基于缺陷工程改性富锂层状材料的研究现状

doi:10.11896/cldb.22070108

材料导报

2024, Vol. 38

Issue (4): 22070108-9 https://doi.org/10.11896/cldb.22070108

无机非金属及其复合材料

基于缺陷工程改性富锂层状材料的研究现状

陈艳丽^1,2, 解自奇¹, 王梦真¹, 马子晗¹, 李姗姗¹, 颜文超^1,*, 李法强¹

1 临沂大学材料科学与工程学院,山东临沂 276000
2 菲律宾克里斯汀大学国际学院,菲律宾马尼拉 1004

Research Status of Li-rich Layered Materials Based on Defect Engineering

CHEN Yanli^1,2, XIE Ziqi¹, WANG Mengzhen¹, MA Zihan¹, LI Shanshan¹, YAN Wenchao^1,*, LI Faqiang¹

1 School of Materials Science and Engineering, Linyi University, Linyi 276000, Shandong, China
2 Philippine Christian University Center for International Education, Manila 1004, Philippine

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摘要随着长续航纯电动汽车的快速发展,开发高能量密度和低成本的动力电池成为影响其发展的重要因素。富锂层状材料具有高的能量密度和低的成本,有望成为下一代商业化正极材料,但循环过程中层状结构向尖晶石结构转变导致电压和容量快速衰减,限制了其商业化的应用。针对上述问题,本文介绍了富锂层状材料的晶体结构、充放电机制、电压和容量衰减产生机理,基于缺陷工程角度综述了改性方法,最后对富锂层状材料的发展进行了展望。

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	陈艳丽
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	马子晗
	李姗姗
	颜文超
	李法强

关键词: 富锂层状材料晶体结构充放电机制空位缺陷离子掺杂

Abstract: With the rapid development of long-range electric vehicles, the development of high-energy-density and low-cost power batteries has become an important factor. Li-rich layered materials, with high energy density and low cost, are expected to be the next-generation commercial cathode materials. Nevertheless, the rapid voltage and capacity attenuation, caused by the transformation from the layered structure to the spinel structure during charge/discharge processes, limited their commercial applications. In regard to these challenges the crystal structure, charge-discharge mechanism, fading mechanism of voltage and capacity of Li-rich layered materials are summarized, and the modification me-thods from the perspective of defect engineering are discussed as well in this paper. Finally, the outlook for future development of Li-rich layered materials is given.

Key words: Li-rich layered material crystal structure charge-discharge mechanism vacancy defect ions doping

出版日期: 2024-02-25 发布日期: 2024-03-01

ZTFLH:

TM912.9

基金资助: 国家自然科学基金(21905124)

通讯作者: *颜文超,临沂大学材料科学与工程学院副教授、硕士研究生导师。2016年12月毕业于中国科学院青岛生物能源与过程研究所化学工程专业,博士毕业后在该所进行博士后研究。2018年10月进入临沂大学工作至今。目前主要从事高性能锂离子电池正极材料包括富锂层状材料、镍锰酸锂和高镍三元材料设计及改性研究。目前主持国家级和省部级项目2项,发表论文20余篇,包括Journal of Power Sources、ACS Sustainable Chemistry & Engineering、Journal of Alloys and Compounds、Electrochimica Acta、Ceramics International等。yanwenchao@lyu.edu.cn

作者简介: 陈艳丽,2013年7月于西南大学获得理学硕士学位。现为临沂大学-菲律宾克里斯汀大学国际学院联合培养博士研究生,在李法强教授的指导下进行研究。目前主要研究领域为高性能锂离子电池正极材料的制备及改性。

引用本文:

陈艳丽, 解自奇, 王梦真, 马子晗, 李姗姗, 颜文超, 李法强. 基于缺陷工程改性富锂层状材料的研究现状[J]. 材料导报, 2024, 38(4): 22070108-9.
CHEN Yanli, XIE Ziqi, WANG Mengzhen, MA Zihan, LI Shanshan, YAN Wenchao, LI Faqiang. Research Status of Li-rich Layered Materials Based on Defect Engineering. Materials Reports, 2024, 38(4): 22070108-9.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.22070108 或 https://www.mater-rep.com/CN/Y2024/V38/I4/22070108

1 Wang N, Chen Y L, Yin J, et al. Journal of Alloys and Compounds, 2022, 900, 163549.
2 Potr S, uek L, Martin M, et al. Renewable and Sustainable Energy Reviews, 2021, 146, 111186.
3 Zhang H, Zhang J. eTransportation, 2021, 7, 100105.
4 Chen J, Huang Z, Zeng W, et al. ChemElectroChem, 2021, 8, 608.
5 Yin S, Deng W, Chen X, et al. Nano Energy, 2021, 83, 105854.
6 Mauler L, Duffner F, Zeier W G, et al. Energy & Environmental Science, 2021, 14, 4712.
7 Yan W C, Xie Y, Jiang J C, et al. ACS Sustainable Chemistry & Engineering, 2018, 6, 4625.
8 Liu J, Wang J, Ni Y, et al. Materials Today, 2021, 43, 132.
9 Cui S L, Gao M Y, Li G R, et al. Advanced Energy Materials, 2021, 12, 2003885.
10 Hu S, Pillai A S, Liang G, et al. Electrochemical Energy Reviews, 2019, 2, 277.
11 Kang R T, Xiao J, Sun Y N, et al. Journal of Liaocheng University (Nat. Sci), 2021, 34(19), 49(in Chinese).
康若彤, 肖晶, 孙一诺, 等. 聊城大学学报(自然科学版), 2021, 34(19), 49.
12 Liu S, Wang B, Zhang S, et al. Matter, 2021, 4, 1511.
13 Zhang K, Li B, Zuo Y, et al. Electrochemical Energy Reviews, 2019, 2, 606.
14 Zhao S Q, Yan K, Zhang J Q, et al. Angewandte Chemie-International Edition, 2021, 60, 2208.
15 Chang W, Kim S J, Park B W, et al. Journal of Alloys and Compounds, 2013, 563, 249.
16 Koyama Y, Tanaka I, Adachi H, et al. Journal of Power Sources, 2003, 119, 644.
17 Ceder G, Mishra S K. Electrochemical and Solid-State Letters, 1999, 2, 550.
18 Boulineau A, Croguennec L, Delmas C, et al. Chemistry of Materials, 2009, 21, 4216.
19 Thackeray M M, Kang S H, Johnson C S, et al. Electrochemistry Communications, 2006, 8, 1531.
20 Kim J S, Johnson C S, Vaughey J T, et al. Chemistry of Materials, 2004, 16, 1996.
21 Thackeray M M, Kang S H, Johnson C S, et al. Journal of Materials Chemistry, 2007, 17, 3112.
22 Armstrong A R, Holzapfel M, Novák P, et al. Journal of the American Chemical Society, 2006, 128, 8694.
23 Xu B, Fell C R, Chi M, et al. Energy & Environmental Science, 2011, 4, 2223.
24 Gu M, Belharouak I, Zheng J, et al. ACS Nano, 2013, 7, 760.
25 Sathiya M, Abakumov A M, Foix D, et al. Nature Materials, 2015, 14, 230.
26 Hu E, Yu X, Lin X, et al. Nature Energy, 2018, 3, 690.
27 Li G, Blake G R, Palstra T T M. Chemical Society Reviews, 2017, 46, 1693.
28 Jiao S, Fu X, Zhang L, et al. Nano Today, 2020, 31, 100833.
29 Zhang Y, Xu J, Long Y, et al. ChemNanoMat, 2020, 6, 1589.
30 Seo D H, Lee J, Urban A, et al. Nature Chemistry, 2016, 8, 692.
31 Li S, Zhang H, Li H, et al. ACS Applied Materials & Interfaces, 2021, 13, 39480.
32 Liu P, Zhang H, He W, et al. Journal of the American Chemical Society, 2019, 141, 10876.
33 Nakamura T, Ohta K, Kimura Y, et al. ACS Applied Energy Materials, 2020, 3, 9703.
34 Tang Z K, Xue Y F, Teobaldi G, et al. Nanoscale Horizons, 2020, 5, 1453.
35 Qiu B, Zhang M, Wu L, et al. Nature Communications, 2016, 7, 12108.
36 Wang Z, Lin X, Zhang J, et al. Journal of Power Sources, 2020, 462, 228171.
37 Bao L, Wei L, Fu N, et al. Journal of Energy Chemistry, 2022, 66, 123.
38 Qian D, Xu B, Chi M, et al. Physical Chemistry Chemical Physics, 2014, 16, 14665.
39 He W, Yuan D, Qian J, et al. Journal of Materials Chemistry A, 2013, 1, 11397.
40 Li Q, Li G, Fu C, et al. ACS Applied Materials & Interfaces, 2014, 6, 10330.
41 Yu H, Zhou H. The Journal of Physical Chemistry Letters, 2013, 4, 1268.
42 Zhao S, Guo Z P, Yan K, et al. Energy Storage Materials, 2021, 34, 716.
43 Xu Y, Cui Q. International Journal of Electrochemical Science, 2020, 15, 803.
44 Dong S, Zhou Y, Hai C, et al. Journal of Power Sources, 2020, 462, 228185.
45 Boulineau A, Simonin L, Colin J F, et al. Nano Letters, 2013, 13, 3857.
46 Shi J L, Zhang J N, He M, et al. ACS Applied Materials & Interfaces, 2016, 8, 20138
47 Shi J L, Xiao D D, Ge M, et al. Advanced Materials, 2018, 30, 1705575.
48 Hy S, Cheng J H, Liu J Y, et al. Chemistry of Materials, 2014, 26, 6919.
49 Abdellahi A, Urban A, Dacek S, et al. Chemistry of Materials, 2016, 28, 3659.
50 Li Q, Li G, Fu C, et al. ACS Applied Materials & Interfaces, 2014, 6, 10330.
51 Yu R, Wang X, Fu Y, et al. Journal of Materials Chemistry A, 2016, 4, 4941.
52 Feng X, Gao Y, Ben L, et al. Journal of Power Sources, 2016, 317, 74.
53 Zhang X, Xiong Y, Dong M, et al. Journal of the Electrochemical Society, 2019, 166, A2960.
54 Li N, An R, Su Y, et al. Journal of Materials Chemistry A, 2013, 1, 9760.
55 Yu R, Wang G, Liu M, et al. Journal of Power Sources, 2016, 335, 65.
56 Wu F, Kim G T, Kuenzel M, et al. Advanced Energy Materials, 2019, 9, 1902445.
57 Wang M, Han Y, Chu M, et al. Journal of Alloys and Compounds, 2021, 861, 158000.
58 Shang H, Ning F, Li Y, et al. ACS Applied Materials & Interfaces, 2018, 10, 21349.
59 He Z, Wang Z, Chen H, et al. Journal of Power Sources, 2015, 299, 334.
60 Zhao Y, Xia M, Hu X, et al. Electrochimica Acta, 2015, 174, 1167.
61 Zhang N, Sun Y, Zhao L, et al. Ionics, 2019, 25, 5239.
62 Yu Z, Ning F, Li B. et al. The Journal of Physical Chemistry C, 2019, 123, 18870.
63 Meng S, Xie Y, Yan W C, et al. Journal of Alloys and Compounds, 2020, 838, 155517.
64 Li L, Song B H, Chang Y L, et al. Journal of Power Sources, 2015, 283, 162.
65 Sun Z, Xu L, Dong C, et al. Nano Energy, 2019, 63, 103887.
66 Li B, Yan H, Ma J, et al. Advanced Functional Materials, 2014, 24, 5112.
67 Zhao Y, Liu J, Wang S, et al. Advanced Functional Materials, 2016, 26, 4760.
68 Wang E, Xiao D, Wu T, et al. Advanced Functional Materials, DOI:10. 1002/adfm. 202201744.
69 Liang Y, Li S, Xie J, et al. New Journal of Chemistry, 2019, 43, 12004.
70 Yang J, Chen Y, Li Y, et al. ACS Applied Materials & Interfaces, 2021, 13, 25981.
71 Hu Y Y, Qin Z Z, Cong B W, et al. Chemelectrochem, 2021, 8, 2315.
72 Zheng H, Zhang C, Zhang Y, et al. Advanced Functional Materials, 2021, 31, 2100783.
73 Zhang P P, Zhai X H, Huang H, et al. Ceramics International, 2020, 46, 24723.
74 Liu D, Fan X, Li Z, et al. Nano Energy, 2019, 58, 786.
75 Chen G, An J, Meng Y, et al. Nano Energy, 2019, 57, 157.
76 Zhang Z H, Xie X Y, Xie H X, et al. Chinese Journal of Structural Chemistry, 2022, 41, 2204061.
77 Jiang W J, Zhang C X, Feng Y Z, et al. Energy Storage Materials, 2020, 32, 37.
78 Tang W, Duan J, Xie J, et al. ACS Applied Materials & Interfaces, 2021, 13, 16407.
79 Liu H, He B, Xiang W, et al. Nanotechnology, 2020, 31, 455704.
80 Saroha R, Cho J S, Ahn J H, et al. Electrochimica Acta, 2021, 366, 137471.

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