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材料导报  2023, Vol. 37 Issue (10): 21060226-11    https://doi.org/10.11896/cldb.21060226
  高分子与聚合物基复合材料 |
高延性地质聚合物复合材料性能及微结构研究进展
吕邦成1, 郭丽萍1,2,3,*, 丁聪1, 吴建东1, 曹园章1, 陈波4
1 东南大学材料科学与工程学院,南京 211189
2 江苏省土木工程材料重点实验室,南京 211189
3 江苏省先进土木工程材料协同创新中心,南京 211189
4 南京水利科学研究院水文资源与水利工程科学国家重点实验室,南京 210029
A Review on Performance and Microstructure of High Ductility Geopolymer Composites
LYU Bangcheng1, GUO Liping1,2,3,*, DING Cong1, WU Jiandong1, CAO Yuanzhang1, CHEN Bo4
1 School of Materials Science and Engineering, Southeast University, Nanjing 211189, China
2 Jiangsu Key Laboratory of Construction Materials, Nanjing 211189, China
3 Jiangsu Collaborative Innovation Center for Advanced Civil Engineering Materials, Nanjing 211189, China
4 State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Nanjing Hydraulic Research Institute, Nanjing 210029, China
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摘要 基于桥联法则理论、经微观力学设计而成的高延性水泥基复合材料(HDCC)以其拉伸荷载下具有的多缝开裂和应变硬化性能而优于普通混凝土,然则其发展仍受制于高制备成本及碳排放。近10年来,绿色经济性地质聚合物/碱激发材料与纤维复合增韧的高延性复合材料(HDGC)得到研究与发展。本文在概述地质聚合物/碱激发材料反应机理及HDCC材料设计理论的基础上,主要综述了HDGC基本性能与微结构的已有最新研究进展。研究表明,制备HDGC具有可行性且制备的HDGC表现出高延性复合材料所具备的力学响应特点,包括压缩、拉伸应变硬化、界面微观力学、弯曲、抗冲击性能等。然而,受材料组成复杂等因素影响,HDGC力学和微结构依赖于地质聚合物/碱激发材料基体化学性质的改变。HDGC同时具有更小的裂缝宽度而利于材料自修复、较大收缩值以及潜在的良好耐久性。此外,基于有限研究,对比了HDGC与HDCC的相似与差异,以期更好地了解地质聚合物/碱激发材料被用作HDCC替代品时应注意的条件。最后进一步对HDGC存在的问题和研究方向做出了总结与展望。
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吕邦成
郭丽萍
丁聪
吴建东
曹园章
陈波
关键词:  高延性  地质聚合物  碱激发  应变硬化  微结构    
Abstract: High ductility cement-based composites (HDCC), based on the bridge principal theory and designed by micromechanics, are superior to ordinary concrete due to their multiple cracking and strain hardening properties under tensile load, but their development is still limited by high production costs and carbon emissions. In the past decade, green and economical high ductility composites (HDGC) reinforced by geopolymer/alkali activated materials and fiber have been researched and developed. On the basis of summarizing the reaction mechanism of geopolymer/alkali activated materials and the design theory of HDCC materials, this paper mainly reviews the recent advances in the basic properties and microstructure of HDGC. The results show that the preparation of HDGC is feasible and the HDGC exhibits mechanical response characteristics of high ductility composites, including compression, tensile strain hardening, interface micromechanics, bending, impact resistance, etc. However, the mechanics and microstructure of HDGC depend on changes in the chemical properties of the geopolymer/alkali activated material matrix due to the complex composition of the material. HDGC also has smaller crack widths that facilitate material self-healing, larger shrinkage values, and potentially good durability. In addition, based on limited studies, the similarities and differences between HDGC and HDCC were compared in order to better understand the conditions that should be paid attention to when geopolymer/alkali activated materials are used as HDCC substitutes. Finally, the existing problems and research direction of HDGC are summarized and prospected.
Key words:  high ductility    geopolymer    alkali activated    strain hardening    microstructure
出版日期:  2023-05-25      发布日期:  2023-05-23
ZTFLH:  TU528  
基金资助: 国家自然科学基金(52178191;51778133);国家重点研发计划资助项目(973计划)(2015CB655102)
通讯作者:  *郭丽萍,博士,教授,博士研究生导师。2002年9月至2008年6月于东南大学硕博连读,获得工学硕士和工学博士学位。现为东南大学材料科学与工程学院副院长、党委委员,教育部“首批党建工作样板支部”建材党支部书记。入选 2015 年度江苏省第十二批“六大人才高峰”项目、2018 年度江苏省第五期“333 工程”第三层次人才。研究工作主要围绕生态高延性纤维混凝土的基础理论和应用研究以及水泥基复合材料的耐久性研究。主持包括国家自然科学基金青年和面上项目、973 项目专题、教育部博士点基金、中国铁路总公司重点课题和企业合作等项目20余项,以第一作者和通信作者在国内外学术期刊上发表论文 100余篇,其中 SCI 收录40余篇; 授权国家发明专利21项。获教育部科技进步二等奖2项、中国铁道学会铁道科技二等奖1项。guoliping@163.com   
作者简介:  吕邦成,2019年6月毕业于安徽建筑大学,获得硕士学位,现为东南大学材料科学与工程学院博士研究生,在郭丽萍教授的指导下进行研究。主要从事高延性水泥基复合材料、碱激发材料、固废物再利用领域的研究。
引用本文:    
吕邦成, 郭丽萍, 丁聪, 吴建东, 曹园章, 陈波. 高延性地质聚合物复合材料性能及微结构研究进展[J]. 材料导报, 2023, 37(10): 21060226-11.
LYU Bangcheng, GUO Liping, DING Cong, WU Jiandong, CAO Yuanzhang, CHEN Bo. A Review on Performance and Microstructure of High Ductility Geopolymer Composites. Materials Reports, 2023, 37(10): 21060226-11.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21060226  或          http://www.mater-rep.com/CN/Y2023/V37/I10/21060226
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