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材料导报  2021, Vol. 35 Issue (5): 5062-5066    https://doi.org/10.11896/cldb.20020107
  无机非金属及其复合材料 |
GaAs材料在光电化学电池中的稳定性
曹诗瑶, 闫小琴
北京科技大学材料科学与工程学院,北京 100083
The Stability of GaAs in Photoelectrochemical Cells
CAO Shiyao, YAN Xiaoqin
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
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摘要 光电化学水分解制氢被誉为人工光合作用,其利用太阳能将水分解为氢气和氧气,是未来可持续能源体系潜在的重要能源转换手段。随着光电化学电池的发展,光电化学电池的转换效率得到了大幅提升,然而光电化学电池的使用寿命却与实际应用标准寿命(10年)相差甚远。
光电化学电池材料体系中Ⅲ-Ⅴ族半导体GaAs由于其优异的光物理性能逐步受到科学家们的广泛关注。然而,GaAs在光电化学体系中存在严重的光腐蚀问题。如何在充分发挥GaAs本征优势的前提下提升其在电解液中的稳定性近年来已成为Ⅲ-Ⅴ族半导体研究的热点。研究表明,针对不同环境下GaAs电极的腐蚀机制设计不同保护层薄膜对GaAs进行防护,能有效地在保证转换效率的前提下延长GaAs电极的寿命。
本文从GaAs材料在不同酸碱性电解液中的腐蚀机理出发,针对GaAs在不同溶液环境中的有效保护措施进行综述,着重阐述了现有手段对GaAs材料在溶液中稳定性提升的成果,同时展望了GaAs材料的未来发展趋势。
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曹诗瑶
闫小琴
关键词:  GaAs  光腐蚀  稳定性  保护层  光电化学水分解    
Abstract: Photoelectrochemical water splitting is renowned as artificial photosynthesis. It converts solar energy and splits water into hydrogen and oxygen. It is a potentially important energy conversion method for future sustainable energy systems. With the development of photoelectroche-mical cells, the energy conversion efficiency improved greatly. However, the lifetime of the photoelectrochemical cell is far from the actual application standard of 10 years.
The excellent photo-physical properties have brought the Ⅲ-Ⅴ semiconductor GaAs under the spotlight. However, GaAs suffers from serious photocorrosion in photoelectrochemical systems. How to improve its stability in electrolyte under the premise of giving full play to its inherent advantages has become a research hotspot of Ⅲ-Ⅴ semiconductors in recent years. Studies have shown that designing different protective films to protect GaAs according to the corrosion mechanism of GaAs electrodes in different environments can effectively extend the lifetime of GaAs electrodes while ensuring conversion efficiency.
This article starts from the corrosion mechanism of GaAs materials in different acid and alkaline electrolytes, and summarizes the effective protection measures of GaAs in different solution environments. This review focuses on the results of existing methods for improving the stability of GaAs materials in solution. Moreover, the future development of GaAs in photoelectrochemical field is prospected.
Key words:  GaAs    photocorrosion    stability    protection layer    photoelectrochemical water splitting
               出版日期:  2021-03-10      发布日期:  2021-03-12
ZTFLH:  TB303  
通讯作者:  xqyan@mater.ustb.edu.cn   
作者简介:  闫小琴教授,博士研究生导师。2004年获得中科院物理所理学博士学位,2004—2007年在日本东北大学金属材料研究所做博士后研究,2005年4月获得日本学术振兴会外国人特别研究员奖。2007年以422优秀人才被引进,在北京科技大学材料科学与工程学院工作,2008年入选北京市科技新星计划,2009年获得教育部新世纪优秀人才计划支持。参加国家重大科学研究计划项目、国家科技部和基金委重点项目、重大国际合作项目及自然基金项目多项。负责国家基金委面上项目、教育部项目等6项。主要研究方向为纳米功能材料及能量转换器件,纳米材料的图案化生长,新材料的拉曼光谱等。在国内外重要学术期刊上发表多篇SCI文章,包括Science、Advanced Materials、Phys. Rev. Lett.、Nano Lett.等期刊论文。
曹诗瑶博士,2020年毕业于北京科技大学材料科学与工程学院并获得工学博士学位,目前主要研究领域专注于一维纳米材料的制造和光电化学水分解。参加国家重大科学研究计划项目、国家科技部和基金委重点项目、重大国际合作项目及自然基金项目多项。负责国家基金委面上项目、教育部项目等6项。主要研究方向为纳米功能材料及能量转换器件,纳米材料的图案化生长,新材料的拉曼光谱等。在国内外重要学术期刊上发表多篇SCI文章,包括Science、Advanced Materials、Phys. Rev. Lett.、Nano Lett.等期刊论文。
曹诗瑶博士,2020年毕业于北京科技大学材料科学与工程学院并获得工学博士学位,目前主要研究领域专注于一维纳米材料的制造和光电化学水分解。
引用本文:    
曹诗瑶, 闫小琴. GaAs材料在光电化学电池中的稳定性[J]. 材料导报, 2021, 35(5): 5062-5066.
CAO Shiyao, YAN Xiaoqin. The Stability of GaAs in Photoelectrochemical Cells. Materials Reports, 2021, 35(5): 5062-5066.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20020107  或          http://www.mater-rep.com/CN/Y2021/V35/I5/5062
1 Veziroglu T N. International Journal of Hydrogen Energy,1998,23,1077.
2 Fujishima A, Kohayakawa K, Honda K. Journal of the Electrochemical Society,1975,122,1487.
3 Fujishima A, Honda K. Nature,1972,238,37.
4 Qiu Y, Leung S-F, Zhang Q, et al. Nano Letters,2014,14,2123.
5 Lin Y, Xu Y, Mayer M T, et al. Journal of the American Chemical Society,2012,134,5508.
6 Mayer M T, Du C, Wang D. Journal of the American Chemical Society,2012,134,12406.
7 Hwang Y J, Boukai A, Yang P. Nano Letters,2008,9,410.
8 Cui X, Ma M, Zhang W, et al. Electrochemistry Communications,2008,10,367.
9 Park J H, Kim S, Bard A J. Nano Letters,2006,6,24.
10 Mor G K, Varghese O K, Wilke R H, et al. Nano Letters,2008,8,1906.
11 Ni M, Leung M K, Leung D Y, et al. Renewable and Sustainable Energy Reviews,2007,11,401.
12 Barroso M, Cowan A J, Pendlebury S R, et al. Journal of the American Chemical Society,2011,133,14868.
13 Wang X, Peng K Q, Hu Y, et al. Nano Letters,2013,14,18.
14 Wolcott A, Kuykendall T R, Chen W, et al. The Journal of Physical Chemistry B,2006,110,25288.
15 Su J, Feng X, Sloppy J D, et al. Nano Letters,2011,11,203.
16 Gao L, Cui Y, Wang J, et al. Nano Letters,2014,14,3715.
17 Wang P, Huang B, Dai Y, et al. Physical Chemistry Chemical Physics,2012,14,9813.
18 Lee M H, Takei K, Zhang J, et al. Angewandte Chemie International Edition,2012,51,10760.
19 Pinaud B A, Benck J D, Seitz L C, et al. Energy & Environmental Science,2013,6,1983.
20 Jiang C, Moniz S J A, Wang A, et al. Chemical Society Reviews,2017,46,4645.
21 Jin J, Walczak K, Singh M R, et al. Energy & Environmental Science,2014,7,3371.
22 Seger B, Castelli I E, Vesborg P C, et al. Energy & Environmental Science,2014,7,2397.
23 Bae D, Seger B, Vesborg P C, et al. Chemical Society Reviews,2017,46,1933.
24 Tromans D, Liu G G, Weinberg F. Corrosion Science,1993,35,117.
25 Allongue P, Blonkowski S. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry,1991,317,77.
26 Gerischer H, Mindt W. Electrochimica Acta,1968,13,1329.
27 Frese Jr K, Madou M, Morrison S R. The Journal of Physical Chemistry,1980,84,3172.
28 Collins M, Ratcliffe C, Ripmeester J. Journal of Physical Chemistry,1990,94,157.
29 Vanmaekelbergh D, Hoogendam C, Kelly J. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry,1989,270,175.
30 Gerischer H, Lübke M. Berichte der Bunsengesellschaft für physikalische Chemie,1983,87,123.
31 Gerischer H, Lübke M. Journal of the Electrochemical Society,1988,135,2782.
32 Allongue P, Cachet H. Journal of the Electrochemical Society,1984,131,2861.
33 Allongue P, Cachet H. Electrochimica Acta,1988,33,79.
34 Young J L, Steirer K X, Dzara M J, et al. Journal of Materials Chemistry A,2016,4,2831.
35 Huang Y, Luo J, Ivey D G. Materials Chemistry and Physics,2005,93,429.
36 Osakabe S, Adachi S. Japanese Journal of Applied Physics,1997,36,7119.
37 Horowitz G, Garnier F. Journal of the Electrochemical Society,1985,132,634.
38 Horowitz G, Tourillon G, Garnier F. Journal of the Electrochemical Society,1984,131,151.
39 Garner L E, Steirer K X, Young J L, et al. ChemSusChem,2017,10,767.
40 Lebedev M V, Calvet W, Mayer T, et al. The Journal of Physical Chemistry C,2014,118,12774.
41 Yang F, Nielander A C, Grimm R L, et al. The Journal of Physical Chemistry C,2016,120,6989.
42 Kornblum L, Fenning D P, Faucher J, et al. Energy & Environmental Science,2017,10,377.
43 Sun K, Saadi F H, Lichterman M F, et al. Proceedings of the National Academy of Sciences,2015,112,3612.
44 Hu S, Shaner M R, Beardslee J A, et al. Science,2014,344,1005.
45 Kang D, Young J L, Lim H, et al. Nature Energy,2017,2,17043.
46 Lin Y, Battaglia C, Boccard M, et al. Nano Letters,2013,13,5615.
47 Nielander A C, Shaner M R, Papadantonakis K M, et al. Energy & Environmental Science,2015,8,16.
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