E-51 epoxy resin is used to strengthen the self-healing property of cement stone as well as to glue the core material and the wall material together. And oil phase separation is used to coat the core material. When the ratio of the core material (Na2HPO4·12H2O) to the wall material (stearic acid) is 1∶1.5, the coating rate of the microcapsule is 87.5%, and the latent heat of phase change is 155.8 J/g while the temperature control range is from 30 ℃ to 95 ℃, and then there is a solid chemical-physical connection between the core material and the wall material. When different amounts of microcapsules are added into the cement slurry, it is found that the fluidity of the cement slurry improves with the increase of the amount of the microcapsule. The rupture strength can be increased by a maximum of 52.2% while the compressive strength can be increased by 47.1%, and the permeability can be reduced by 61.1% at most. As well, the temperature of the exothermic peak of the slurry can be reduced by 1.8 ℃ at most, and the retardation time can even reach 520 min.
Key words:  deep-water cementing    hydrate formations    cement slurry hydration heat release    temperature control microcapsule    self-repairing of cementing stone
               出版日期:  2021-01-25      发布日期:  2021-01-28
ZTFLH:  TB332  
基金资助: 国家重点研发计划项目“乳品废水乳糖母液基微生物固井技术”(2016YFE0204300);中国地质大学(武汉)中央高校基本科研业务费专项资金
通讯作者:  liutianle2008@163.com   
作者简介:  杨国坤,2018年毕业于中国地质大学(武汉),获得工学学士学位。现为中国地质大学(武汉)工程学院地质工程专业硕士研究生,在刘天乐副教授的指导下进行研究。目前主要研究领域为深水水合物地层的固井水泥浆控温材料和自愈合微胶囊。
刘天乐,中国地质大学(武汉)工程学院,副教授。2010年6月本科毕业于中国地质大学(武汉)工程学院,2013年6月在俄罗斯圣彼得堡国立矿业大学钻探教研室取得博士学位,同年9月回到中国地质大学(武汉)任职特聘副教授。主要研究方向为控温加固微胶囊制备、非常规固井与特种加固技术的研究,并取得了大量系统性、创新性的研究成果,入选湖北省“海外优秀博士引智计划”和江苏省“双创人才计划”,主持或参与科研项目10余项,在国内外重要期刊发表文章30余篇,以第一完成人申报中国发明专利6项、俄罗斯发明专利8项,获教育部技术发明一等奖1项、湖北省自制实验仪器奖二等奖1项、俄罗斯圣彼得堡青年科技奖三等奖1项。
引用本文:    
杨国坤, 蒋国盛, 刘天乐, 覃鑫, 余尹飞. 控温自修复微胶囊的制备及在水合物地层固井水泥浆中的应用[J]. 材料导报, 2021, 35(2): 2032-2038.
YANG Guokun, JIANG Guosheng, LIU Tianle, QIN Xin, YU Yinfei. Analysis on Preparation of Temperature Controlled Self-repairing Microcapsules and Its Application in Cement Slurry for Hydrate Formation. Materials Reports, 2021, 35(2): 2032-2038.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19110085  或          http://www.mater-rep.com/CN/Y2021/V35/I2/2032
1 Guang X J, Wang M S. Petroleum Drilling Techniques, 2016, 44(5), 45(in Chinese).
光新军,王敏生.石油钻探技术, 2016, 44(5), 45.
2 Taoutaou S, Ashraf S, Takahashi U. In: 2014 International Petroleum Technology Conference. Kuala Lumpur, 2014, pp. 1.
3 Li C M, Di R L. Exploration Engineering, 2000(3), 5 (in Chinese).
李常茂, 狄瑞伦. 探矿工程, 2000(3), 5.
4 Liu L P, Sun Z L, Z L, et al. Acta Geologica Sinica-English Edition. 2019, 93(3), 731.
5 Zheng M M, Liu T L, Gao Z Y, et al. Journal of Petroleum Science and Engineering,2019, 178, 429.
6 Marin-Moreno, Hector,Giustiniani, Michela,Tinivella, Umberta, et al. Marine and Petroleum Geology, 2016, 71, 76.
7 Fusao Oka, Sayuri Kimoto, Tomohiko Fushita.International Journal of Mechanical Sciences, 2010, 52(2), 365.
8 Tupsakhare, Swanand S, Kattekola. Samhita, Castaldi, Marco J. Industrial & Engineering Chemistry Research, 2017, 56(15), 4588.
9 Liu T L, Zheng S J, Wang R, et al. Acta Petrolei Sinica, 2018, 39(8), 937(in Chinese).
刘天乐, 郑少军, 王韧, 等. 2018, 39(8), 937.
10 Liu Z Z, Li T S, Sun H C, et al. Journal of Energy Chemistry, 2019, 30, 90.
11 Ruppel C, Jones E, Boswell R. Marine and Petroleum Geology, 2008, 25(9), 819.
12 Fujii Tetsuya, Suzuki Kiyofumi, Komatsu Yuhei. Marine and Petroleum Geology, 2015, 66(Pt.2), 358.
13 Bai Y H, Li Q P, Zhou J L, et al.Drilling Petroleum Techniques, 2009, 37(3), 17(in Chinese).
白玉湖, 李清平, 周建良, 等. 石油钻探技术, 2009, 37(3), 17.
14 Fang C L, Liu T L, Zheng M M, et al. Journal of Nayural Gas Science & Engineering, 2018, 52(4), 348.
15 Guo X Y, Bu Y H, Li J, et al.Natural Gas Industry, 2013, 33(11), 86(in Chinese).
郭辛阳, 步玉环, 李娟, 等.天然气工业, 2013, 33(11), 86.
16 Nabipour A, Joodi B, Sarmadivaleh M, et al. In: Deep Gas Conference and Exhibition. Manama, Bahrain, 2015, pp, 577.
17 Wu B S, Liu T L, Zhang X, et al. Energies, 2017, 11(1), 42.
18 Kenneth Hampshire, Mike mcFadyen, Dominic Ong. In: IADC/SPE Asia Pacific drilling technology conference and exhibition. 2004, pp, 1.
19 Liu T L, Jiang G S, Zhang P, et al. Journal of Natural Gas science and Engineering, 2016, 33(7), 934.
20 Zheng M M, Liu T L, Jiang G S, et al. Journal of Earth Science, 2016, 27(10),856.
21 Ron Leppers, Castellon Castellon, Luisa F Cabeza, et al. Energy and Buildings, 2006, 39(2007), 113.
22 Shang H B, Xu L L, Shen Y H, et al. Materials Review, 2015,19(12), 42(in Chinese).
尚红波,徐玲玲,沈艳华等.材料导报,2005,19(12), 42.
23 Chen C, Guo H F, Liu Y N, et al. Energy and Buildings, 2008, 40(5), 882.
24 Sam meure, Dong Y W, David Solomon. Progress in Polymer Science. 2008, 33(5), 479.
25 Liu M, Li M, Liu X Z, et al. Drilling & Production Technology,2015 (2), 27(in Chinese).
刘萌, 李明, 刘小利, 等.钻采工艺, 2015(2),27.
26 Zhang M. A study on microcapsule based self-healing method and mechanism for cementitious composites. Ph.D. Thesis, Central South University, China, 2013 (in Chinese).
张鸣.水泥基材料用微胶囊自修复技术与原理的研究. 博士学位论文. 中南大学, 2013.
27 Li L.Research on preparation and properties of phase change materials and energy storage.Ph.D. Thesis, Chongqing University, China, 2010 (in Chinese).
李莉. 相变材料及其储能混凝土的制备与性能研究. 博士学位论文, 重庆大学,2010.
28 Liu T L, Wu W B, Dou B, et al. Marine Georesources & Geotechnology, 2016, 35(4), 8.
29 Zhang R, Mao X, Peng Z G, et al. Fine Chemicals, 2017, 34(4), 469(in Chinese).
张 瑞, 毛 旭, 彭志刚, 等. 精细化工, 2017, 34(4), 469.
30 Zhang L, Huang W, Zong H. Journal of Highway and Transportation Research and Development, 2006, 23(8), 9(in Chinese).
张磊, 黄卫, 宗海. 公路交通科技, 2006,23 (8), 9.
31 Jun Cheol Lee, Chang Joon Lee, Chul-Woo Chung, et al. Materials Letters, 2013, 105(Aug.15), 224.
32 Ou J P, Ding S Q, Wang J L, et al. Smart Materials & Structures, DOI:10.1088/1361-665X/aae59f.
33 Xu D, Hou G, Xi J J, et al. Petrochemical Industry Application, 2016, 35(8), 32(in Chinese).
许迪, 候冠中, 席江军, 等. 石油能源化工, 2016, 35(8), 32.
34 Sun X J, Xu G, Qu Z H, et al. Natural Gas and Oil, 2017, 35(4), 63(in Chinese).
孙晓杰, 余纲, 瞿志浩, 等. 天然气与石油, 2017, 35(4), 63.
35 Wang T Y.Study on temperature regulation and enhanced heat transfer of calcium carbonate-coated paraffin-based phase change microcapsules. Ph.D. Thesis, South China University of Technology, China, 2017(in Chinese).
王婷玉.碳酸钙包覆石蜡基相变微胶囊的调温及强化传热研究. 博士学位论文, 华南理工大学, 2017.
36 Lu Z C. Effect of different functional group organic admixtures on cement hydration and analysis of its mechanism. Ph.D. Thesis, Tsinghua University, China, 2017(in Chinese).
卢子成. 不同官能团有机外加剂对水泥水化的影响规律及机理分析.博士学位论文, 清华大学, 2017.
37 Zhao L. Study on strengthening of cement-based composites by PC modified GO and its mechanism. Ph.D. Thesis, Southeast University, China, 2018(in Chinese).
赵丽. PC改性GO对水泥基复合材料的强化及其机理研究.博士学位论文, 东南大学, 2018.
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