Research Progress on the Glass Structure of Supplementary Cementitious Materials with Relation to Their Hydraulic Reactivity
JIN Yu1,2, FENG Weipeng2, DONG Zhijun2, Manuel Monasterio2, LI Mingyu1
1 School of Material Science and Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen 518055, China; 2 Institute of Technology for Marine Civil Engineering, Shenzhen Institute of Information Technology, Shenzhen 518172, China;
Abstract: Industrial by-products or solid waste, such as blast furnace slag, coal-combustion fly ash et al., have long been used as supplementary cementitious materials (SCM) in Portland cement and concrete. Utilization of SCM can mitigate the problems caused by cement production, including high energy and natural resources consumption, massive carbon dioxide emission. To reach the desired high replacement levels (beyond 30wt%) of Portland cement without significant performance loss, triggering SCM reactivity is the key. However, from the point of view of material science, the empirical testing approach concerning macroscopic properties led to a quite fragmented understanding of SCM reactivity. In addition to their specific surface area, the hydraulic reactivity of SCM is highly dependent on the dissolution-precipitation reaction of the glass phase within the minerals. The glass structure of SCM can be simply expressed as the molar ratio between network modifer (e.g. Ca, Na) and network former (e.g. Si, Al), such as depolymerization degree in glass chemistry. Recent studies on CaO-SiO2-Al2O3 glass enhance the understanding of the structure in terms of Si(Qn(mAl)) polymerization units. The polymerization degree of the glass, saturation index in the solution, cation/anion species and their concentration and pH determine the dissolution rate of the glass structure. Besides, formation of precipitates changes the dissolution kinetics as well. This review offers a retrospection of the research efforts on the glass structure of SCM in relation to the hydraulic reactivity. The glass structures in terms of depolymerization degree and Si(Qn(mAl)) are presented, respectively. The reactivity of the glass structure under different activation conditions is also elaborated. Therefore, it lays a foundation for the development of the building materials with low-carbon footprint, while stable quality and good durability of the building materials are maintained.
金宇, 冯伟鹏, 董志君, ManuelMonasterio, 李明雨. 辅助胶凝材料玻璃体结构与胶凝活性的研究进展[J]. 材料导报, 2021, 35(3): 3016-3020.
JIN Yu, FENG Weipeng, DONG Zhijun, Manuel Monasterio, LI Mingyu. Research Progress on the Glass Structure of Supplementary Cementitious Materials with Relation to Their Hydraulic Reactivity. Materials Reports, 2021, 35(3): 3016-3020.
Belie N de, Soutsos M, Gruyaert E. Properties of fresh and hardened concrete containing supplementary cementitious materials, Springer, Germany,2018.2 Juenger M C G, Snellings R, Bernal S A.Cement and Concrete Research,2019,122,257.3 Li X, Snellings R, Antoni M, et al.Materials and Structures,2018,51,151.4 Snellings R.RILEM Technical Letters,2016,1,50.5 Avet F, Snellings R, Diaz A A, et al.Cement and Concrete Research,2016,85,1.6 Snellings R, Scrivener K L.Materials and Structures,2016,49(8),3265.7 Skibsted J, Snellings R.Cement and Concrete Research,2019,124,105799.8 Fernandez R, Martirena F, Scrivener K L.Cement and Concrete Research,2011,41(1),113.9 Garg N, Skibsted J.Journal of the American Ceramic Society,2019,291(12),2400.10 Hellmann R, Cotte S, Cadel E, et al.Nature Materials,2015,14(3),307.11 Shimoda K, Tobu Y, Kanehashi K, et al.Journal of Non-Crystalline So-lids,2008,354(10-11),1036.12 Qin Y, Liu H, Yang Y.Metallurgical Research & Technology,2018,115(1),113.13 Liu Y, Lv X, Li B, et al.Ironmaking & Steelmaking,2018,45(6),492.14 Zhang S, Zhang X, Peng H.ISIJ International,2014,54(4),734.15 Liang D, Yan Z, Lv X,et al.Metallurgical and Materials Transactions B,2017,48(1),573.16 Murdoch J B, Stebbins J F, Carmichael I S E.American Mineralogist,1985,70(3-4),332.17 Lee S K, Stebbins J F.American Mineralogist,1999,84(5-6),937.18 Neuville D R, Cormier L, Montouillout V.Journal of Non-Crystalline So-lids,2007,353(2),180.19 Duxson P, Provis J L.Journal of the American Ceramic Society,2008,91(12),3864.20 Oey T, Timmons J, Stutzman P, et al.Journal of the American Ceramic Society,2017,100(10),4785.21 Moesgaard Mette, Keding Ralf, Skibsted J, et al.Chemistry of Materials,2010,22(15),4471.22 Thomsen R M, Skibsted J, Yue Y.The Journal of Physical Chemistry B,2018,122(12),3184.23 Kanehashi K.Solid State Nuclear Magnetic Resonance,2017,84,158.24 Kucharczyk S, Sitarz M, Zajac M, et al.Spectrochimica Acta Part A, Molecular and Biomolecular Spectroscopy,2018,194,163.25 Kucharczyk S, Zajac M, Stabler C, et al.Cement and Concrete Research,2019,120,77.26 Snellings R.Journal of the American Ceramic Society,2013,96(8),2467.27 Snellings R.Journal of the American Ceramic Society,2015,98(1),303.28 Schöler A, Winnefeld F, Ben Haha M, et al.Journal of the American Ceramic Society,2017,100(6),2553.29 Durdziński P T, Snellings R, Dunant C F, et al.Cement and Concrete Research,2015,78,263.30 Xu B, Pu X C.Journal of the Chinese Ceramic Society,1997,25(6),729(in Chinese).徐彬,蒲心诚.硅酸盐学报,1997,25(6),729.31 Li Y, Sun H, Liu X, et al.Science in China Series E: Technological Sciences,2009,52(9),2695.32 Kinnunen P, Sreenivasan H, Cheeseman C R.Journal of Cleaner Production,2019,3(10),126.33 Durdziński P T, Dunant C F, Ben Haha M, et al.Cement and Concrete Research,2015,73,111.34 Newlands K C, Foss M, Matchei T, et al.Journal of the American Cera-mic Society,2017,100(5),1941.35 Walkley B, San Nicolas R, Sani M A, et al.Cement and Concrete Research,2017,99,155.36 Schott J, Pokrovsky O S, Oelkers E H.Reviews in Mineralogy and Geochemistry,2009,70(1),207.37 Chave T, Frugier P, Gin S, et al.Geochimica et Cosmochimica,2011,75(15),4125.38 Newlands K C, Macphee D E.Advances in Applied Ceramics,2017,116(4),216.39 Riding K, Silva D A, Scrivener K.Cement and Concrete Research,2010,40(6),935.40 Fleury B, Godon N, Ayral A, et al.Journal of Nuclear Materials,2013,442(1-3),17.41 Suraneni P, Palacios M, Flatt R J.Cement and Concrete Research,2016,79,209.42 Gruskovnjak A, Lothenbach B, Winnefeld F, et al.Cement and Concrete Research,2008,38(7),983.43 Whittaker M, Zajac M, Ben Haha M, et al.Cement and Concrete Research,2014,66,91.44 Fernández-Jiménez A, Garcia-Lodeiro I, Maltseva O, et al.Journal of the American Ceramic Society,2019,102(5),427.45 Alahrache S, Winnefeld F, Champenois J B, et al.Cement and Concrete Composites,2016,66,10.46 García-Lodeiro I, Fernández-Jiménez A, Palomo A.Cement and Concrete Composites,2013,52,112.47 García-Lodeiro I, Donatello S, Fernández-Jiménez A, et al.Materials,2016,9,605.48 Matschei T, Lothenbach B, Glasser F P.Cement and Concrete Research,2007,37(4),551.
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2021, Vol. 35 
