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材料导报  2021, Vol. 35 Issue (7): 7121-7126    https://doi.org/10.11896/cldb.19110024
  金属与金属基复合材料 |
不同粒径金属基纳米颗粒的性质与其环境行为和生物效应的关系
谭聪1, 刘洋1, 何莹1, 李洋1, 李博文1, 仇浩2
1 昆明理工大学环境科学与工程学院,云南省土壤固碳与污染控制重点实验室,昆明 650500
2 上海交通大学环境科学与工程学院,上海 200240
Relationships Between the Properties of Metal-based Nanoparticles with Different Particle Sizes and Their Environmental Behaviors and Biological Responses
TAN Cong1, LIU Yang1, HE Ying1, LI Yang1, LI Bowen1, QIU Hao2
1 Provincial Key Laboratory of Soil Carbon Sequestration and Pollution Control, Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China
2 School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
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摘要 随着纳米技术的高速发展,金属基纳米颗粒(MNPs)物理化学性质的变化与其环境行为、生物效应之间的关系受到广泛关注。由于独特的物理化学性质,MNPs被应用于农业、化工、航天等各个领域,其不可避免地释放到环境中,对环境生物及人类健康造成威胁。随着粒径的减小,MNPs展现出较大的比表面积、较高的表面电荷密度和表面能等独特的属性,这些性质在很大程度上影响着MNPs的界面反应及生物效应。本文综述了不同粒径MNPs的比表面积、表面官能团、表面能及表面电荷密度变化与其吸附、聚集、溶解等环境行为的关系,深入剖析了不同粒径的MNPs在不同环境条件(如溶解性有机质(DOM)、光照、pH值、离子强度)下的生物效应及个中机理,就现有研究中存在的问题提出了改进意见与建议。
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谭聪
刘洋
何莹
李洋
李博文
仇浩
关键词:  纳米颗粒  金属基  粒径  环境行为  生物效应    
Abstract: With the rapid development of nanotechnology, relationships between the varying physicochemical properties of metal-based nanoparticles (MNPs) and their environmental behaviors or biological responses have recently received intensive attentions from researchers and policy makers. Due to the unique physiochemical properties, MNPs have been applied in various fields including agriculture, chemistry, aerospace and so on. This inevitably leads to their release into the environment, posing a great threat to environmental living organisms or even the human health. With the decrease of particle size, the properties of MNPs can be also altered such as showing a larger specific surface area, an increased surface charge density and surface energy as compared with bulk materials, which greatly affects the interface reactions and biological effects of MNPs. This paper thus reviewed the relationships between the specific surface area, the surface functional groups, the surface energy or the surface charge density of MNPs at different particle sizes and their environmental behaviors such as adsorption, aggregation and dissolution. The biological effects and the underlying mechanisms of MNPs at different particle sizes were deeply analyzed under different environmental conditions (e.g. dissolved organic matter (DOM), illumination, pH value and ionic strength). Some suggestions were put forward to improve the existing research.
Key words:  nanoparticles    metal-based    particle size    environmental behaviors    biological responses
               出版日期:  2021-04-10      发布日期:  2021-04-22
ZTFLH:  TB303  
基金资助: 云南省基础研究专项面上项目(202001AT070042);云南省万人计划(YNWR-QNBJ-2019-065);国家自然科学基金青年基金(41703111);地区基金(41967039);昆明理工大学省级人才培养项目(KKSY201622012)
作者简介:  谭聪,2018年6月毕业于陕西理工大学,获得理学学士学位。现为昆明理工大学环境科学与工程学院硕士研究生,在刘洋副教授的指导下进行研究。目前主要研究领域为不同粒径氧化铜纳米颗粒的环境行为与生物毒性。
刘洋,昆明理工大学环境科学与工程学院副教授。2009年7月本科毕业于中国农业大学水利与土木工程学院农业建筑环境与能源工程系,2011年9月取得中国农业大学水利与土木工程学院农业建筑环境与能源工程系硕士学位,2015年在荷兰莱顿大学理学院环境科学系获得博士学位。2017年8月至今在昆明理工大学环境科学与工程学院环境科学系工作,副教授,硕士研究生导师,2019年入选云南省“万人计划”。主要从事污染物生态毒性效应评价与预测、混合污染物毒性作用机理、纳米材料的环境行为及健康风险评价、天然有机质与污染物的相互作用、生物炭中自由基的生物效应的研究。近年来在环境科学领域发表文章近20篇,包括Environmental Science & Technology、Environmental Pollution、Water Research、Chemosphere、Frontiers of Environmental Science & Engineering等。
引用本文:    
谭聪, 刘洋, 何莹, 李洋, 李博文, 仇浩. 不同粒径金属基纳米颗粒的性质与其环境行为和生物效应的关系[J]. 材料导报, 2021, 35(7): 7121-7126.
TAN Cong, LIU Yang, HE Ying, LI Yang, LI Bowen, QIU Hao. Relationships Between the Properties of Metal-based Nanoparticles with Different Particle Sizes and Their Environmental Behaviors and Biological Responses. Materials Reports, 2021, 35(7): 7121-7126.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19110024  或          http://www.mater-rep.com/CN/Y2021/V35/I7/7121
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