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材料导报  2020, Vol. 34 Issue (20): 20034-20039    https://doi.org/10.11896/cldb.19070258
  无机非金属及其复合材料 |
基于表面能理论的破碎卵石与沥青粘附性能研究
耿九光1, 兰倩1, 刘光军2, 周恒玉2, 刘润喜2
1 长安大学材料科学与工程学院,西安 710064
2 中交二公局第四工程有限公司,洛阳 471013
Study on Adhesion Properties of Broken Pebble and Asphalt Based on Surface Energy Theory
GENG Jiuguang1, LAN Qian1, LIU Guangjun2, ZHOU Hengyu2, LIU Runxi2
1 School of Material Science and Engineering, Chang’an University, Xi’an 710064, China
2 China Communications Second Public Office Fourth Engineering Co., Ltd., Xi’an 471013, China
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摘要 针对破碎卵石成分复杂且随着粒径变化其成分存在差异这一问题,基于表面能理论研究了不同粒径破碎卵石与沥青的粘附性能。采用躺滴法和毛细管上升法分别测试沥青和破碎卵石的表面能,并计算沥青与破碎卵石体系的粘附功以及剥落功;采用综合能量比(CER)来评价四种沥青混合料中破碎卵石与沥青的粘附性能。结果表明:抗剥落剂的加入会使沥青的表面能降低、极性分量升高、色散分量降低;由于不同粒径的破碎卵石的化学成分、矿物成分、表面电荷不同,导致不同粒径的破碎卵石的表面能不同,从大到小排序为5~10 mm、10~15 mm、3~5 mm、0~3 mm;0~3 mm和3~5 mm的破碎卵石与SK90沥青、SBS改性沥青以及添加抗剥落剂的SK90沥青和SBS改性沥青的粘附功都优于5~10 mm和10~15 mm的破碎卵石,0~3 mm和5~10 mm的破碎卵石与这四种沥青的剥落功都小于3~5 mm和10~15 mm的破碎卵石,这表明不同粒径的破碎卵石与沥青粘附性的配伍性不同;混合料的水稳定性能试验表明,CER这一指标评价破碎卵石与沥青的粘附性能是合理的,并且CER可以作为沥青-破碎卵石系统材料组合的选择依据,这为破碎卵石在实际工程中的应用提供了理论和技术支持。
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耿九光
兰倩
刘光军
周恒玉
刘润喜
关键词:  表面能理论  破碎卵石  粘附性能  水稳定性  综合能量比    
Abstract: Aiming at the problem that the composition of broken pebbles is complex and its composition varies with particle size, based on the surface energy theory, the adhesion properties of asphalt and broken pebbles with different particle sizes were studied. The surface energy of asphalt and broken pebble was tested by sessile drop method and capillary rise method, and the adhesion work and peeling work of asphalt and broken pebble system were calculated. The comprehensive energy ratio (CER) was used to evaluate the adhesion properties of broken pebbles and asphalt in the four asphalt mixtures. The results show that the addition of anti-stripping agent will reduce the surface energy of the asphalt, increase the polar component, and reduce the dispersion component. Due to the different chemical composition, mineral composition and surface charge of broken pebble with different particle sizes, the surface energy of broken pebble with different particle sizes is different and the order from large to small is 5—10 mm, 10—15 mm, 3-5 mm, 0—3 mm. The adhesion work of 0—3 mm and 3—5 mm broken pebbles to SK90 asphalt, SBS modified asphalt,SK90 asphalt and SBS modified asphalt with anti stripping agent are better than that of 5—10 mm and 10—15 mm broken pebbles, and the peeling work of 0—3 mm and 5—10 mm broken pebbles to these four kinds of asphalt are less than that of 3—5 mm and 10—15 mm broken pebbles, which shows that the compatibility of different particle size broken pebbles and asphalt is different in adhesion perfor-mance. The results of water stability test of the mixture show that it is reasonable to evaluate the adhesion performance of broken pebble and asphalt with CER, and the size of CER can be used as the basis for selecting the material combination of asphalt aggregate system (especially the aggregate with complex composition),which provides theoretical and technical support for the application of broken pebbles in actual engineering.
Key words:  surface energy theory    broken pebble    adhesion properties    water stability    comprehensive energy ratio
               出版日期:  2020-10-25      发布日期:  2020-11-06
ZTFLH:  U414  
基金资助: 陕西省重点研发计划(2018SF-380);国家自然科学基金(51608045);中央高校基本科研业务费资助项目 (310831173701);江西省交通科技计划项目(2016C0005)
通讯作者:  1085173844@qq.com   
作者简介:  耿九光,2004年毕业于长安大学,获化学工程与工艺专业学士学位,2007年获长安大学材料学硕士学位,2009年获长安大学道路与铁道工程博士学位。 现任职于长安大学材料学院材料科学与工程系,主要从事路面结构与材料研究(包括改性沥青、路面再生技术和新型道路材料研究等),发表相关学术论文四十余篇,参与的3项科研项目获得省级科技进步奖。现主持国家自然科学基金青年项目一项,中国博士后科学基金项目一项,横向委托项目三项。
兰倩,2017年毕业于长安大学,获学士学位。现就读于长安大学,主要从事路面材料研究。
引用本文:    
耿九光, 兰倩, 刘光军, 周恒玉, 刘润喜. 基于表面能理论的破碎卵石与沥青粘附性能研究[J]. 材料导报, 2020, 34(20): 20034-20039.
GENG Jiuguang, LAN Qian, LIU Guangjun, ZHOU Hengyu, LIU Runxi. Study on Adhesion Properties of Broken Pebble and Asphalt Based on Surface Energy Theory. Materials Reports, 2020, 34(20): 20034-20039.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19070258  或          http://www.mater-rep.com/CN/Y2020/V34/I20/20034
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