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材料导报  2024, Vol. 38 Issue (4): 22070108-9    https://doi.org/10.11896/cldb.22070108
  无机非金属及其复合材料 |
基于缺陷工程改性富锂层状材料的研究现状
陈艳丽1,2, 解自奇1, 王梦真1, 马子晗1, 李姗姗1, 颜文超1,*, 李法强1
1 临沂大学材料科学与工程学院,山东 临沂 276000
2 菲律宾克里斯汀大学国际学院,菲律宾 马尼拉 1004
Research Status of Li-rich Layered Materials Based on Defect Engineering
CHEN Yanli1,2, XIE Ziqi1, WANG Mengzhen1, MA Zihan1, LI Shanshan1, YAN Wenchao1,*, LI Faqiang1
1 School of Materials Science and Engineering, Linyi University, Linyi 276000, Shandong, China
2 Philippine Christian University Center for International Education, Manila 1004, Philippine
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摘要 随着长续航纯电动汽车的快速发展,开发高能量密度和低成本的动力电池成为影响其发展的重要因素。富锂层状材料具有高的能量密度和低的成本,有望成为下一代商业化正极材料,但循环过程中层状结构向尖晶石结构转变导致电压和容量快速衰减,限制了其商业化的应用。针对上述问题,本文介绍了富锂层状材料的晶体结构、充放电机制、电压和容量衰减产生机理,基于缺陷工程角度综述了改性方法,最后对富锂层状材料的发展进行了展望。
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陈艳丽
解自奇
王梦真
马子晗
李姗姗
颜文超
李法强
关键词:  富锂层状材料  晶体结构  充放电机制  空位缺陷  离子掺杂    
Abstract: With the rapid development of long-range electric vehicles, the development of high-energy-density and low-cost power batteries has become an important factor. Li-rich layered materials, with high energy density and low cost, are expected to be the next-generation commercial cathode materials. Nevertheless, the rapid voltage and capacity attenuation, caused by the transformation from the layered structure to the spinel structure during charge/discharge processes, limited their commercial applications. In regard to these challenges the crystal structure, charge-discharge mechanism, fading mechanism of voltage and capacity of Li-rich layered materials are summarized, and the modification me-thods from the perspective of defect engineering are discussed as well in this paper. Finally, the outlook for future development of Li-rich layered materials is given.
Key words:  Li-rich layered material    crystal structure    charge-discharge mechanism    vacancy defect    ions doping
出版日期:  2024-02-25      发布日期:  2024-03-01
ZTFLH:  TM912.9  
基金资助: 国家自然科学基金(21905124)
通讯作者:  *颜文超,临沂大学材料科学与工程学院副教授、硕士研究生导师。2016年12月毕业于中国科学院青岛生物能源与过程研究所化学工程专业,博士毕业后在该所进行博士后研究。2018年10月进入临沂大学工作至今。目前主要从事高性能锂离子电池正极材料包括富锂层状材料、镍锰酸锂和高镍三元材料设计及改性研究。目前主持国家级和省部级项目2项,发表论文20余篇,包括Journal of Power Sources、ACS Sustainable Chemistry & Engineering、Journal of Alloys and Compounds、Electrochimica Acta、Ceramics International等。yanwenchao@lyu.edu.cn   
作者简介:  陈艳丽,2013年7月于西南大学获得理学硕士学位。现为临沂大学-菲律宾克里斯汀大学国际学院联合培养博士研究生,在李法强教授的指导下进行研究。目前主要研究领域为高性能锂离子电池正极材料的制备及改性。
引用本文:    
陈艳丽, 解自奇, 王梦真, 马子晗, 李姗姗, 颜文超, 李法强. 基于缺陷工程改性富锂层状材料的研究现状[J]. 材料导报, 2024, 38(4): 22070108-9.
CHEN Yanli, XIE Ziqi, WANG Mengzhen, MA Zihan, LI Shanshan, YAN Wenchao, LI Faqiang. Research Status of Li-rich Layered Materials Based on Defect Engineering. Materials Reports, 2024, 38(4): 22070108-9.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22070108  或          http://www.mater-rep.com/CN/Y2024/V38/I4/22070108
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