具有高热稳定性Sm3+激活硼磷酸盐Na3B6PO13橙红色荧光粉的发光特性

doi:10.11896/cldb.23080106

材料导报

2024, Vol. 38

Issue (21): 23080106-6 https://doi.org/10.11896/cldb.23080106

无机非金属及其复合材料

具有高热稳定性Sm³⁺激活硼磷酸盐Na₃B₆PO₁₃橙红色荧光粉的发光特性

刘雨昕, 胡倩, 粟茵, 文麒麟, 刘丽欣, 覃钺, 梁露露, 张宏志^*, 朱静^*

云南大学材料与能源学院,昆明 650000

Luminescence Properties of Sm³⁺-activated Borophosphate Na₃B₆PO₁₃ Orange-red Phosphor with High Thermostability

LIU Yuxin, HU Qian, SU Yin, WEN Qilin, LIU Lixin, QIN Yue, LIANG Lulu, ZHANG Hongzhi^*, ZHU Jing^*

School of Materials and Energy, Yunnan University, Kunming 650000, China

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摘要选用硼磷酸盐Na₃B₆PO₁₃作为基质,采用高温固相法合成Sm³⁺激活橙红光荧光粉。利用X射线衍射、扫描电子显微镜和发光光谱等技术手段研究了荧光粉的晶体结构、微观形貌及发光性能。光谱测试结果表明,Na₃B₆PO₁₃:9%Sm³⁺的光谱强度最强,9%为最佳掺杂浓度,激发光谱峰值主要位于402 nm处,对应Sm³⁺的⁶H_5/2→⁴F_7/2跃迁;发射峰主要位于599 nm与646 nm处,分别对应Sm³⁺的⁴G_5/2→⁴H_7/2、⁶H_9/2跃迁,而后随着掺杂浓度升高发生浓度猝灭现象,猝灭机制为电偶极-电四极相互作用。Na₃B₆PO₁₃:9%Sm³⁺的色坐标为(0.559 1,0.431 7),发光呈橙红色。发光热稳定性测试结果表明,样品在150 ℃时仍能保持室温下发光强度的90%。以上研究结果表明Na₃B₆PO₁₃: Sm³⁺可作为橙红色荧光粉候选材料。

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	刘雨昕
	胡倩
	粟茵
	文麒麟
	刘丽欣
	覃钺
	梁露露
	张宏志
	朱静

关键词: 硼磷酸盐 Sm³⁺掺杂橙红光晶体结构

Abstract: In this work, borophosphate Na₃B₆PO₁₃ was used as substrate to synthesize Sm³⁺ activated orange-red phosphor by high temperature solid phase method. The crystal structure, microscopic morphology and luminescence properties of phosphors were studied by X-ray diffraction, scanning electron microscopy, and luminescence measurements. Na₃B₆PO₁₃:9%Sm³⁺ has the strongest spectral intensity and the best doping concentration, the peak value of excitation spectrum is 402 nm, corresponding to the ⁶H_5/2→⁴F_7/2 transition. The emissions at 599 nm and 646 nm correspond to the ⁴G_5/2→⁴H_7/2 and ⁶H_9/2 transitions, separately. The concentration quenching occurs with the increase of doping concentration, which is caused by the electric dipole-quadrupole interaction. The color coordinates of Na₃B₆PO₁₃:9%Sm³⁺ are (0.559 1, 0.431 7), corresponding to orange-red color. The temperature-dependent luminescence shows that the sample at 150℃ maintains 90% of the luminescence intensity at room temperature. The above results indicate that Na₃B₆PO₁₃: Sm³⁺ phosphor is a promising orange-red phosphor material.

Key words: borophosphate Sm³⁺ doping orange-red luminescence crystal structure

出版日期: 2024-11-10 发布日期: 2024-11-11

ZTFLH:

O469

基金资助: 国家自然科学基金 (22165031);国家大学生创新创业训练 (202310673024)

通讯作者: *张宏志,云南大学材料与能源学院博士后。2014年兰州大学材料物理专业本科毕业,2018年中南林业科技大学化学工程与技术专业硕士毕业,2022年中南大学材料科学与工程专业博士毕业。目前主要从事无机发光材料方面的研究工作。以第一或通信作者发表论文8篇,包括Chemical Engineering Journal、Advanced Optical Materials、ACS Sustainable Chemistry & Engineering、Journal of Materials Chemistry C等。zhanghz@ynu.edu.cn;
朱静,云南大学材料与能源学院教授、博士研究生导师。2001年西安理工大学材料系材料科学与工程专业本科毕业,2004年西安理工大学材料系材料学专业硕士毕业,2007年中国科学院福建物质结构研究所无机化学专业毕业后到云南大学工作至今。目前从事稀土发光材料节能照明显示、光伏新能源用新型稀土发光材料研究工作。发表论文80余篇,包括Journal of Advanced Ceramics、Ceramics International、Applied Materials Today、Dalton Transactions等。jzhu@ynu.edu.cn

作者简介: 刘雨昕,2022年9月于云南大学获得工学学士学位。现为云南大学材料与能源学院硕士研究生,在朱静教授的指导下进行研究。目前主要研究领域为稀土发光材料。

引用本文:

刘雨昕, 胡倩, 粟茵, 文麒麟, 刘丽欣, 覃钺, 梁露露, 张宏志, 朱静. 具有高热稳定性Sm³⁺激活硼磷酸盐Na₃B₆PO₁₃橙红色荧光粉的发光特性[J]. 材料导报, 2024, 38(21): 23080106-6.
LIU Yuxin, HU Qian, SU Yin, WEN Qilin, LIU Lixin, QIN Yue, LIANG Lulu, ZHANG Hongzhi, ZHU Jing. Luminescence Properties of Sm³⁺-activated Borophosphate Na₃B₆PO₁₃ Orange-red Phosphor with High Thermostability. Materials Reports, 2024, 38(21): 23080106-6.

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http://www.mater-rep.com/CN/10.11896/cldb.23080106 或 http://www.mater-rep.com/CN/Y2024/V38/I21/23080106

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