聚吡咯纳米复合材料的研究进展

doi:10.11896/cldb.21110151

材料导报

2023, Vol. 37

Issue (9): 21110151-10 https://doi.org/10.11896/cldb.21110151

高分子与聚合物基复合材料

聚吡咯纳米复合材料的研究进展

郝璐, 于德梅^*

西安交通大学化学学院,西安 710049

Research Progress in Polypyrrole Nanocomposites

HAO Lu, YU Demei^*

School of Chemistry, Xi'an Jiaotong University, Xi'an 710049, China

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摘要聚吡咯具有较大的比电容、较高的电导率、较好的化学稳定性等诸多优点,被认为是最有可能实现工业化生产的导电聚合物。然而,常规块状聚吡咯通常在电学、光学和生物学特性方面存在不足,而纳米结构聚吡咯由于明确的纳米结构和更大的表面积,具有特殊的电化学活性、改善的光学性能和良好的生物相容性。此外,面对日新月异的科技发展,单一的聚吡咯纳米材料已经不足以应对各方面的应用需求,而聚吡咯纳米复合材料保留了单个组分的功能以及与其他功能材料集成时的协同效应,可以同时具备几种材料各自的优点,从而大大拓宽聚吡咯的应用范围。本文综述了聚吡咯纳米复合材料的研究进展,介绍了五种类型的聚吡咯纳米复合材料,基于其优异的导电性和可逆的氧化还原等性能,结合近几年的文献,介绍了聚吡咯纳米复合材料在储能、生物医学、吸附和杂质去除、电催化、吸波材料、传感器和腐蚀防护领域的应用,最后展望了这一研究领域目前所面临的挑战和机遇。

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	郝璐
	于德梅

关键词: 聚吡咯纳米复合物储能生物医药

Abstract: Due to its large specific capacitance, high electrical conductivity, chemical stability and many other advantages, polypyrrole is considered to be the most likely conductive polymer for industrialization. However, bulk polypyrrole is usually deficient in electrical, optical and biological properties, while nano-structured polypyrrole has special electrochemical activity, improved optical properties and good biocompatibility due to its well-defined nanostructure and larger surface area. In addition, with the rapid development of science and technology, single polypyrrole nanomaterials have been insufficient to cope with the application needs of various aspects. However, polypyrrole nanocomposites can retain the function of the individual components and the synergistic effect when integrated with other functional materials, and can simultaneously possess the advantages of several materials, thus greatly broadening the application range of polypyrrole. This article summarizes the research progress of polypyrrole nanocomposites and introduces the five types of polypyrrole nanocomposites. Based on their excellent electrical conductivity and reversible redox properties, the applications of polypyrrole nanocomposites in the fields of energy storage, biomedicine, adsorption and impurity removal, electrocatalysis, wave-absorbing materials, sensors and corrosion protection are presented. Finally, the perspectives on the challenges and opportunities in this emerging area of research are discussed.

Key words: polypyrrole nanocomposite energy storage biomedicine

出版日期: 2023-05-10 发布日期: 2023-05-04

ZTFLH:	O626.1
	TB332

基金资助: 国家自然科学基金(51473133);陕西省国际科技合作项目(2015KW-016);教育部中央高校基本科研业务费专项科研项目(xjh012019034)

通讯作者: *于德梅,西安交通大学化学学院教授、博士研究生导师。1984年天津大学化工系基本有机合成专业本科毕业后到西安交通大学工作至今,1989年西安交通大学化学化工学院高分子材料科学与工程专业硕士毕业,1998年西安交通大学电气工程学院电工材料与绝缘技术专业博士毕业。目前主要从事电功能高分子、功能纳米复合材料、聚合物加工和流变学等方面的研究工作。发表论文80余篇,包括Progress in Polymer Science、Journal of Physical Chemistry C、Carbon、Composite Science & Technology等。dmyu@xjtu.edu.cn

作者简介: 郝璐,西安交通大学化学学院助理教授。2010年陕西师范大学化学与材料科学学院化学专业本科毕业,2019年西安交通大学材料科学与工程专业博士毕业后到西安交通大学工作至今。目前主要从事导电聚吡咯及其衍生物的制备、表征及性能等方面的研究工作。发表论文8篇,包括Progress in Organic Coatings、Materials Science & Engineering C、Journal of Adhesion Science & Technology等。

引用本文:

郝璐, 于德梅. 聚吡咯纳米复合材料的研究进展[J]. 材料导报, 2023, 37(9): 21110151-10.
HAO Lu, YU Demei. Research Progress in Polypyrrole Nanocomposites. Materials Reports, 2023, 37(9): 21110151-10.

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http://www.mater-rep.com/CN/10.11896/cldb.21110151 或 http://www.mater-rep.com/CN/Y2023/V37/I9/21110151

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