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材料导报  2023, Vol. 37 Issue (5): 21030201-13    https://doi.org/10.11896/cldb.21030201
  无机非金属及其复合材料 |
钙钛矿太阳能电池稳定性研究进展及模组产业化趋势
金胜利1,2, 寿春晖1,2,*, 黄绵吉1,2, 贺海晏1,2, 李聪3
1 浙江省太阳能利用与节能技术重点实验室,杭州 311121
2 浙江浙能技术研究院有限公司,杭州 311121
3 西安电子科技大学先进材料与纳米科技学院,西安 710126
Research Progress on Stability of Perovskite Solar Cells and Industrialization Trend of Modules
JIN Shengli1,2, SHOU Chunhui1,2,*, HUANG Mianji1,2, HE Haiyan1,2, LI Cong3
1 Key Laboratory of Solar Energy Utilization & Energy Saving Technology of Zhejiang Province,Hangzhou 311121,China
2 Zhejiang Energy R & D Institute Co., Ltd.,Hangzhou 311121,China
3 School of Advanced Materials and Nanotechnology, Xidian University, Xi'an 710126, China
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摘要 有机无机杂化钙钛矿材料具有优异的光电特性,在光伏、显示和传感领域均获得了广泛关注。近年来,钙钛矿太阳能电池技术发展迅速,在效率提升和面积放大方面不断取得突破,但钙钛矿材料和器件的稳定性问题一直没能得到根本性的解决,严重制约了钙钛矿光伏器件的实用性能及商业化推广进程。钙钛矿太阳能电池的不稳定性来源于器件中钙钛矿层、电荷传输材料和电极材料的失效,失效原因主要包括光照、水分、温度和氧气等环境因素,因此深入理解各因素对钙钛矿太阳能电池稳定性的作用机理至关重要。此外,与晶硅和其他薄膜电池相比,钙钛矿太阳能电池在材料性能、器件结构等方面都有较大差别。目前晶硅电池和其他薄膜电池的稳定性评价方法和测试手段对钙钛矿太阳能电池不能完全适用,为了使不同机构间钙钛矿太阳能电池稳定性的测试结果可以对比,需要统一稳定性测试标准。
本文总结了钙钛矿材料及光伏器件稳定性的影响因素,剖析了光照、水分、温度和氧气等环境因素对钙钛矿器件稳定性的作用机理,并对提升钙钛矿太阳能电池稳定性的方法进行了综述。最后分析了钙钛矿太阳能电池稳定性的评价方法和测试手段,并对钙钛矿太阳能电池的未来发展方向进行了预测,以期为钙钛矿太阳能电池商业化应用提供新思路。
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金胜利
寿春晖
黄绵吉
贺海晏
李聪
关键词:  钙钛矿材料  太阳能电池  稳定性  商业化应用    
Abstract: Organic-inorganic hybrid perovskite materials have been widely used in the area of photovoltaic, display devices and sensors because of their excellent photoelectric properties. In recent years, the key technology of perovskite solar cells (PSCs) has developed rapidly, and there are many breakthroughs that have been made in photoelectric conversion efficiency and devices area. However, the stability of perovskite mate-rials and devices has not been fundamentally solved, which seriously restricts the practical performance and commercialization of perovskite photovoltaic devices. The instability of PSCs derived from the perovskite active layer, the charge transport materials and the electrode materials. The causes mainly include environmental factors such as light, water, temperature and oxygen. Therefore, it is crucial to understand the mechanism of each factor on the stability of PSCs. In addition, compared with crystalline silicon solar cells and other thin-film solar cells, PSCs have great differences in material properties and device structures. At present, the stability evaluation methods and testing methods of crystalline silicon cells and other thin film cells are not fully applicable to PSCs. A standard stability tests procedure is required in order to compare the stability test results of perovskite cells between the various institutions.
In this paper, the factors affecting the stability of perovskite materials and photovoltaic devices are firstly summarized. Then the mechanism of environmental factors such as light, moisture, temperature and oxygen on the stability of perovskite devices are analyzed, and the methods to improve the stability of PSCs are summarized. Finally, the stability evaluation and testing methods, as well as the future development direction of PSCs are analyzed and forecasted, which provide a new idea for the commercial application of PSCs.
Key words:  perovskite material    solar cell    stability    industrialization trend
出版日期:  2023-03-10      发布日期:  2023-03-14
ZTFLH:  TM914  
基金资助: 浙江省重点研发计划项目(2021C04009);浙江省太阳能利用与节能技术重点实验室项目(ZNKJ2017083)
通讯作者:  *寿春晖,2012年毕业于浙江大学,获博士学位。现为浙江省太阳能利用与节能技术重点实验室副主任,浙江浙能技术研究院有限公司新能源研究所所长,高级工程师。目前累计发表论文30余篇,获中电联电力科技创新一等奖等,主要研究领域为太阳能电池材料和器件、光伏系统增效和节能技术等。shouchunhui@zjenergy.com.cn   
作者简介:  金胜利,2019年3月毕业于华北电力大学,获工程硕士学位。2019年5月入职浙江浙能技术研究院有限公司,目前主要研究领域为新型太阳能电池材料及器件。近年来作为第一或共同作者在电子材料和器件领域发表多篇论文,包括Advanced Optical Materials、 ACS Applied Materials & Interfaces、Chemical Communications和Energy Technology等。
引用本文:    
金胜利, 寿春晖, 黄绵吉, 贺海晏, 李聪. 钙钛矿太阳能电池稳定性研究进展及模组产业化趋势[J]. 材料导报, 2023, 37(5): 21030201-13.
JIN Shengli, SHOU Chunhui, HUANG Mianji, HE Haiyan, LI Cong. Research Progress on Stability of Perovskite Solar Cells and Industrialization Trend of Modules. Materials Reports, 2023, 37(5): 21030201-13.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21030201  或          http://www.mater-rep.com/CN/Y2023/V37/I5/21030201
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