管件内壁电沉积涂层技术的研究进展

doi:10.11896/cldb.20100118

材料导报

2022, Vol. 36

Issue (13): 20100118-7 https://doi.org/10.11896/cldb.20100118

金属与金属基复合材料

管件内壁电沉积涂层技术的研究进展

向鑫^*, 杨飞龙, 张桂凯, 胡立, 宋雅琪, 朱力桂

中国工程物理研究院材料研究所,四川江油 621908

Research Status of Electrodeposition Coating Technique for Inner Walls of Pipe Workpieces

XIANG Xin^*, YANG Feilong, ZHANG Guikai, HU Li, SONG Yaqi, ZHU Ligui

Institute of Materials, China Academy of Engineering Physics, Jiangyou 621908,Sichuan,China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 2899KB )
输出: BibTeX | EndNote (RIS)

摘要因设备简单、镀层致密、成分和厚度可控、绕镀性强等优点,电沉积涂层技术在管件(特别是异形件)的内壁改性和防护方面得到了广泛应用。然而,相对于外表面,管件内壁电沉积技术面临更大的挑战,具有阴/阳极面积比大、内角难以涂覆、涂层厚度不均匀、存在局部过热或温度梯度等技术难点。工程上,常采用精细化象形阳极设计及合理的前处理方法优化电沉积工艺参数(如电流密度、电流效率、镀液温度、搅拌速率等),以获得均匀致密的涂层。鉴于此,本文简要分析和评述了管件内壁电沉积的技术特点、影响因素及工程化应用,以期能为相关基础研究和工程实践提供参考和指导。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	向鑫
	杨飞龙
	张桂凯
	胡立
	宋雅琪
	朱力桂

关键词: 管件内壁电沉积影响因素象形阳极

Abstract: The electrodeposition technique is widely adopted for the inner wall modification and protection for pipe workpieces, especially for those with complex geometry. This technique is possessed of the following advantages of simple facilities required, dense coatings, controllable composition and thickness, and good platability, etc. However, compared with the technique for the outer surface treatment, greater challenges will emerge for the inner wall electrodeposition of pipe workpieces, such as large area ratio of cathode/anode, difficulty in coating the inner corners, inhomogeneity of coating thickness, and existence of local overheating or temperature gradation, etc. In order to obtain homogenous and dense coatings in the engineering practice, a fine designed conformable anode and appropriate treating method prior to plating are commonly employed, accompanied by optimizing the electrodeposition parameters like the current density, current efficiency, electrolyte temperature and stirring rate, etc. The characteristics, influence factors and engineering applications of inner wall electrodeposition technique of pipe workpieces are thus reviewed, expecting to provide some reference and guideline for related fundamental research and engineering practice.

Key words: pipe workpiece inner walls electrodeposition influence factor conformable anode

出版日期: 2022-07-10 发布日期: 2022-07-12

ZTFLH:

TL214+.6

基金资助: 国家磁约束核聚变能发展研究专项项目(2018YFE0313100;2017YFE0300304);国家自然科学基金(11975213);表面物理与化学重点实验室基金(WDZC202105)

通讯作者: * xiangxin-7s@caep.cn

作者简介: 向鑫,博士,中国工程物理研究院材料研究所副研究员。2006年获得浙江大学材料科学与工程专业工学学士学位,后分别于2009年、2016年获得中国工程物理研究院核燃料循环与材料专业工学硕士和博士学位。长期从事材料中氢同位素及氦的行为、聚变堆相关氚工艺以及涉氚材料等科学技术研究,作为技术骨干先后参与我国参试ITER产氚试验包层(HCCB TBM)氚处理系统概念设计及关键技术研究、CFETR氚燃料循环工厂系统概念设计及关键技术研究、CFETR包层材料中氚循环技术研究等大型科技攻关。目前,主持ITER人才课题及国家自然科学基金面上项目各一项,授权国家发明专利2项,发表科研论文50余篇。

引用本文:

向鑫, 杨飞龙, 张桂凯, 胡立, 宋雅琪, 朱力桂. 管件内壁电沉积涂层技术的研究进展[J]. 材料导报, 2022, 36(13): 20100118-7.
XIANG Xin, YANG Feilong, ZHANG Guikai, HU Li, SONG Yaqi, ZHU Ligui. Research Status of Electrodeposition Coating Technique for Inner Walls of Pipe Workpieces. Materials Reports, 2022, 36(13): 20100118-7.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.20100118 或 http://www.mater-rep.com/CN/Y2022/V36/I13/20100118

1 Zhao Y H, Jia Y, Yu B H,et al. Surface Technology, 2014, 43(2), 118 (in Chinese).
赵彦辉, 贾莹, 于宝海, 等. 表面技术, 2014, 43(2), 118.
2 Zhang Y, Liu Y, Zhou Z, et al. IOP Conference Series: Materials Science and Engineering, 2017, 230, 012018.
3 Igolkin A I, Zelenin Y V. Chemical and Petroleum Engineering, 2009, 45(3-4), 251.
4 Xue D, Chen Y, Ling G, et al. Fusion Engineering and Design, 2015, 101, 128.
5 Ensinger W, Lensch O, Kraus T, et al. Surface & Coatings Technology, 2002, 150, 227.
6 Baba K, Hatada R. Surface & Coatings Technology, 2000, 128-129, 112.
7 Ayata S, Ensinger W. Surface & Coatings Technology, 2018, 340, 121.
8 Meng J, Yang X T, Zhang J H, et al. Physics Procedia, 2012, 32, 865.
9 Berreth K, Maile K, Lyutovich A. Materials and Corrosion, 2005, 56(12), 916.
10 黄绍松, 刘宇, 赵纪军, 等. 中国专利, CN201810057645.7, 2018.
11 Xiong Y, Gao H, Ren N, et al. Plasma Science & Technology, 2018, 20, 035507.
12 Barton I, Matejec V, Mrazek J, et al. Journal of Sol-Gel Science and Technology, 2017, 81, 867.
13 Fan H L. The method research on preparation coating by powder electric spraying on the inner surface of tube.Master's Thesis, Lanzhou University of Technology,China, 2017 (in Chinese).
范宏林. 粉末电爆喷涂用于管内壁涂层制备方法的研究. 硕士学位论文, 兰州理工大学, 2017.
14 Tian Z, Zhang G, Huang W, et al. Key Engineering Materials, 2013, 537, 279.
15 Hu Z, Wang H, Zhu Y, et al. AIChE Journal, 2017, 63(9), 3636.
16 Du H, Song G, Nakajima H, et al. Applied Surface Science, 2013, 264, 772.
17 Xiang X, Yang F, Zhang G, et al. Coatings, 2019, 9, 95.
18 Hu L, Zhang G, Wang H, et al. Fusion Engineering and Design, 2019, 148, 111280.
19 Wei B J, Hu L, Xiang X, et al. Acta Physica Sinica, 2021,70(3), 208 (in Chinese).
韦炳军, 胡立, 向鑫, 等. 物理学报, 2021,70(3), 208.
20 Li F, Wu Y, Hu R N. Plating and Finishing, 2011, 33(10), 17 (in Chinese).
李峰, 吴欲, 胡如南. 电镀与精饰, 2011, 33(10), 17.
21 Xie H B, Zhang L X. Electroplating & Pollution Control, 2004, 24(6), 20 (in Chinese).
谢洪波, 张来祥. 电镀与环保, 2004, 24(6), 20.
22 Chen B. Basic research on the application of crack-free hard chromium electroplating. Master's Thesis, Nanjing University of Aeronautics and Astronautics,China, 2017 (in Chinese).
陈斌. 无裂纹电镀硬铬应用基础研究. 硕士学位论文, 南京航空航天大学, 2017.
23 Hu R H, Huo D Y. Electroplating & Finishing, 2017, 36(13), 711 (in Chinese).
胡瑞华, 霍大勇. 电镀与涂饰, 2017, 36(13), 711.
24 Xi B. Electroplating & Pollution Control, 2012, 32(6), 49 (in Chinese).
奚兵. 电镀与环保, 2012, 32(6), 49.
25 Yang B, Leu M C. US patent, US6409902, 2002.
26 Yang D C, Yun N Z. New Technology & New Process, 2004(2), 33 (in Chinese).
杨大春, 云乃彰. 新技术新工艺, 2004(2), 33.
27 Yang J M, Zhu D, Wang K. Electromachining & Mould, 2004(5), 23 (in Chinese).
杨建明, 朱荻, 王昆. 电加工与模具, 2004(5), 23.
28 Yang J M, Zhu D, Wang K. Machine Design and Research, 2004, 20(5), 56 (in Chinese).
杨建明, 朱荻, 王昆. 机械设计与研究, 2004, 20(5), 56.
29 Ren G P, An C Q, Tong W, et al. Plating and Finishing, 2016, 38(7), 32 (in Chinese).
任国鹏, 安成强, 佟威, 等. 电镀与精饰, 2016, 38(7), 32.
30 Li W Q. Plating and Finishing, 2014, 36(7), 33 (in Chinese).
李卫权. 电镀与精饰, 2014, 36(7), 33.
31 Li J D, Xuan M, Wu Y H,et al. Journal of Functional Materials Devices, 2008, 14(2), 336 (in Chinese).
李加东, 宣明, 吴一辉, 等. 功能材料与器件学报, 2008, 14(2), 336.
32 Zhang Q H, Wu Z C, Wang Q G. Journal of Ordnance Engineering College, 2006(18), 25 (in Chinese).
张庆海, 武占成, 王庆国. 军械工程学院学报, 2006(18), 25.
33 Yang J M. Materials Protection, 2010, 43(4), 38 (in Chinese).
杨建明. 材料保护, 2010, 43(4), 38.
34 Oh Y J, Chung S H, Lee M S. Materials Transactions, 2004, 45(10), 3005.
35 Ge X R. Electro Brush Plating Technology, 1995(1), 1 (in Chinese).
葛祥荣. 电刷镀技术, 1995(1), 1.
36 Yuan S P. Electroplating & Finishing, 2009, 28(4), 40 (in Chinese).
袁诗璞. 电镀与涂饰, 2009, 28(4), 40.
37 Li Y, Li J S. Pretreatment and post treatment of electroplating, Chemical Industry Press, China, 2009, pp.1 (in Chinese).
李异, 李建三. 电镀前处理与后处理, 化学工业出版社, 2009, pp.1.
38 Qu H L. Electroplating & Finishing, 2009, 28(9), 28 (in Chinese).
琚红亮. 电镀与涂饰, 2009, 28(9), 28.
39 Zhang F, Wang X H, Xiao Y K. Electroplating & Finishing, 2005, 24(10), 20 (in Chinese).
张峰, 王旭辉, 肖耀坤. 电镀与涂饰, 2005, 24(10), 20.
40 Zhang G K. Research on aluminide tritium permeation barriers by the method of aluminium plating in room temperature molten salts combined with oxidation. Master's Thesis, China Academy of Engineering Physics,China, 2010 (in Chinese).
张桂凯. 室温熔盐镀铝-氧化法制备铝化物阻氚层技术研究. 硕士学位论文, 中国工程物理研究院, 2010.
41 Xiang G P. Theory and application of pulse electroplating, Tianjin Science Press, China, 1989, pp.1 (in Chinese).
向国朴. 脉冲电镀的理论与应用, 天津科学出版社, 1989, pp.1.
42 Yang C C. Materials Chemistry and Physics, 1994, 37(4), 335.
43 Du L Q, Liu H J, Qin J,et al. Optics and Precision Engineering, 2007, 15(1), 69 (in Chinese).
杜立群, 刘海军, 秦江, 等. 光学精密工程, 2007, 15(1), 69.
44 Wang Z X, Wang S, Yang Z, et al. International Journal of Surface Science and Engineering, 2010, 88(5), 272.
45 Zhou B N, Yu Z X, Lu Z H,et al. Nonferrous Metal, 1993(3), 27 (in Chinese).
周邦娜, 余仲兴, 陆芝华, 等. 有色金属, 1993(3), 27.
46 Wang W X. Preparation of Al₂O₃/FeAl tritium permeation barriers on CLAM steels. Master's Thesis, China Academy of Engineering Physics, China,2015 (in Chinese).
王文轩. CLAM钢表面Al₂O₃/FeAl防氚渗透膜层制备. 硕士学位论文, 中国工程物理研究院, 2015.
47 Qin Q X, Liu S L. Plating and Finishing, 2008, 30(8), 25 (in Chinese).
覃奇贤, 刘淑兰. 电镀与精饰, 2008, 30(8), 25.
48 Chen Y M. Electroplating of Al on internal surface of tube in ionic liquids.Master's Thesis, Zhejiang University, China,2015 (in Chinese).
陈益明. 管道内壁离子液体镀铝技术的研究. 硕士学位论文, 浙江大学, 2015.
49 Song Y Q. Research on palladium coating technology on porous stainless steel substrates. Master's Thesis. China Academy of Engineering Physics,China, 2018 (in Chinese).
宋雅琪. 多孔不锈钢基体上钯膜镀覆技术研究. 硕士学位论文, 中国工程物理研究院, 2018.
50 Zhu L Q. Electrodeposition theory and technology of functional coatings, Beijing University of Aeronautics and Astronautics Press, China, 2005, pp.21 (in Chinese).
朱立群. 功能膜层的电沉积理论与技术, 北京航天航空大学出版社, 2005, pp.21.
51 Jiang T, Chollier B M J, Dubé G. Surface & Coatings Technology, 2006, 201(l&2), 1.
52 Chang J K, Chen S Y, Wen T T, et al. Journal of the Electrochemical Society, 2008, 155(3), C112.
53 Zhong M E, He L P, Xiao Y K,et al. Materials Protection, 2006, 39(6), 26 (in Chinese).
钟美娥, 何莉萍, 肖耀坤, 等. 材料保护, 2006, 39(6), 26.
54 Zhang W G, Li W X, Wang B, et al. Plating and Finishing, 2007, 29(4), 33 (in Chinese).
张卫国, 李伟祥, 王飙, 等. 电镀与精饰, 2007, 29(4), 33.
55 Zhu L R. Surface Techniques, 1993, 22(2), 66 (in Chinese).
朱流荣. 表面技术, 1993, 22(2), 66.
56 He F J, Gao H, Huang Y N,et al. Materials Protection, 2006, 39(8), 63 (in Chinese).
何凤姣, 高晖, 黄宇宁, 等. 材料保护, 2006, 39(8), 63.
57 Yuan S P. Electroplating & Finishing, 2009, 28(2), 39 (in Chinese).
袁诗璞. 电镀与涂饰, 2009, 28(2), 39.
58 Qin Q X, Liu S L. Plating and Finishing, 2008, 30(9), 31 (in Chinese).
覃奇贤, 刘淑兰. 电镀与精饰, 2008, 30(9), 31.
59 Zhang S M, Zhou Y Q. Acta Scientiarum Naturalium Universitatis Nankaiensis, 1999, 32(4), 63 (in Chinese).
张守民, 周永洽. 南开大学学报(自然科学), 1999, 32(4), 63.
60 Zhang G, Yang F, Lu G, et al. Journal of Fusion Energy, 2018, 37, 317.
61 Xie R Z, Zou J J, Lin N M,et al. Corrosion & Protection, 2017, 38(8), 619 (in Chinese).
谢瑞珍, 邹娇娟, 林乃明, 等. 腐蚀与防护, 2017, 38(8), 619.
62 Li J D, Wu Y H, Zhang P,et al. Optics and Precision Engineering, 2008, 16(3), 452 (in Chinese).
李加东, 吴一辉, 张平, 等. 光学精密工程, 2008, 16(3), 452.
63 Yang H L, Ding J J, Jiang Y D,et al. Rare Metal Materials Engineering, 2018, 47(5), 1523 (in Chinese).
杨慧玲, 丁晶晶, 江奕东, 等. 稀有金属材料与工程, 2018, 47(5), 1523.
64 Li H J, Ming P M, Zhao Y L,et al. Electromachining & Mould, 2016(5), 47 (in Chinese).
李慧娟, 明平美, 赵云龙, 等. 电加工与模具, 2016(5), 47.
65 Tan Y J, Lim K Y. Surface & Coatings Technology, 2003, 167, 255.
66 Wang S N, Wang Z L. Plating and Finishing, 2008, 30(12), 24 (in Chinese).
王劭南, 王增林. 电镀与精饰, 2008, 30(12), 24.
67 Yuan S P. Electroplating & Finishing, 2009, 28(1), 43 (in Chinese).
袁诗璞. 电镀与涂饰, 2009, 28(1), 43.
68 林光喜. 中国专利, CN01253719.5, 2001.
69 凌国平, 陈益明. 中国专利, CN20151078369.9, 2015.

[1]	王俊辉, 黄悦, 杨国涛, 魏琦安, 刘文卓. 再生混凝土抗压性能研究进展[J]. 材料导报, 2022, 36(Z1): 21100033-9.
[2]	林欢, 石启亮, 蔡利海, 刘文言, 李万利. 聚硼硅氧烷剪切增稠凝胶的制备影响因素及其在不同温度下的流变性能研究[J]. 材料导报, 2022, 36(Z1): 21070206-6.
[3]	姚峄林, 张锦秋, 杨培霞, 安茂忠. 激光辅助电沉积技术及其在制备功能材料方面的应用[J]. 材料导报, 2022, 36(3): 20080209-9.
[4]	周志刚, 周扬, 刘智仁. 透水沥青混合料动态模量影响因素分析[J]. 材料导报, 2022, 36(13): 21010221-7.
[5]	李世杰, 黄慧娟, 尚莉莉, 马建峰, 马千里, 刘杏娥. 活性炭净化室内甲醛的研究进展[J]. 材料导报, 2021, 35(z2): 75-80.
[6]	王旭, 牛宗伟, 王晓明, 赵阳, 韩国峰, 常青, 付华, 滕涛, 赵菲菲. 外场(力)辅助射流电沉积研究现状[J]. 材料导报, 2021, 35(5): 5107-5121.
[7]	杨燕, 谭康豪, 覃英宏. 混凝土内氯离子扩散影响因素的研究综述[J]. 材料导报, 2021, 35(13): 13109-13118.
[8]	廖磊, 吕承航, 黄维刚, 秦霸. 电沉积法制备纳米SnO₂及其应用综述[J]. 材料导报, 2020, 34(Z2): 57-62.
[9]	吴建辉, 吴蒙华, 佐姗姗, 钱宁开. 无掩模定域性电沉积三维微结构的仿真研究[J]. 材料导报, 2020, 34(Z1): 427-432.
[10]	李平, 赵焰杰, 王李波. 基于交互正交试验的304不锈钢冲蚀磨损性能的影响因素研究[J]. 材料导报, 2020, 34(8): 8149-8153.
[11]	肖江, 周书葵, 刘星, 储陆平, 张建, 李智东, 田林玉, 李嘉丽. 层状双金属氢氧化物及其复合材料去除水体中重金属离子的研究进展[J]. 材料导报, 2020, 34(5): 5023-5031.
[12]	吴双全, 任鑫, 初鑫, 江仁康, 窦春岳, 高志玉. 基于双向脉冲电沉积下的Ni-纳米TiC复合镀层结构及耐磨性能[J]. 材料导报, 2020, 34(24): 24080-24085.
[13]	贾卫平, 吴蒙华, 贾振元, 董桂馥, 李晓鹏, 周绍安. 超声功率对多场耦合作用下脉冲电沉积Ni-ZrO₂纳米复合镀层性能的影响[J]. 材料导报, 2020, 34(2): 2017-2022.
[14]	王泳丹, 刘子铭, 郝培文. 综论沥青的疲劳损伤自愈合行为:理论研究,评价方法,影响因素,数值模拟[J]. 材料导报, 2019, 33(9): 1517-1525.
[15]	王一雍, 周新宇, 金辉, 梁智鹏. 超声辅助电沉积Ni-Co/Y₂O₃复合镀层的电化学研究[J]. 材料导报, 2019, 33(6): 1011-1016.

[1]	Lanyan LIU,Jun SONG,Bowen CHENG,Wenchi XUE,Yunbo ZHENG. Research Progress in Preparation of Lignin-based Carbon Fiber[J]. Materials Reports, 2018, 32(3): 405 -411 .
[2]	Haoqi HU,Cheng XU,Lijing YANG,Henghua ZHANG,Zhenlun SONG. Recent Advances in the Research of High-strength and High-conductivity CuCrZr Alloy[J]. Materials Reports, 2018, 32(3): 453 -460 .
[3]	Yanchun ZHAO,Congyu XU,Xiaopeng YUAN,Jing HE,Shengzhong KOU,Chunyan LI,Zizhou YUAN. Research Status of Plasticity and Toughness of Bulk Metallic Glass[J]. Materials Reports, 2018, 32(3): 467 -472 .
[4]	Xinxing ZHOU,Shaopeng WU,Xiao ZHANG,Quantao LIU,Song XU,Shuai WANG. Molecular-scale Design of Asphalt Materials[J]. Materials Reports, 2018, 32(3): 483 -495 .
[5]	Yongtao TAN, Lingbin KONG, Long KANG, Fen RAN. Construction of Nano-Au@PANI Yolk-shell Hollow Structure Electrode Material and Its Electrochemical Performance[J]. Materials Reports, 2018, 32(1): 47 -50 .
[6]	Ping ZHU,Guanghui DENG,Xudong SHAO. Review on Dispersion Methods of Carbon Nanotubes in Cement-based Composites[J]. Materials Reports, 2018, 32(1): 149 -158 .
[7]	Fangyuan DONG,Shansuo ZHENG,Mingchen SONG,Yixin ZHANG,Jie ZHENG,Qing QIN. Research Progress of High Performance ConcreteⅠ:Raw Materials and Mix Proportion Design Method[J]. Materials Reports, 2018, 32(1): 159 -166 .
[8]	Guiqin HOU,Yunkai LI,Xiaoyan WANG. Research Progress of Zinc Ferrite as Photocatalyst[J]. Materials Reports, 2018, 32(1): 51 -57 .
[9]	Jianxiang DING,Zhengming SUN,Peigen ZHANG,Wubian TIAN,Yamei ZHANG. Current Research Status and Outlook of Ag-based Contact Materials[J]. Materials Reports, 2018, 32(1): 58 -66 .
[10]	Jing WANG,Hongke LIU,Pingsheng LIU,Li LI. Advances in Hydrogel Nanocomposites with High Mechanical Strength[J]. Materials Reports, 2018, 32(1): 67 -75 .

Viewed

Full text

Abstract

Cited

Shared

Discussed