多级结构超疏水表面的制备与性能分析

doi:10.11896/cldb.22100133

材料导报

2024, Vol. 38

Issue (9): 22100133-5 https://doi.org/10.11896/cldb.22100133

高分子与聚合物基复合材料

多级结构超疏水表面的制备与性能分析

位振^1,2, 戴飞², 何强^1,2,*

1 中国民用航空飞行学院民航安全工程学院,四川广汉 618307
2 甘肃农业大学机电工程学院,兰州 730000

Preparation and Performance Analysis of Superhydrophobic Surface with Multilevel Structure

WEI Zhen^1,2, DAI Fei², HE Qiang^1,2,*

1 Civil Aviation Safety Engineering College of Civil Aviation Flight Academy of China, Guanghan 618307, Sichuan, China
2 School of Mechanical and Electrical Engineering, Gansu Agricultural University, Lanzhou 730000, China

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摘要随着橡胶产品应用的广泛拓展,具备超疏水性能的橡胶产品越来越受关注。然而如何便捷、大规模地制备超疏水表面对橡胶的疏水应用具有重要的意义。本工作通过在未硫化的氟硅橡胶表面喷涂一层二氧化硅粒子,构造第一层级微观结构,然后通过模板法在氟硅橡胶表面成功地复制了不锈钢编织网的结构,构造了第二层级结构,并分析了构造的氟硅橡胶表面的官能团存在情况、微观结构、疏水性能以及液滴弹跳和自清洁性能。结果表明:通过模板法和喷涂技术在氟硅橡胶表面制备的多级微观结构为液滴提供了支持力和排斥作用,其静态接触角为(156.7±0.97)°,滚动角为1°。并且构建的多级结构表面具有优异的液滴弹跳性能和良好的自清洁性能。在氟硅橡胶表面构建多级结构可以极大地提升表面的疏水性能,为制备超疏水表面提供一种新的思路。

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	位振
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关键词: 多级结构喷涂法模板法氟硅橡胶超疏水

Abstract: With the extensive application of rubber products, more and more attention has been paid to rubber products with superhydrophobic properties. However, how to prepare superhydrophobic surface conveniently and on a large scale is of great significance to the application of rubber. In this work, a layer of silicon dioxide particles was sprayed on the surface of unvulcanized fluorosilicone rubber to construct the first-level microstructure. Then the structure of stainless steel woven net was successfully replicated on the surface of fluorosilicone rubber by template method, and the second hierarchical structure was constructed. The existence of functional groups, microstructure, hydrophobicity, droplet bounce and self-cleaning performance of the surface of the fluorosilicone rubber were analyzed. The results show that the multilevel microstructure prepared on the surface of fluorosilicone rubber by template method and spraying technology provide the supporting force and repelling effect for the droplets, and its static contact angle is (156.7±0.97)° and rolling angle is 1°. And the constructed multilevel structure surface had excellent droplet bouncing performance and good self-cleaning performance. Constructing multilevel structure on the surface of fluorosilicone rubber can greatly improve the hydrophobicity of the surface, which provided a new idea for preparing superhydrophobic surface.

Key words: multilevel structure spraying method template method fluorosilicone rubber superhydrophobic

出版日期: 2024-05-10 发布日期: 2024-05-13

ZTFLH:

TQ333

基金资助: 2023年四川省科技计划项目(23NSFSC1923)

通讯作者: * 何强,中国民用航空飞行学院民航安全工程学院教授、博士研究生导师。2012年西安理工大学精仪专业博士毕业。目前主要从事电动飞机、轴承密封等方面的研究工作。发表论文160余篇,包括Coordination Chemistry Reviews、Journal of Colloid And Interface Science、Progress in Organic Coa-tings、Colloids and Surfaces A: Physicochemical and Engineering Aspects、ACS Omega、Polymer Testing等。aystar@163.com

作者简介: 位振,2019年7月毕业于新乡学院机械设计制造及其自动化专业,获得学士学位。现为甘肃农业大学机电工程学院硕士研究生,在何强教授和戴飞教授的指导下进行研究。目前主要进行多功能复合材料的制备与机理研究。

引用本文:

位振, 戴飞, 何强. 多级结构超疏水表面的制备与性能分析[J]. 材料导报, 2024, 38(9): 22100133-5.
WEI Zhen, DAI Fei, HE Qiang. Preparation and Performance Analysis of Superhydrophobic Surface with Multilevel Structure. Materials Reports, 2024, 38(9): 22100133-5.

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http://www.mater-rep.com/CN/10.11896/cldb.22100133 或 http://www.mater-rep.com/CN/Y2024/V38/I9/22100133

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