复合氟化改性制备EP-ZnO纳米超疏水涂层的研究

材料导报

2021, Vol. 35

Issue (z2): 56-59

无机非金属及其复合材料

复合氟化改性制备EP-ZnO纳米超疏水涂层的研究

舒忠虎¹, 何建军², 段焱森¹, 罗金¹, 周承伟², 鲍江涌²

1 国家能源集团龙源江永风力发电有限公司,长沙 410000
2 长沙理工大学能源与动力工程学院,长沙 410114

Study on Preparation of EP-ZnO Nano Superhydrophobic Coating by Compound Fluorination Modification

SHU Zhonghu¹, HE Jianjun², DUAN Yansen¹, LUO Jin¹, ZHOU Chengwei², BAO Jiangyong²

1 Longyuan Jiangyong Wind Power Generation Co., Ltd. of CHN Energy Group, Changsha 410000, China
2 School of Energy and Power Engineering, Changsha University of Science and Technology, Changsha 410114,China

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摘要风力发电机叶片覆冰严重影响风机安全经济运行,高质量的超疏水防冰涂层是当前研究的热点之一。本实验采用复合氟化改性的方法分别对环氧树脂(EP)和固化剂进行氟化改性,同时通过ZnO纳米颗粒对涂层表面结构进行修饰制备EP-ZnO纳米复合超疏水涂层,并研究了涂层的疏水性、耐磨性和抗冲击性能。研究结果表明,复合氟化改性能有效提高涂层的疏水性能,其接触角为150°,滚动角为6°;经过ZnO纳米颗粒对涂层表面结构修饰后涂层的接触角达158°,滚动角为3°。涂层具有良好的粘附力、稳定的抗冲击能力和耐磨性能,在磨损实验过后,涂层仍能保持较高的疏水性能。

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	舒忠虎
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	鲍江涌

关键词: 氟化改性超疏水涂层 ZnO 低表面能微纳米结构

Abstract: The icing of wind turbine blades seriously affects the safe and economic operation of wind turbines, and high-quality super-hydrophobic anti-icing coatings are the current research focus. In this paper, the epoxy resin (EP) and curing agent are fluorinated modified by the compound fluorination modification method, and the surface structure of the coating is modified by ZnO nanoparticles to prepare the EP-ZnO nanocomposite superhydrophobic coating.The hydrophobicity, wear resistance and impact resistance of the coating are studied.The research results show that the composite fluorinated modification properties effectively improve the hydrophobic properties of the coating, with a contact angle of 150° and a rolling angle of 6°; the contact angle of the coating after the modification of the coating surface structure by ZnO nanoparticles reaches 158°, and the roll angle is 3°. The coating has good adhesion, stable impact resistance and wear resistance. After the wear test, the coating can still maintain high hydrophobic properties.

Key words: fluorination modification superhydrophobic coating ZnO low surface energy micro-nanostructure

发布日期: 2021-12-09

ZTFLH:

TK83

基金资助: 国家高端外专项目(BG20190229005);国家能源集团科技创新项目(HJLFD-QTHT-2019-09)

通讯作者: hejianjun@csust.edu.cn

作者简介: 舒忠虎,国家能源集团龙源江永风力发电有限公司总工程师,主要从事能源动力设备与新能源智慧运维技术研究。
何建军,博士,长沙理工大学能源与动力工程学院教授。2006年毕业于湖南大学材料科学与工程专业,获工学博士学位,湖南省高校青年骨干教师,澳大利亚莫纳什大学访问学者。主要从事金属材料、新能源材料与风力发电技术等领域的科研,主持国家自然科学基金、湖南省自然科学基金重点项目、国家能源集团科技创新项目等科研项目10余项,在国内外重要期刊发表论文70余篇。

引用本文:

舒忠虎, 何建军, 段焱森, 罗金, 周承伟, 鲍江涌. 复合氟化改性制备EP-ZnO纳米超疏水涂层的研究[J]. 材料导报, 2021, 35(z2): 56-59.
SHU Zhonghu, HE Jianjun, DUAN Yansen, LUO Jin, ZHOU Chengwei, BAO Jiangyong. Study on Preparation of EP-ZnO Nano Superhydrophobic Coating by Compound Fluorination Modification. Materials Reports, 2021, 35(z2): 56-59.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2021/V35/Iz2/56

1 刘韬文,蒙文川,戴承伟,等.湖北电力,2019,43(1),10-17.
2 邱刚, 舒立春, 胡琴,等. 中国电机工程学报, 2018(7),2198.
3 陈炳彬, 张征, 鲁聪达,等. 中国机械工程, 2019, 030(7),771.
4 舒立春, 戚家浩, 胡琴,等. 中国电机工程学报, 2017, 37(13),3816.
5 林修洲,杨丽,梅拥军,等. 中国腐蚀与防护学报,2017,37(6),567.
6 郑海坤,常士楠,赵媛媛.化学进展,2017,29(1),102.
7 马国佳, 郑海坤, 常士楠,等. 化学学报, 2019, 77(3),269.
8 蒋炜, 杨超, 袁绍军, 等. 化工进展, 2019, 38(1),351.
9 占彦龙, 李文, 李宏, 等. 材料工程, 2019, 47(1),58.
10 Davis J, O'Grady A P, Dale A, et al.Science of the Total Environment, 2015, 534,65.
11 Qing Y, Yang C, Hu C, et al. Applied Surface Science, 2015, 326,48.
12 Vazirinasab E, Jafari R, Momen G. Surface & Coatings Technology, 2018,341,40.
13 张静, 许海波, 黄悦, 等. 材料导报, 2020(12),12005.
14 何金梅, 何姣, 袁明娟, 等. 化工进展, 2019, 38(7),3013.
15 Scarratt L R J, Steiner U, Neto C.Advances in Colloid and Interface Science, 2017,246,133.
16 周莹,肖利吉,姚丽,等.材料导报,2019,33(7),1234.
17 徐卜琴, 赵宗倩, 徐桂龙, 等. 硅酸盐学报, 2018, 046(8),1173.
18 杨舒生,屈健,杨学贵. 工程热物理学报,2018,39(7),1549.
19 王凯, 王德武, 侯得印, 等. 化工学报, 2019, 70(1),308.
20 侯成敏, 李娜, 董海涛,等. 功能材料, 2019, 50(8),8091.
21 Kang H, Liu Y, Lai H, et al. ACS Nano, 2018, 12(2),1074.
22 Choi D, Yoo J, Park S M, et al.Applied Surface Science, 2017, 393,449.
23 Wang X, Li X, Lei Q, et al.Applied Surface Science, 2019, 478,642.
24 Zhu J, Hu X F. Materials Letters, 2016, 190,115.
25 Wang W,Lockwood K, Boyd L M, et al. ACS Applied Materials &Interfaces,2016,8(29),18664.
26 Liu Y, Fu K, Liu J, et al. Applied Surface Science, 2019, 497,143663.
27 Qi Y, Chen S, Zhang J. Applied Surface Science, 2019, 476, 161.
28 Cassie A B D, Baxter S. Transactions of the Faraday Society, 1944, 40:546.

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[14]	潘会, 胡轶, 兀晓文, 胡帅帅, 张浩茹. ZnO/CNTs复合材料的制备、表征及光催化性能[J]. 材料导报, 2018, 32(24): 4224-4229.
[15]	高硕洪, 刘敏, 张小锋, 邓春明. 新型陶瓷基复合超疏水涂层的制备及其性能[J]. 材料导报, 2018, 32(20): 3510-3516.

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