Abstract: Molybdenum carbide is formed when carbon atoms are introduced into the crystal lattice of molybdenum. This kind of mesenchymal structure has unique physical and chemical properties. This material has excellent catalytic activity in hydrogenation reaction and hydrogen production reaction, and its catalytic performance can be compared with platinum and palladium. Molybdenum carbide has active chemical properties, so the synthesis method and experimental conditions closely affect the physical and chemical properties of the final product. Small changes in the reaction materials and experimental conditions may result in changes in the crystal phase structure, grain size, and specific surface area of molybdenum carbide, thus changing the catalytic performance of the material. This paper reviews the research progress of molybdenum carbide. The crystalline phase types and spatial structure of several typical molybdenum carbides are introduced, the electronic properties affecting the structure of molybdenum carbide are analyzed, the synthetic strategies of molybdenum carbide are summarized systematically, and the advantages and disadvantages of different preparation methods are pointed out. Ta-king programmed temperature carbonization as an example, the growth mechanism is emphatically analyzed, and the influence and importance of preparation conditions on the final synthetic material are discussed from three aspects: final temperature of carbonization, heating rate, and carbon source concentration. The applications of molybdenum carbide in hydrogenation reaction, hydrogen production reaction, sensor, and biomedical materials are reviewed. The catalytic mechanism and improvement strategy of molybdenum carbide in electrocatalytic hydrogen evolution and CO2 hydroconversion are introduced in detail. Finally, based on the existing challenges, the future development direction of molybdenum carbide material is further proposed.
通讯作者:
*魏强,中国石油大学(北京)化学工程与环境学院教授、博士研究生导师。2001年7月本科毕业于山东大学,2009年中国石油大学(北京)化学工程与技术专业博士毕业。主要研究方向为重质油加工、清洁油品生产。获发明专利授权10余项,在国内外发表论文30余篇,包括Journal of Catalysis、Energy & Fuels、Catalysis Today、Fuel Processing Technology、Frontiers of Chemical Science and Enginee-ringis、Journal of Fuel Chemistry & Technology等。qwei@cup.edu.cn
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2024, Vol. 38 
