磷杂菲添加型阻燃剂对乙烯基酯树脂改性探究

doi:10.11896/cldb.21040246

材料导报

2022, Vol. 36

Issue (15): 21040246-5 https://doi.org/10.11896/cldb.21040246

高分子与聚合物基复合材料

磷杂菲添加型阻燃剂对乙烯基酯树脂改性探究

陈春悦^1,2, 徐春萍^1,2, 张永航¹, 龚维², 班大明^1,2,*

1 贵州师范大学化学与材料科学学院,贵阳 550001
2 贵州省功能高分子材料科技创新人才团队, 贵阳 550025

Study on Vinyl Ester Resin with Additive Flame Retardant of Phosphaphenanthrene

CHEN Chunyue^1,2, XU Chunping^1,2, ZHANG Yonghang¹, GONG Wei², BAN Daming^1,2,*

1 School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, China
2 Guizhou Functional Polymer Materials Science and Technology Innovation Talent Team, Guiyang 550025, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 4185KB )
输出: BibTeX | EndNote (RIS)

摘要以4-甲氧基酚和三氯氧磷为原料合成二氯化磷酸-4-甲氧基苯酯(MPC)中间体,再通过熔融聚合得到聚对甲氧基苯氧基磷酸-4,4'-异丙基双酚酯(PMIP)。利用傅里叶红外光谱(FTIR)和¹H、¹³C、³¹P核磁共振对其分子结构进行表征,并用凝胶色谱(GPC)分析其分子量。将PMIP单独或复配聚磷酸铵(APP)应用在乙烯基酯树脂(VER)中制备了PMIP-VER、PMIP/APP-VER复合材料,通过极限氧指数(LOI)、垂直燃烧(UL-94)测试、热重(TGA)分析等研究了PMIP/APP-VER复合材料的阻燃性和热稳定性。结果表明,添加20%(质量分数)的PMIP/APP时,其LOI为24.5%,UL-94可达到V-0级,残炭率为36.60%,有效提高了VER的成炭效率。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	陈春悦
	徐春萍
	张永航
	龚维
	班大明

关键词: 改性阻燃性能耐热性磷酸酯

Abstract: The intermediate of 4-methoxyphenyl phosphate dichloride (MPC) was synthesized from 4-methoxyphenol and phosphorus oxychloride, and then poly (p-methoxyphenoxyphosphate-4,4'-isopropyl bisphenol ester (PMIP) was obtained by melt polymerization.The molecular structure of PMIP was characterized by fourier transform infrared spectroscopy (FTIR) and ¹H,¹³C and ³¹P nuclear magnetic resonance. The molecular weight of PMIP was analysed by gel permeation chromatography (GPC). In addition, ammonium polyphosphate (APP) and PMIP were applied in vinyl ester resin (VER) to prepare PMIP-VER and PMIP/APP-VER composites. The flame retardancy and the thermal stability of PMIP/APP-VER composites were analyzed by limiting oxygen index (LOI), vertical combustion (UL-94) and thermogravimetric analysis (TGA). The results show that when 20% (mass fraction) of PMIP/APP is added, the LOI is 24.5%, that UL-94 can reach class V-0, and that the residual carbon rate was 36.60%, which effectively improves the coking efficiency of VER.

Key words: modification flame retardency property heat resistant phosphate

出版日期: 2022-08-10 发布日期: 2022-08-15

ZTFLH:

O632.4

基金资助: 国家自然科学基金(51763005);贵州省科技计划项目(黔科合平台人才〔2017〕5726 号)

通讯作者: *bdaming@gznu.edu.cn

作者简介: 陈春悦,2019年6月毕业于贵州师范大学求是学院,获得学士学位。2019年9月至2021年6月在贵州师范大学进行硕士阶段学习,主要从事阻燃剂和阻燃材料领域的研究。
班大明,贵州师范大学化学与材料科学学院教授。2004年7月博士毕业于四川大学化学学院高分子化学与物理专业。同年加入贵州师范大学理学院工作至今,2011年至2013年在北京理工大学从事博士后研究,2018年至2019年在英国博尔顿大学进行访问学者研究。主要从事无卤阻燃剂研究与开发,重点研究磷系阻燃剂的开发应用。在国内外重要期刊发表文章30多篇,申报发明专利10余项。

引用本文:

陈春悦, 徐春萍, 张永航, 龚维, 班大明. 磷杂菲添加型阻燃剂对乙烯基酯树脂改性探究[J]. 材料导报, 2022, 36(15): 21040246-5.
CHEN Chunyue, XU Chunping, ZHANG Yonghang, GONG Wei, BAN Daming. Study on Vinyl Ester Resin with Additive Flame Retardant of Phosphaphenanthrene. Materials Reports, 2022, 36(15): 21040246-5.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.21040246 或 http://www.mater-rep.com/CN/Y2022/V36/I15/21040246

1 Jiao W W, Cai Y M, Liu W G, et al. Applied Surface Science, 2018, 439, 88.
2 Arrieta J S, Richaud E, Farolle B, et al. Polymer Degradation and Stability, 2016, 129, 142.
3 Dev S, Shah P N, Zhang Y P, et al. Polymer, 2017, 133, 20.
4 Duan H J, Ji S, Yan T, et al. Journal of Applied Polymer Science, 2019, 136, 1
5 Zhang X, Zhang W W, Zhang W C, et al. Polymer International, 2020, 69, 1196.
6 Zhang W W, Zhang W C, Qin Z L, et al. Polymers for Advanced Techno-logies, 2020, 31, 1836.
7 Zou J H, Duan H J, Chen Y S, et al. Composites Part B: Engineering, 2020, 199, 108228.
8 Luo C Y, Nan C, Zuo J D, et al. Journal of Applied Polymer Science, 2020, 78, 1.
9 Zeng G F, Zhang W W, Zhang X, et al. Journal of Applied Polymer Science, 2020, 137, 2
10 Vu C M, Nguyen V H, Van T N. Polymer Testing, 2021, 93, 106987.
11 Zhang W W, Zhang X, Zeng G F, et al. Polymers for Advanced Technologies, 2019, 30, 3061.
12 Ji S, Duan H J, Chen Y S, et al. Polymer, 2020, 207, 2.
13 Shen H Y, Gou J, Fu H, et al. New Chemical Materials, 2020, 48(5), 192(in Chinese).
申慧滢, 苟佳, 付海, 等. 化工新型材料, 2020, 48(5), 192.
14 Ali K, Haghighi M N, Faramarz A T, et al. Polymer Degradation and Stability, 2020, 180, 109310.
15 Ciacomo G, Sara F, Miriam C, et al. Road Materials and Pavement Design, 2020, 23(3), 491.
16 Kurt G, Ersen G. Journal of Polymer Research, 2020, 27(10), 1.

[1]	栗启, 胡魁, 俞才华, 张桃利, 王丹丹. 聚乙烯与沥青相互作用的分子动力学机理研究[J]. 材料导报, 2023, 37(5): 21080176-6.
[2]	魏铭, 张长森, 王旭, 诸华军, 焦宝祥, 孙楠. 微纳米材料改性地质聚合物的研究进展[J]. 材料导报, 2023, 37(4): 21020065-10.
[3]	张家庆, 张达, 陈昆峰, 薛冬峰, 梁风. 稀土改性锂基氧化物固态电解质研究现状与展望[J]. 材料导报, 2023, 37(3): 22110300-9.
[4]	赵宏顺, 戚燕俐, 任玉荣. 钠离子电池负极材料锐钛矿型二氧化钛的研究进展[J]. 材料导报, 2023, 37(3): 21030187-10.
[5]	符明君, 张勇, 张耿飞, 王凯, 贾致远, 王娜. 钼及钼合金改性硅化物高温抗氧化涂层研究现状[J]. 材料导报, 2023, 37(3): 21030219-8.
[6]	杨薛明, 胡宗杰, 王炜晨, 刘强, 王帅. 利用蔗糖改性氮化硼提高环氧树脂复合材料的导热性能[J]. 材料导报, 2023, 37(2): 21110039-6.
[7]	丁鹤洋, 汪海年, 徐宁, 王宠惠, 屈鑫, 尤占平. 基于分子动力学的生物质油改性沥青相容性研究[J]. 材料导报, 2023, 37(2): 21050266-8.
[8]	孟兆通, 张昌海, 迟庆国, 张天栋. 固体绝缘材料中空间电荷的主要影响因素及抑制方法[J]. 材料导报, 2023, 37(1): 21040316-9.
[9]	李世杰, 王智辉, 代琳心, 李振瑞, 王佳军, 马建锋, 刘杏娥. 银/尿素改性竹质活性炭的制备及甲醛净化与抗菌性能[J]. 材料导报, 2022, 36(Z1): 22030103-6.
[10]	王秀超, 秦莹莹, 郭红革. 生物基可降解包装薄膜的研究进展[J]. 材料导报, 2022, 36(Z1): 21070279-8.
[11]	张子健, 姜锋, 于春晓. 长碳链聚酰胺PA1012的改性研究进展[J]. 材料导报, 2022, 36(Z1): 21100088-6.
[12]	王长龙, 赵高飞, 王永波, 张苏花, 郑永超, 霍泽坤, 王绍熙, 任真真, 邹佳一. 水库底泥和电石渣高温改性钢渣的研究[J]. 材料导报, 2022, 36(9): 21040178-7.
[13]	刘方, 张昆昆, 罗滔, 马卫卫, 蒋伟. 复杂环境因素下纳米改性混凝土冻融损伤研究[J]. 材料导报, 2022, 36(8): 20100024-5.
[14]	王岚, 罗学东, 张琪, 周晓东, 李超. 温拌胶粉改性沥青-集料粘附性及其体系水稳定性分析[J]. 材料导报, 2022, 36(8): 21010186-4.
[15]	李佩悦, 马立云, 谢恩俊, 任子杰, 周新军, 高惠民, 吴建新. 六方氮化硼高导热纳米材料:晶体结构、导热机理及表面修饰改性[J]. 材料导报, 2022, 36(6): 20090231-12.

[1]	Lanyan LIU,Jun SONG,Bowen CHENG,Wenchi XUE,Yunbo ZHENG. Research Progress in Preparation of Lignin-based Carbon Fiber[J]. Materials Reports, 2018, 32(3): 405 -411 .
[2]	Haoqi HU,Cheng XU,Lijing YANG,Henghua ZHANG,Zhenlun SONG. Recent Advances in the Research of High-strength and High-conductivity CuCrZr Alloy[J]. Materials Reports, 2018, 32(3): 453 -460 .
[3]	Yanchun ZHAO,Congyu XU,Xiaopeng YUAN,Jing HE,Shengzhong KOU,Chunyan LI,Zizhou YUAN. Research Status of Plasticity and Toughness of Bulk Metallic Glass[J]. Materials Reports, 2018, 32(3): 467 -472 .
[4]	Xinxing ZHOU,Shaopeng WU,Xiao ZHANG,Quantao LIU,Song XU,Shuai WANG. Molecular-scale Design of Asphalt Materials[J]. Materials Reports, 2018, 32(3): 483 -495 .
[5]	Yongtao TAN, Lingbin KONG, Long KANG, Fen RAN. Construction of Nano-Au@PANI Yolk-shell Hollow Structure Electrode Material and Its Electrochemical Performance[J]. Materials Reports, 2018, 32(1): 47 -50 .
[6]	Ping ZHU,Guanghui DENG,Xudong SHAO. Review on Dispersion Methods of Carbon Nanotubes in Cement-based Composites[J]. Materials Reports, 2018, 32(1): 149 -158 .
[7]	Fangyuan DONG,Shansuo ZHENG,Mingchen SONG,Yixin ZHANG,Jie ZHENG,Qing QIN. Research Progress of High Performance ConcreteⅠ:Raw Materials and Mix Proportion Design Method[J]. Materials Reports, 2018, 32(1): 159 -166 .
[8]	Guiqin HOU,Yunkai LI,Xiaoyan WANG. Research Progress of Zinc Ferrite as Photocatalyst[J]. Materials Reports, 2018, 32(1): 51 -57 .
[9]	Jianxiang DING,Zhengming SUN,Peigen ZHANG,Wubian TIAN,Yamei ZHANG. Current Research Status and Outlook of Ag-based Contact Materials[J]. Materials Reports, 2018, 32(1): 58 -66 .
[10]	Jing WANG,Hongke LIU,Pingsheng LIU,Li LI. Advances in Hydrogel Nanocomposites with High Mechanical Strength[J]. Materials Reports, 2018, 32(1): 67 -75 .

Viewed

Full text

Abstract

Cited

Shared

Discussed