Abstract: The macroscopic properties of asphalt are closely related to its chemical composition and microstructure, which is an important consideration for selecting the proper asphalt when designing a pavement. The research on the correlation between asphalt properties and chemical characteristic has always been a hot topic for researchers. In this paper, we summarize the recent research on the relationship between the macroscopic properties and the microscopic chemical composition of asphalt, and introduce about the chemical composition, molecular interaction, the microscopic structure model, the qualitative relationship studies and mathematical relationship models between the properties and the chemical composition of asphalt. Furthermore, the effects of fraction composition, polarity, heteroatomic content, characteristic functional groups, molecular weight and aromaticity on asphalt properties are analyzed. Finally, we prospect the future development direction and research hotspot of the field. This work provides a reference for the research of asphalt genomics, modification and upgrading, recycling and performance prediction.
吴偲, 范思远, 王兆程, 韩照明. 沥青宏观性能与微观化学组成关系的研究进展[J]. 材料导报, 2023, 37(S1): 23020053-5.
WU Cai, FAN Siyuan, WANG Zhaocheng, HAN Zhaoming. Research Progress on the Relationship Between Macroscopic Properties and Microscopic Chemical Composition of Asphalt. Materials Reports, 2023, 37(S1): 23020053-5.
1 Wang C H. Petroleum Refining and Chemical Industry, 2019, 50(2), 36 (in Chinese). 王翠红. 石油炼制与化工, 2019, 50(2), 36. 2 Roopashree M S, Singh D, Showkat B. Construction and Building Materials, 2020, 258(3), 120338. 3 Hou X, Lv S, Chen Z, et al. Measurement, 2018, 121, 304. 4 Ma J, Sun G, Sun D, et al. Construction and Building Materials, 2021, 278, 122386. 5 Qian S A, Li C F, Zhang P Z. Fuel, 1984, 63(2), 268. 6 Dickie J P, Yen T F. Analytical Chemistry, 1967, 39(14), 1847. 7 Shan L, Xie R, Wanger N J, et al. Fuel, 2019, 253, 1589. 8 Zhang E, Shan L, Qi X, et al. Construction and Building Materials, 2022, 343, 128001. 9 Lesueur D. Advances in Colloid & Interface Science, 2009, 145(1-2), 42. 10 Yun B, Sui H, Liu X, et al. Fuel, 2019, 240, 252. 11 Silva H S, Sodero A C R, Bouyssiere B, et al. Energy & Fuels, 2016, 30(7), 5656. 12 Green J B, Yu S K T, Pearson C D, et al. Energy & Fuels, 1993, 7(1), 119. 13 Tauste R, Moreno-Navarro F, Sol-Sánchez M, et al. Construction and Building Materials, 2018, 192, 593. 14 Santos R G, Loh W, Bannwart A C, et al. Brazilian Journal of Chemical Engineering, 2014, 31(3), 571. 15 Petersen J C, RobertsonR E, Branthaver J F, et al. Binder characterization and evaluation: Volume 1. No. SHRP-A-367, National Research Council, Washington DC, 1994. 16 Wang Y, Wang W, Wang L. Construction and Building Materials, 2022, 329, 127161. 17 Boussingault J. Comptes Rendus de l'Académie des Sciences, 1836, 3, 375. 18 Richardson C. The modern asphalt pavement, John Wiley and Sons, New York, 1905. 19 Corbett L W. Analytical Chemistry, 1969, 41(4), 576. 20 Zhang M, Hao P, Dong S, et al. Measurement, 2019, 151, 107255. 21 Guo M, Liang M, Fu Y, et al. Materials and Structures, 2021, 54(4), 1. 22 Zhou X L, Chen S Z, Chang K Y. Journal of East China University of Science and Technology: Natural Science Edition, 1995, 21(6), 649 (in Chinese). 周晓龙, 陈绍洲, 常可怡. 华东理工大学学报:自然科学版, 1995, 21(6), 649. 23 Feng Z G, Zhang J B, Li X J, et al. Chromatography, 2015, 33(2), 195 (in Chinese). 冯振刚, 张建宾, 李新军, 等. 色谱, 2015, 33(2), 195. 24 Bisht H, Reddy M, Malvanker M, et al. Energy & Fuels, 2013, 27(6), 3006. 25 Zhang C M, Li A Y, Shen Z M, et al. Analytical Chemistry, 1986, 14(3), 161 (in Chinese). 张昌鸣, 李爱英, 沈曾民, 等. 分析化学, 1986, 14(3), 161. 26 Liang H, Tian S B, Zhu X Y, et al. Acta Petrolei Sinica (Petroleum Processing Section), 2011, 27(4), 634 (in Chinese). 梁欢, 田松柏, 祝馨怡, 等. 石油学报(石油加工), 2011, 27(4), 634. 27 Redelius P. Road Materials and Pavement Design, 2009, 10, 25. 28 Riazi M R, Roomi Y A. Industrial & Engineering Chemistry Research, 2001, 40(8), 1975. 29 Wanger J P, Schreiner P R. Angewandte Chemie International Edition, 2015, 54(42), 12274. 30 Hunter C A, Sanders J K M. Journal of the American Chemical Society, 1990, 112(14), 5525. 31 Grimme S. Angewandte Chemie International Edition, 2008, 47(18), 3430. 32 Redelius P, Soenen H. Fuel, 2015, 140(15), 34. 33 Redelius P, Soenen H. Road Materials and Pavement Design, 2005, 6(3), 385. 34 Yen T F. Energy Sources, 1974, 1(4), 447. 35 Strausz O P, Mojelsky T W, Lown E M. Fuel, 1992, 71(12), 1355. 36 Eyssautier J, Levitz P, Espinat D, et al. Journal of Physical Chemistry B, 2011, 115(21), 6827. 37 Rosinger V A. Kolloid-Zeitschrift, 1914, 15(5), 177. 38 Nellensteyn F J. Journal of Petroleum Technology, 1924, 10, 311. 39 Mack C. The Journal of Physical Chemistry, 2002, 36(12), 2901. 40 Pfeiffer J P, Saal R N J. The Journal of Physical Chemistry, 1940, 44(2), 139. 41 Saal R N J, Labout J W A. The Journal of Physical Chemistry, 1940, 44(2), 149. 42 Broome D C. Nature, 1964, 202(4934), 739. 43 Gaestel C, Smadia R, Lamminan K A. Revue Générale des Routes et des Aérodromes, 1971, 466, 85. 44 Oyekunle L O. Oil & Gas Science and Technology-Revue d'IFP Energies Nouvelles, 2006, 61(3), 433. 45 Yen T F. Fuel Science & Technology International, 1992, 10(4-6), 723. 46 Yen T F. In: Pan-Pacific Synfuels Conference. Tokyo, 1982, pp.547. 47 Mullins O C. Energy & Fuels, 2010, 24(4), 2179. 48 Barre L, Espinat D, Rosenberg E, et al. Oil & Gas Science & Technology, 1997, 52(2), 161. 49 Barre L, Jestin J, Morisset A, et al. Oil & Gas Science & Technology, 2009, 64(5), 617. 50 Tan Y Q, Li G N, Shan L Y, et al. Journal of Traffic and Transportation Engineering, 2020, 20(6), 1 (in Chinese). 谭忆秋, 李冠男, 单丽岩, 等. 交通运输工程学报, 2020, 20(6), 1. 51 Redelius P. Hansen solubility parameters: a user's handbook, 2007, pp.151. 52 Redelius P. Fuel, 2000, 79(1), 27. 53 Redelius P. Energy & Fuels, 2004, 18(4), 1087. 54 O'Donnell G, Snider L T, Rietz E G. Analytical Chemistry, 1951, 23(6), 894. 55 Simpson W C, Griffin R L, Miles T K. Journal of Chemical and Engineering Data, 1961, 6(3), 426. 56 Chen H X, He M S, Ji X H, et al. Journal of Chang'an University: Natural Science Edition, 2014, 34(3), 1 (in Chinese). 陈华鑫, 贺孟霜, 纪鑫和, 等. 长安大学学报:自然科学版, 2014, 34(3), 1. 57 Dealy J M. The Canadian Journal of Chemical Engineering, 1979, 57(6), 677. 58 Christensen R J, Lindberg W R, Dorrence S M. Fuel, 1984, 63(9), 1312. 59 Zenke G. Bitumen, 1977, 6, 175. 60 Weigel S, Stephan D. Road Materials and Pavement Design, 2018, 19(7), 1636. 61 Luo P, Gu Y. Fuel, 2007, 86(7-8), 1069. 62 Robertson R E. Chemical properties of asphalts and their relationship to pavement performance, National Research Council, Washington DC, 1991. 63 Michalica P, Kazatchkov I B, Stastna J, et al. Fuel, 2008, 87(15-16), 3247. 64 Sultana S, BhasinA. Construction and Building Materials, 2014, 72, 293. 65 Bukka K, Miller J D, Oblad A G. Energy & Fuels, 1991, 5(2), 333. 66 Bukka K, Miller J D, Hanson F V, et al. Fuel, 1994, 73(2), 257. 67 Pauli A T, Huang S C. International Journal of Pavement Research and Technology, 2013, 6(1), 1. 68 Maharaj R. International Journal of Applied Chemistry, 2009, 5(3), 169. 69 Branthaver J F, Petersen J C, Robertson R E, et al. SHRP-A-368 Binder characterization and evaluation: vol. 2—chemistry, National Research Council, Washington DC, 1993. 70 Salehfard R, Behbahani H, Dalmazzo D, et al. Construction and Buil-ding Materials, 2021, 281, 122563. 71 Kang J Q. Study on correlation between chemical structure and macroscopic properties of asphalt. Master's Thesis, China University of Petroleum (East China), 2015 (in Chinese). 康剑翘. 沥青化学组成结构与宏观性质关联关系研究. 硕士学位论文, 中国石油大学(华东), 2015. 72 Wang J, Wang T, Hou X, et al. Fuel, 2019, 238, 320. 73 Wang T, Wang J, Hou X, et al. Road Materials and Pavement Design, 2021, 22(3), 539. 74 Kim K W, Burati J L, Park J S. Journal of Materials in Civil Engineering, 1995, 7(1), 31. 75 Lu X, Isacsson U. Construction and Building Materials, 2002, 16(1), 15. 76 Stangl K. Linking chemical and physical characteristics with mechanical performance of bitumen, TU Wien, 2010. 77 Weigel S, Stephan D. Materials and Structures, 2017, 50(1), 1. 78 Zhao K C, Wang Y H, Yang Z. Journal of Highway and Transportation Science and Technology, 2021, 38(5), 10 (in Chinese). 赵可成, 王予红, 杨震. 公路交通科技, 2021, 38(5), 10.