Progress in Development of Metal Oxide Nanoparticles by Supercritical Anti-solvent Method
LI Zezhen1,2, LIU Hao1,2, XU Peiyao1,2, CHEN Zhoujiang1,2, WANG Shibin1,2, CHEN Aizheng1,2
1 Institute of Biomaterials and Tissue Engineering, Huaqiao University, Xiamen 361021, Fujian, China 2 Fujian Key Laboratory of Biochemical Technology, College of Chemical Engineering, Huaqiao University, Xiamen 361021, Fujian, China
Abstract: Metal oxides with nanometer size have attracted much attention in the fields of electrochemistry, biomedicine and other sciences due to their excellent catalytic properties. At present, the traditional methods of preparing metal oxide nanoparticles include the hydrothermal method, solthermal method, precipitation method, microemulsion method, sol-gel method and template method. However, the development of these methods is limited due to the high cost and the existence of residual organic solvents. Therefore, it is urgent to develop a new preparation techno-logy of metal oxide nanoparticles to make up for the shortcomings of traditional methods and promote the development of preparation technology of metal oxide nanoparticles. Supercritical fluid is a kind of fluid in a special state whose temperature and pressure are above the critical temperature and pressure of material. It has some properties of gas and liquid. It has unique solvation characteristics, near zero surface tension, low viscosity, easy to adjust, close to the density and solubility of liquid and similar gas diffusion properties. In recent years, the supercritical fluid technology has garnered enormous interest in chemical, environmental, pharmaceutical and other fields due to the mild operation conditions and unique properties of supercritical fluids (SCFs). Amongst different variants of SCF processes, the supercritical anti-solvent (SAS) method is widely used in the fabrication of nanoparticulate forms of various substrates as its moderate operating condition, results in no residual organic solvents in the particles, and controllable particle size among others. Various metal oxide nanoparticles can be synthesized using this SAS process, which showed excellent applications in various fields, such as catalysis, sensing, and biomedicine. In this article, the basic principle, preparation process and application of diverse metal oxide nanoparticles by the SAS method are reviewed. In addition, the effects of temperature, pressure and solution concentration in SAS process on the size and morphology of metal nanoparticles were also discussed. And we also emphasized the challenge that may affect the application and future development.
李泽朕, 刘昊, 徐沛瑶, 陈洲江, 王士斌, 陈爱政. 超临界抗溶剂法制备金属氧化物纳米颗粒的研究进展[J]. 材料导报, 2022, 36(3): 20080184-6.
LI Zezhen, LIU Hao, XU Peiyao, CHEN Zhoujiang, WANG Shibin, CHEN Aizheng. Progress in Development of Metal Oxide Nanoparticles by Supercritical Anti-solvent Method. Materials Reports, 2022, 36(3): 20080184-6.
1 Manjakkal L, Szwagierczak D, Dahiya R. Progress in Materials Science, 2020, 109,100635. 2 Zheng Z L, He X W, Zhao J W, et al.Journal of Functional Materials, 2016, 47(6),6043 (in Chinese). 郑志林, 何小伟, 赵佳伟, 等.功能材料, 2016, 47(6), 6043. 3 Xu Z Y, Zhao W B, Chai M Y, et al. New Chemical Materials, 2019, 47(4), 38(in Chinese). 徐志勇, 赵文波, 柴牧原, 等. 化工新型材料, 2019, 47(4),38. 4 Xu Y H. Research on the preparation of nano-structured metal complex oxides and their application in electrochemical sensors. Ph. D. Thesis, Shanghai University,China, 2011 (in Chinese). 徐彦红. 金属复合氧化物纳米材料的制备及其在电化学传感器中的应用研究. 博士学位论文, 上海大学, 2011. 5 Lu H J, Wang J K, Stoller M, et al. Advances in Materials Science & Engineering, 2016, 2016,1. 6 Greta R P, Zhou Y, Roman K, et al. Angewandte Chemie International Edition, 2011, 50(4), 856. 7 Chen Z X, Zheng B Y, Li X X, et al. Chemical Industry and Engineering Progress, 2010, 29(1),94 (in Chinese). 陈彰旭, 郑炳云, 李先学, 等. 化工进展, 2010, 29(1), 94. 8 Zhang Y M, Jiang H X. Chemical Industry and Engineering Progress, 2013, 32(8),1825 (in Chinese). 张以敏, 姜浩锡. 化工进展, 2013, 32(8),1825. 9 Knez Z, Markocic E, Leitgeb M, et al. Energy, 2014, 77,235. 10 Fang C H, Chen P H, Chen Y P, et al. Chemical Engineering & Techonlogy, 2020, 43(6), 1186. 11 Wang Y L, Dave R N, Pfeffer R. Journal of Supercritical Fluid, 2004, 28(1),85. 12 Yeo S D, Kiran E. Journal of Supercritical Fluid, 2005, 34(3), 287. 13 Haq M, Chun B S. LWT-Food Science and Technology, 2018, 92,523. 14 Yeo S D, Lim G B, Debendetti P G, et al. Biotechnology and Bioengineering, 1993, 41(3),341. 15 Hakuta Y, Hayashi H, Arai K. Current Opinion in Solid State & Materials Science, 2003, 7(4/5),341 16 Falk R, Randolph T W, Meyer J D, et al. Journal of Controlled Release, 1997, 44(1), 77. 17 Chattopadhyay P, Gupta R B. Industrial & Engineering Chemistry Research, 2002, 41(24), 6049. 18 Margulis K, Neofytou E A, Beygui R E, et al. ACS Nano, 2015, 9(9), 9416. 19 Chen A Z, Wang G Y, Wang S B, et al. International Journal of Nano-Medicine, 2012, 7,3013. 20 Meziani M J, Sun Y P. Journal of the American Chemical Society, 2003, 125(26), 8015. 21 Shen Y B, Du Z, Wang Q, et al. Powder Technology, 2014, 254, 416. 22 Pu X M, Kang Y Q, Chen A Z, et al.Journal of Functional Materials, 2007(4),549 (in Chinese). 蒲曦鸣, 康云清, 陈爱政, 等. 功能材料, 2007(4),549. 23 Chen B Q, Kankala R K, Wang S B, et al. Journal of Supercritical Fluids, 2018, 133,486. 24 Kankala R K, Liu C G, Chen A Z, et al. ACS Biomaterials Science & Engineering, 2017, 3(10),2431. 25 Jiang H X, He C H, Sun H H, et al. Journal of Inorganic Matericals, 2010, 25(10),1065 (in Chinese). 姜浩锡, 何春花, 孙焕花, 等. 无机材料学报, 2010, 25(10),1065. 26 Kang Y Q, Chen A Z, Wang S B, et al. Chemical Industry and Enginee-ring Progress, 2013, 32(8),1734 (in Chinese). 康永强, 陈爱政, 王士斌, 等. 化工进展, 2013, 32(8),1734. 27 Kang Z W, Kankala R K, Chen B Q, et al. Applied Materials & Interfaces, 2019, 11,28781. 28 Jiang H X, Zhou J L, Sun H H, et al. Journal of Rare Earths, 2016, 34(11),1126. 29 Jiang D Y, Zhang M H, Li G M, et al. Catalysis Communications, 2011, 17, 59. 30 Jiang H X, Wu X H, Wang C X, et al. Catalysis Surveys from Asis, 2017, 21(1),37. 31 Jiang N N, Wang Y W, Li D Y, et al. Partical & Partical Systems Cha-racterization, 2019, 36(9),1900016. 32 Lu T J, Blackburn S, Dickinson C, et al. Powder Technology, 2008, 188(3),264. 33 Jiang H X, Huang P, Liu L, et al. Materials Characterization, 2011, 63,98. 34 Tang Z R, Edwards J K, Bartley J K, et al. Journal of Catalysis, 2007, 249(2),208. 35 He C Y, Jiang H X, Zhang M H. Chinese Journal of Catalysis, 2007, 10(28),890(in Chinese). 何春燕, 姜浩锡, 张敏华. 催化学报, 2007, 10(28),890. 36 Reverchon E, Marco I D, Torino E. Journal of Supercritical Fluid, 2007, 43,126. 37 An K, Hyeon T. Nano Today, 2009, 4(4),359.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2022, Vol. 36 
