Research Status of Improving Cementitious Activity and Volume Stability of Steel Slag
WANG Jianfeng, CHANG Lei, WANG Yan, LIU Hui, YUE Deyu, CUI Suping, LAN Mingzhang
Key Laboratory of Advanced Functional Materials, Ministry of Education,Facaulty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, China
Abstract: With the yearly increase of crude steel production, the accumulated storage volume of steel slag in China is also rising, and the use of steel slag as supplementary cementitious material is an effective measure to improve the comprehensive utilization rate of steel slag and reduce the carbon emission of cement and concrete industry. However, steel slag has problems such as low content and low activity of the cementitious component and high content of swelling components, which limit its application in cement and concrete. At present,many methods are used to improve the cementitious activity and volume stability of steel slag, including mechanical grinding activation, high temperature activation, acid activation, alkali activation, organic activation and carbonization activation. Mechanical grinding activation mainly through the physical way to break the steel slag crystal structure and reduce the particle size, but it has high energy consumption and only for the early strength benefit. High temperature activation mainly includes high temperature curing and high temperature reconstruction. High temperature curing promotes hydration by changing the external environment in which the steel slag is hydrated, but the higher temperature will cause the decomposition of ettringite and introduce pores. High temperature reconstruction process directly changes the mineral composition of the steel slag, but there are problems such as high energy consumption and poor homogeneity. Alkali activation can promote ion dissolution and consume calcium hydroxide, but there are problems such as alkali aggregate reaction and efforescence. Acid activation can promote ion dissolution and increase the specific surface area of steel slag, but it will react with the active components in steel slag. In organic activation, alkanolamines can promote ion dissolution through complexation, but the mechanism of action of alkanolamines with different molecular structures is still unclear. Carbonation fills the pores through the reaction of calcium and magnesium minerals with CO2 to form carbonates as microaggregates, but the presence of CO2 diffusion resistance to the interior of the specimen will make the carbonation degree uneven inside and outside. This paper analyzes the reasons of low activity and poor volume stability of steel slag from the source and composition of steel slag, summarizes the common methods for improving the cementitious activity and volume stability of steel slag, points out the current dilemmas faced by various methods and makes certain outlooks, in order to provide references for further optimization of steel slag properties and promote the further application of steel slag in the cement and concrete industry.
王剑锋, 常磊, 王艳, 刘辉, 岳德钰, 崔素萍, 兰明章. 钢渣胶凝活性与体积稳定性优化研究现状[J]. 材料导报, 2023, 37(11): 21100032-9.
WANG Jianfeng, CHANG Lei, WANG Yan, LIU Hui, YUE Deyu, CUI Suping, LAN Mingzhang. Research Status of Improving Cementitious Activity and Volume Stability of Steel Slag. Materials Reports, 2023, 37(11): 21100032-9.
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2023, Vol. 37 
