Research Progress of Utilization of Red Mud in Building Materials and Geopolymer Composites
LIU Xiaoming1,2,*, ZHANG Zengqi1,*, LI Yu2, ZHANG Na3, WANG Yaguang4, ZHANG Wei1, ZHANG Yihe3
1 School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China 2 State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083, China 3 School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China 4 School of Civil Engineering and Architecture, Henan University, Kaifeng 475004, Henan, China
Abstract: Red mud is a kind of industrial solid waste with low comprehensive utilization rate, and its large-scale, complete and safe utilization is very important for the green development of the electrolytic aluminum industry. The preparation of building materials products is the major way to realize the large-scale utilization of industrial solid wastes. Cementitious materials with excellent properties such as cement or geopolymer can be prepared by taking full advantage of the high alkalinity of red mud. The total content of the solid wastes in building blocks and road base materials prepared by red mud could exceed 90% due to the synergistic effect between various raw materials. At the same time, the production of ceramic or ceramisite is a green, low carbon, high value and efficient way to consume red mud. Using red mud as filler of composite polymer materials can also realize the high value-added utilization of red mud. In recent years, researchers have carried out systematic research on the recycling and utilization of red mud to prepare cementitious materials, building blocks, road base materials, ceramisites and composite polymer materials, and some of the results have been popularized in industrialization. This paper mainly introduces the latest progress of the utilization of red mud in preparation of building materials and composite polymer materials, and puts forward suggestions on the improvement of the comprehensive utilization rate of red mud from the aspects of basic theoretical research, application technology development and the national policy guidance.
通讯作者:
*刘晓明,北京科技大学冶金与生态工程学院教授、副院长、博士研究生导师,入选国家级重大人才计划青年项目。中国矿业大学(北京)和美国威斯康星-麦迪逊大学联合培养博士,2010年获得工学博士学位,2010年到北京科技大学工作至今。目前主要从事工业固废/危废资源化高效利用的研究与应用工作。发表论文110余篇,包括Journal of Hazardous Materials、Chemical Engineering Journal、Journal of Cleaner Production、Resources、Conservation and Recycling等。 张增起,北京科技大学冶金与生态工程学院副教授、硕士研究生导师,入选中国科协青年人才托举工程。2014年和2019年于清华大学土木工程系分别获得工学学士学位和博士学位,2021年到北京科技大学工作至今。目前主要从事工业固废建材化利用等研究工作。发表论文30余篇,包括Cement and Concrete Research、Journal of Cleaner Production、Resources、Conservation and Recycling 等。liuxm@ustb.edu.cn;zhangzq@ustb.edu.cn
引用本文:
刘晓明, 张增起, 李宇, 张娜, 王亚光, 张未, 张以河. 赤泥在建筑材料和复合高分子材料中的利用研究进展[J]. 材料导报, 2023, 37(10): 23020109-14.
LIU Xiaoming, ZHANG Zengqi, LI Yu, ZHANG Na, WANG Yaguang, ZHANG Wei, ZHANG Yihe. Research Progress of Utilization of Red Mud in Building Materials and Geopolymer Composites. Materials Reports, 2023, 37(10): 23020109-14.
1 Li S, Zhou B, Liu W C, et al. China Journal of Nonferrous Metallurgy, 2022, 51(5), 32(in Chinese). 李帅, 周斌, 刘万超, 等. 中国有色冶金, 2022, 51(5), 32. 2 Mahinroosta M, Karimi Z, Allahverdi A. Encyclopedia of Renewable and Sustainable Materials, 2020, 2, 561. 3 Mayara S, Liseane P. Construction and Building Materials, 2020, 260, 119894. 4 Tsakiridis P, Agatzini-Leonardou S, Oustadakis P. Journal of Hazardous Materials, 2004, 116, 103. 5 Lei W, Liang C, Daniel C, et al. Environment International, 2019, 133(Part B), 105247. 6 Liu C, Ma S, Zheng S, et al. Hydrometallurgy, 2018, 175, 224. 7 Liu W, Chen X, Li W, et al. Journal of Cleaner Production, 2014, 84, 606. 8 Man K, Zhu Q, Li L, et al. Ceramics International, 2017, 43(10), 7565. 9 Zhang N, Sun H, Liu X, et al. Journal of Hazardous Materials, 2009, 167, 927. 10 Yang J, Zhang D, Jian H, et al. Ceramics International, 2008, 34(1), 125. 11 Wang S, Li Z, Bai X, et al. Journal of Analytical and Applied Pyrolysis, 2018, 136(11), 8. 12 Chen R, Cai G, Dong X, et al. Construction and Building Materials, 2019, 216(8), 188. 13 Alessandra L, Danilo D, Roberto C, et al. Construction and Building Materials, 2015, 101, 432. 14 Ogawa K, Roy D. Cement and Concrete Research, 1982, 12(2), 247. 15 Kim T, Kang C. Materials, 2021, 14(9), 2301. 16 Wu F, Li H, Yang K. Bulletin of the Chinese Ceramic Society, 2016, 35(4), 1306(in Chinese). 吴锋, 李辉, 杨康. 硅酸盐通报, 2016, 35(4), 1306. 17 Xie L L, Deng M. Journal of Nanjing Tech University, 2021, 43(4), 473(in Chinese). 谢礼兰, 邓敏. 南京工业大学学报, 2021, 43(4), 473. 18 Tobias H, Amy V, Silviana O. Cement and Concrete Research, 2021, 145, 106463. 19 Wang S, Jin H, Deng Y, et al. Journal of Cleaner Production, 2020, 289(11), 125136. 20 Zhang W, Liu X M, Wang Y G, et al. Journal Hazarders Materials, 2021, 410, 124592. 21 Shen Y, Liu S, Wang Y, et al. Construction and Building Materials. 2022, 345, 129171. 22 Dener M, Karatas M, Mohabbi M. Construction and Building Materials, 2021, 304, 124671. 23 Dai L L, Chen J N, Rui J W. Bulletin of the Chinese Ceramic Society, 1988(4), 25(in Chinese). 戴丽莱, 陈建南, 芮君渭. 硅酸盐通报, 1988(4), 25. 24 Zhang W, Hao X S, Wei C, et al. Journal of Building Engineering, 2022, 60, 105177. 25 Kaige T, Wang Y, Dong B, et al. Construction and Building Materials, 2022, 351, 128869. 26 Garanayak L. Materials Today:Proceedings, 2021, 44, 1437. 27 Xia R J, Zhu J P, Liu S X, et al. Nonferrous Metals, 2017, 7(6), 58(in Chinese). 夏瑞杰, 朱建平, 刘少雄, 等. 有色金属工程, 2017, 7(6), 58. 28 Wang G. Preparation of green red mud based sintering-free ceramsites and its performance research. Master's Thesis, Shandong University, China, 2021(in Chinese). 王冠. 赤泥基绿色免烧结陶粒的制备试验及性能研究. 硕士学位论文. 山东大学, 2021. 29 Mota B, Matschei T, Scrivener K. Cement and Concrete Research, 2018, 108, 172. 30 Gao Y F, Li Z, Zhang J, et al. Construction and Building Materials, 2020, 264, 120201. 31 Huang Y, Pei Y, Qian J, et al. Construction and Building Materials, 2020, 249, 118774. 32 Ren C, Wang W, Mao Y, et al. Journal of Cleaner Production, 2017, 167(20), 1314. 33 Fu L J, Yang Y, Lu J H. China Building Materials Science and Technology, 2021, 30(4), 80(in Chinese). 付立娟, 杨勇, 卢静华. 中国建材科技, 2021, 30(4), 80. 34 Liu W C, Yan K, He X Z, et al. Bulletin of the Chinese Ceramic Society, 2016, 35(2), 453(in Chinese). 刘万超, 闫琨, 和新忠, 等. 硅酸盐通报, 2016, 35(2), 453. 35 Kumar A, Kumar S. Construction and Building Materials, 2013, 38, 865. 36 Yang Z, Mocadlo R, Zhao M, et al. Construction and Building Materials, 2019, 221, 308. 37 He J, Zhang J, Yu Y, et al. Construction and Building Materials, 2012, 30, 80. 38 Pan Z, Cheng L, Lu Y, et al. Cement and Concrete Research, 2002, 32(3), 357. 39 Pan Z, Li D, Yu J, et al. Cement and Concrete Research, 2003, 33(9), 1437. 40 Giannopoulou I, Dimas D, Maragkos I, et al. Global NEST Journal, 2009, 11(2), 127. 41 Ye N. Study on the preparation of geopolymer from pretreated bay red mud and mechanism of the strength formation. Ph. D. Thesis, Huazhong University of Science and Technology, China, 2016(in Chinese). 叶楠. 拜耳法赤泥活化预处理制备地聚物及形成强度机理研究. 博士学位论文, 华中科技大学, 2016. 42 Ke X Y, Ye N, Bernal S A, et al. In:Proceedings of the 2nd International Conference on Advances in Chemically Activated Materials. Changsha, 2014. 43 Hyeok J K, Kang S, Choe G. International Journal of Concrete Structures and Materials, 2018, 12(1), 1. 44 Zhang M, Zhao M, Zhang G, et al. Construction and Building Materials, 2016, 124, 373. 45 Zhang M, El-Korchi T, Zhang G, et al. Fuel, 2014, 134, 315. 46 Choo H, Lim S, Lee W, et al. Construction and Building Materials, 2016, 125, 21. 47 Bǎdǎnoiu A, Al-Saadi T, Voicu G. International Journal of Mineral Processing, 2015, 135, 1. 48 Kaya K, Soyer-Uzun S. Ceramics International, 2016, 42(6), 7406. 49 Singh S, Aswath M U, Ranganath R V. Construction and Building Materials, 2018, 177, 91. 50 Li Y, Min X, Ke Y, et al. Waste Management, 2019, 83, 202. 51 Ye N, Yang J, Ke X, et al. Journal of the American Ceramic Society, 2014, 97(5), 1652. 52 Bao S, Qin L, Zhang Y, et al. Construction and Building Materials, 2021, 297, 123789. 53 Ke X, Bernal S, Ye N, et al. Journal of the American Ceramic Society, 2015, 98(1), 5. 54 Yao Y, Li Y, Liu X, et al. Construction and Building Materials, 2013, 47, 496. 55 Tao M L, Zhang Z S, Zhuo R F. Nonferrous Metals(Extractive Metallurgy), 2009(4), 45(in Chinese). 陶敏龙, 张召述, 卓瑞锋. 有色金属(冶炼部分), 2009(4), 45. 56 Yang J, Xiao B. Construction and Building Materials, 2008, 22, 22299. 57 Li Z P, Liu X M, Li Y, et al. Construction and Building Materials, 2020, 262, 120722. 58 Feng Y L, Yu L J, Chao Y H. Acta Mineralogica Sinica, 2013(S2), 694(in Chinese). 冯有利, 于立竟, 晁钰鸿. 矿物学报, 2013(S2), 694. 59 Zhang N, Liu X M, Sun H H. Chinese Journal of Materials Research, 2014, 28(5), 325(in Chinese). 张娜, 刘晓明, 孙恒虎. 材料研究学报, 2014, 28(5), 325. 60 Xu Y T, Yang B, Liu X M, et al. International Journal of Minerals, Metallurgy, and Materials, 2019, 26(8), 983. 61 Dodoo-Arhin D, Konadu D S, Annan E, et al. American Journal of Materials Science, 2013, 3, 110. 62 He H, Yue Q, Su Y, et al. Journal of Hazardous Material, 2012, 203-204, 53. 63 Liu X M, Zhang N, Sun H H, et al. Cement and Concrete Research, 2011, 41(8), 847. 64 Mandal A K, Verma H R, Sinha O. Journal of Cleaner Production, 2017, 162, 949. 65 Liu S, Guan X, Zhang S, et al. Ceramics International, 2017, 43(15), 13004. 66 Zhang Y L, Liu X M, Xu Y T, et al. Journal of Cleaner Production, 2019, 232, 980. 67 Krivenko P, Kovalchuk O, Pasko A, et al. Construction and Building Materials, 2017, 151, 819. 68 Li Y, Liu X M, Li Z P, et al. Journal of Cleaner Production, 2021, 284, 124777. 69 Mukiza E, Liu X M, Zhang L L, et al. Construction and Building Materials, 2019, 220, 297. 70 Liu X M, Tang B W, Yin H F, et al. Chinese Journal of Engineering, 2018, 40(4), 438(in Chinese). 刘晓明, 唐彬文, 尹海峰, 等. 工程科学学报, 2018, 40(4), 438. 71 Zhang Y L, Liu X M, Xu Y T, et al. Construction and Building Mate-rials, 2019, 220, 364. 72 Zhang W, Gu J R, Zhou X, et al. Journal of Cleaner Production, 2021, 316, 128355. 73 Liu Z Y. Study on modification and mechanism of red mud used in base pavement. Master's Thesis, Taiyuan University of Technology, China, 2021(in Chinese). 刘治言. 赤泥用于路面基层材料的改性与机理研究. 硕士学位论文, 太原理工大学, 2021. 74 Zhang J M, Zhang T, Li C. Journal of Shandong Jiaotong University, 2017, 25(3), 51(in Chinese). 张嘉明, 张涛, 李昶. 山东交通学院学报, 2017, 25(3), 51. 75 Tan B, Liu Q, Chen P. Journal of Wuhan University of Technology, 2021, 43(8), 51(in Chinese). 谭波, 刘琦, 陈平. 武汉理工大学学报, 2021, 43(8), 51. 76 Geng R C. Research on road performance of cement red mud stabilized crushed stone base material. Master's Thesis, Shandong Jianzhu University, China, 2020(in Chinese). 耿汝超. 水泥赤泥稳定碎石基层材料的路用性能研究. 硕士学位论文, 山东建筑大学, 2020. 77 Wang M F, Liu X M. Journal of Hazardous Materials, 2021, 408, 124420. 78 Cui Y P, Wang L C, Liu J, et al. Construction and Building Materials, 2022, 323, 126444. 79 Enrico B, Hamada E, Anna M, et al. Construction and Building Materials, 2022, 359, 129540. 80 Zhu X B, Li W, Guan X M. Journal of Hazardous Materials, 2015, 286, 85. 81 Mukiza E, Zhang L L, Liu X M, et al. Resources, Conservation and Recycling, 2019, 141, 187. 82 Zhang N, Li H X, Zhao Y Z, et al. Journal of Hazardous Materials, 2016, 306, 66. 83 Zhang Y L, Liu X M, Xu Y T, et al. Journal of Hazardous Materials, 2020, 390, 122188. 84 Wang S H, Jin H X, Deng Y, et al. Journal of Cleaner Production, 2021, 289, 125136. 85 Sglavo V M, Maurina S, Conci A, et al. Journal of the European Ceramic Society, 2000, 20(3), 245. 86 Babisk M P, Amaral L F, Ribeiro L D, et al. Journal of Materials Research and Technology-JMR&T, 2020, 9(2), 2186. 87 Pei D J, Li Y, Cang D Q. Materials Letters, 2019, 240, 229. 88 Li Y, Liu Y M. Chinese Journal of Engineering, 2021, 43(12), 1713(in Chinese). 李宇, 刘月明. 工程科学学报, 2021, 43(12), 1713. 89 Pei D J, Li Y, Cang D Q. Ceramics International, 2017, 43(18), 16936. 90 Wang W, Chen W J, Liu H T. Ceramics International, 2019, 45(8), 9852. 91 Liu S H, Guan X M, Zhang S S, et al. Ceramics International, 2017, 43(15), 13004. 92 Ding X, Pan K K, Peng B, et al. Journal of the Chinese Ceramic Society, 2022, 50(3), 713(in Chinese). 丁祥, 潘凯凯, 彭波, 等. 硅酸盐学报, 2022, 50(3), 713. 93 Zong Y B, Chen W H, Fan Y, et al. International Journal of Minerals, Metallurgy and Materials, 2018, 25(9), 1010. 94 李宇, 高峰, 林安极, 等. 中国专利, CN113880554B, 2022. 95 Pei D J. Study on the mechanism and application of Si-Ca multicomponent ceramics prepared from metallurgical slags. Ph. D. Thesis, University of Science and Technology Beijing, China, 2019(in Chinese). 裴德健. 利用冶金渣制备硅钙基多元体系陶瓷的机理及应用研究. 博士学位论文, 北京科技大学, 2019. 96 Wang Y K, Li Y, Wang Y Z, et al. Energy for Metallurgical Industry, 2018, 37(2), 48(in Chinese). 王亚昆, 李宇, 王耀忠, 等. 冶金能源, 2018, 37(2), 48. 97 Sun Y H, Li J S, Chen Z, et al. Construction and Building Materials, 2021, 287, 122993. 98 Mi H C, Yi L S, Wu Q, et al. Ceramics International, 2021, 47(13), 18218. 99 Wang J N, Xu K D, Li Z X, et al. Light Metals, 2021(5), 21(in Chinese). 王继娜, 徐开东, 李志新, 等. 轻金属, 2021(5), 21. 100 姚长青, 李宇, 郑灵棋, 等. 中国专利, CN214148790U, 2021. 101 李宇, 姚长青. 中国专利, CN112880394B, 2022. 102 Agrawal S, Dhawan N. Minerals Engineering, 2021, 171, 107084. 103 Gao Y, Zhang J, Chen C, et al. Journal of Cleaner Production, 2021, 320, 128887. 104 Kazak O, Tor A. Journal of Hazardous Materials, 2020, 393, 122391. 105 Chand N, Hashmi S. Indian Journal of Engineering and Materials Sciences, 2000, 7(2), 103. 106 Ding C, Zhang Y, Zhang N, et al. Construction and Building Materials, 2022, 333, 127340. 107 Wang X, Zhang N, Zhang Y, et al. Construction and Building Materials, 2020, 261, 120495. 108 Biswas S, Patnaik A, Kaundal R. Advances in Mechanical Engineering, 2012, 4, 141248. 109 Biswas S, Satapathy A. Materials and Design, 2010, 31(4), 1752. 110 Panda S, Behera D. Materials Today:Proceedings, 2017, 4, 3325.