Research Progress in Preparation of Super-hydrophobic Surface of Metal Matrix by Laser Processing
ZHENG Boyuan1,2, DI Yuelan2, WANG Haidou1,2, KANG Jiajie1, LIU Tao2
1 School of Engineering and Technology, China University of Geosciences (Beijing),Beijing 100083, China 2 National Key Laboratory for Remanufacturing, Academy of Army Armored Forces, Beijing 100072, China
Abstract: Metal materials are widely used, but are susceptible to corrosion. The super-hydrophobic coating prepared on the surface of the metal substrate can corrode the corrosive medium and improve the corrosion resistance and stain resistance of the metal. In addition, the super-hydrophobic coating can also be applied in anti-icing and antibacterial applications, giving the metal material a wider range of functions and application scenarios. In order to achieve superhydrophobicity, firstly, low surface free energy is required, so that the droplets are not easily spread on the surface; secondly, it is necessary to construct a rough micro-nano structure in order to retain air and increase the gas-liquid contact area. There are many methods for preparing superhydrophobic coatings, but many conventional processing methods are not suitable due to the high hardness of the metal materials and the high melting point. For metal materials, common superhydrophobic surface preparation methods are: chemical etching, electrochemical methods, hydrothermal methods, vapor deposition, and so on. However, these methods have poor controllability and stability, and it is often difficult to process the desired surface structure. As a method for preparing super-hydrophobic surface, laser etching has the cha-racteristics of environmental protection, controllability and stability. It can directly form specific micro-nano structures on the surface and is suitable for metal material processing and has received extensive attention in recent years. Different laser processing parameters and scanning paths can be used to machine different surface micro-nano structures. Research on the effects of various laser processing parameters on surface structure has been carried out. Common laser processing parameters include: spot parameters, energy density, number of pulses, scanning speed, scanning pitch, and spot lap rate. These parameters will have different effects on the surface structure. At present, surface micro-nanostructures prepared by laser using good hydrophobic properties include micro-square column structure, micro-mesh structure, micro-groove structure, micro-sinusoidal protrusion structure, Gaussian lattice structure, and laser-induced periodic surface structure. Based on the theory of super-hydrophobicity, this paper introduces the influence of various laser parameters on the surface structure, the characteristics and hydrophobic properties of different micro-nanostructures, and the surface treatment after etching. Finally, this paper summarizes the main points of laser preparation of super-hydrophobic surface of metal matrix, and sorts out some existing problems.
郑博源, 底月兰, 王海斗, 康嘉杰, 刘韬. 激光加工制备金属基体超疏水表面的研究进展[J]. 材料导报, 2020, 34(23): 23109-23120.
ZHENG Boyuan, DI Yuelan, WANG Haidou, KANG Jiajie, LIU Tao. Research Progress in Preparation of Super-hydrophobic Surface of Metal Matrix by Laser Processing. Materials Reports, 2020, 34(23): 23109-23120.
1 Barthlott W, Neinhuis C. Planta,1997,202,1. 2 Liu B, Xu W F, Li H, et al. Chemical Journal of Chinese Universities,2013,34(9),2191(in Chinese). 刘兵,徐万飞,李红,等.高等学校化学学报,2013,34(9),2191. 3 Feng L, Zhang Y, Cao Y, et al. Soft Matter,2011,7,2977. 4 Feng L, Zhang Y, Xi J, et al. Langmuir,2008,24,4114. 5 Zheng Y, Gao X, Jiang L. Soft Matter,2007,3,178. 6 Wu D, Wang J N, Wu S Z, et al. Advanced Functional Materials,2011,21,2927. 7 Gao X, Jiang L. Nature,2004,432,36. 8 Liu T, Lau K T, Chen S G, et al. Advanced Materials Research,2008,47,173. 9 Herbots N, Watson C F, Culbertson E J, et al. MRS Advances,2016,1,2141. 10 Zhang H, Lamb R, Lewis J. Science and Technology of Advanced Mate-rials,2005,6,236. 11 Wei C Q, Jin B Y, Zhang Q H, et al. Journal of Alloys and Compounds,2018,765,721. 12 Ding S, Xiang T, Li C, et al. Materials & design,2016,117,280. 13 Nagai H, Irie T, Takahashi J, et al. Biosensors and Bioelectronics,2007,22,1968. 14 Gao H, Sun P, Zhang Y, et al. Surface and Coatings Technology,2018,339,147. 15 Ramos Chagas G, Morán Cruz, Gabriela M, et al. Applied Surface Science,2018,452,352. 16 Long J, Fan P, Jiang D, et al. Advanced Materials Interfaces,2016,3,1600641. 17 Young T. Philosophical Transactions of the Royal Society of London,1805,95,65. 18 Wenzel, Robert N. Transactions of the Faraday Society,1936,28,988. 19 Cassie A B D, Baxter S. Transactions of the Faraday Society,1944,40,546. 20 Herminghaus S. Europhysics Letters,2000,52,165. 21 Nosonovsky M, Bhushan B. Microelectronic Engineering,2007,84,382. 22 Nosonovsky M, Bhushan B. Journal of Physics Condensed Matter,2008,20,395005. 23 Patankar, Neelesh A. Langmuir,2003,19(4),1249. 24 Bhushan B, Jung Y C. Journal of Physics Condensed Matter,2008,20,225010. 25 Mannion P T, Magee J, Coyne E, et al. Applied Surface Science,2004,233,275. 26 Yuan D Q, Zhou M, Cai L, et al. Spectroscopy and Spectral Analysis,2009(6),1454(in Chinese). 袁冬青,周明,蔡兰,等.光谱学与光谱分析,2009(6),1454. 27 Zhou S Q, Ma G J, Wang C H, et al. Chinese Journal of Lasers,2016(9),76(in Chinese). 周树清,马国佳,王春华,等.中国激光,2016(9),76. 28 Moradi S, Kamal S, Englezos P, et al. Nanotechnology,2013,24,415302. 29 Fu X, Zhang F, Jiang M, et al. Laser Technology,2014,38(4),435(in Chinese). 傅茜,张菲,蒋明,等.激光技术,2014,38(4),435. 30 Li T. A study on process technology and surface wettability of picosecond laser texturing metal. Master’s Thesis, Huazhong University of Science and Technology, China,2017(in Chinese). 李田.金属表面皮秒激光纹理刻蚀工艺及润湿性能研究.硕士学位论文,华中科技大学,2017. 31 Wu X F. Research on the wettability of micro/nano structured solid surface fabricated by femtosecond laser. Master’s Thesis, Changchun University of Science and Technology, China,2017(in Chinese). 吴先福.飞秒激光制备固体润湿性能微纳结构表面的研究.硕士学位论文,长春理工大学,2017. 32 Zhou S Q. The research of bionic hydrophobic surface induced by femtosecond laser. Master’s Thesis, Hefei University of Technology, China,2017(in Chinese). 周树清.仿生疏水表面飞秒激光制备研究.硕士学位论文,合肥工业大学,2017. 33 Zhang S J, Li Y, Liu Z P, et al. Applied Physics Letters,2014,105,061101. 34 Pou P, Del Val J, Riveiro A, et al. Applied Surface Science,2019,475,896. 35 Zhao X, Xue Y, Yang H, et al. Surface Engineering,2019,1,267. 36 Juanjuan S, Deren W, Leyong H, et al. Applied Surface Science,DOI:S0169433218315551. 37 Song Y, Wang C, Dong X, et al. Optics & Laser Technology,2018,102,25. 38 Sarbada S, Shin Y C. Applied Surface Science,2017,405,465. 39 Cai Y K, Chang W L, Luo X C, et al. Precision Engineering,2018,52,266. 40 Li S Y. Construction of the bionic-structured superhydrophobic surface and antimicrobial application. Master’s Thesis, Jilin University, China,2018(in Chinese). 李淑一.仿生结构化超疏水表面的构筑与抗菌应用.硕士学位论文,吉林大学,2018. 41 Long J, Zhong M, Fan P, et al. Journal of Laser Applications,2015,27,S29107. 42 Yan X, Huang Z, Sett S, et al. ACS Nano,2019,13,4160. 43 Ta D V, Dunn A, Wasley T J, et al. Applied Surface Science,2015,357,248. 44 Sciancalepore C, Gemini L, Romoli L, et al. Surface and Coatings Technology,2018,352,370. 45 Trdan U, Hoevar M, Gregori P. Corrosion Science,2017,123,21. 46 Kietzig A M, Hatzikiriakos S G, Englezos P. Langmuir,2009,25,4821. 47 Ngo C V, Chun D M. Applied Surface Science,2017,409,232. 48 Long J, Zhong M, Zhang H, et al. Journal of Colloid and Interface Science,2014,441C,1. 49 Yang Z, Liu X, Tian Y. Journal of Colloid and Interface Science,2019,533,268. 50 Huang J Y, Wei S B, Zhang L X, et al. Materials,2019,12,1155. 51 Wang X C, Wang B, Xie H, et al. Journal of Physics D Applied Physics,2018,51,115305. 52 Wu B, Zhou M, Li B J, et al. Journal of Functional Materials,2013,44(24),3658(in Chinese). 吴勃,周明,李保家,等.功能材料,2013,44(24),3658.
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2020, Vol. 34 
