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材料导报  2024, Vol. 38 Issue (4): 22090167-14    https://doi.org/10.11896/cldb.22090167
  高分子与聚合物基复合材料 |
化纤织物疏水疏油功能整理的发展概况
黄勇1, 李俊越2, 张栋葛2, 韩津春1, 郁崇文1, 俞建勇3, 丁彬3,*, 李召岭1,3,*
1 东华大学纺织学院,上海 201620
2 无锡小天鹅电器有限公司,江苏 无锡 214111
3 东华大学纺织科技创新中心,上海 201620
Development of Hydrophobic and Oleophobic Functional Finishing of Chemical Fiber Fabrics
HUANG Yong1, LI Junyue2, ZHANG Dongge2, HAN Jinchun1, YU Chongwen1, YU Jianyong3, DING Bin3,*, LI Zhaoling1,3,*
1 College of Textiles, Donghua University, Shanghai 201620, China
2 Wuxi Little Swan Electric Co.,Ltd., Wuxi 214111, Jiangsu, China
3 Innovation Center for Textile Science and Technology, Donghua University, Shanghai 201620, China
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摘要 早期荷叶表面的拒水现象引起了人们极大的兴趣,研究人员基于荷叶效应不断模仿荷叶表面的微纳结构,以获得可以比拟荷叶的超疏水表面。将超疏水表面应用于化纤织物有着巨大的应用前景,基于荷叶效应,可以通过构筑粗糙纹理表面的方法制备超疏水表面,但有些液体悬浮在纹理表面的稳定性较差,因此适用性有限。通过化学方法合成的含氟整理剂能够降低材料的表面能,使材料对大部分表面能较高的液体具有抵抗作用,使用含氟整理剂整理是目前制备超疏水表面的主流方法。但不论是构筑粗糙表面还是使用含氟整理剂整理,都无法使超疏水表面在极端环境下保持较好的拒液效果。通过在材料表面构建自愈合体系可以获得具有长久拒液效果的自愈合材料,这种超疏水材料的表面在受到机械磨损或化学腐蚀时,受损部位会自愈,从而达到持续的拒液效果。本文主要以化纤织物为例综述了疏水疏油功能整理的方法,阐释了化纤织物的疏水疏油机理,探讨了化纤织物受到化学腐蚀、机械磨损时应如何保持拒液稳定性的问题,并对未来化纤织物疏水疏油功能整理的发展方向进行了展望。
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黄勇
李俊越
张栋葛
韩津春
郁崇文
俞建勇
丁彬
李召岭
关键词:  化纤织物  超疏水表面  疏水疏油功能整理  含氟整理剂  自愈合材料    
Abstract: The water repellent phenomenon on the lotus leaf surface has aroused great research interest in the early period. Based on the lotus leaf effect, researchers constantly imitate micro-nano-structure of the lotus leaf surface in order to obtain a superhydrophobic surface comparable to the lotus leaf. The application of superhydrophobic surface to chemical fiber fabrics has great application prospects, based on the lotus leaf effect, and superhydrophobic surfaces can be prepared by the method of constructing rough texture surface, but some liquids are suspended on the textured surface with poor stability, thus the applicability is limited. Fluorocarbon finishing agents synthesized by chemical methods are able to reduce the surface energy of materials and provide resistance to most liquids with high surface energy, which is currently the mainstream method to prepare superhydrophobic surfaces. However, neither constructing rough surfaces nor finishing with fluorocarbon finishing agents could allow the superhydrophobic surfaces to maintain better water rejection under harsh environments. Self-healing materials with long-lasting liquid rejection effect can be obtained by constructing self-healing system on the surface of materials, and the surface of these superhydrophobic materials would self-heal at damaged sites when subjected to mechanical wear or chemical corrosion, thus achieving a sustained liquid rejection effect. Taking chemical fiber fabrics as an example, this review has summarized the hydrophobic and oil repellent finishing methods of fabrics, explained the hydrophobic and oil repellent mechanism of fabrics, discussed how to maintain the liquid repellent stability when the fabrics are subjected to chemical corrosion and mechanical wear, and gave future outlook of hydrophobic and oil repellent research for the chemical fiber fabrics.
Key words:  chemical fiber fabrics    superhydrophobic surface    hydrophobic and oleophobic functional finishing    fluorine containing finishing agent    self-healing material
出版日期:  2024-02-25      发布日期:  2024-03-01
ZTFLH:  TS195  
基金资助: 国家现代农业产业技术体系资助(CARS-16)
通讯作者:  *丁彬,东华大学科研院院长,2005年获日本庆应大学理工学部工学博士学位并留校任教,期间兼任日本SNT纳米科技会社主任研究员。2007—2008年在美国加州大学戴维斯分校进行博士后研究。国家自科基金委杰青、教育部“长江学者”特聘教授、国家“万人计划”领军人才、爱思唯尔中国高被引学者,主要从事微纳米纤维材料的成型理论和结构设计及其在功能服装、国防军工、环境保护等领域的应用研究。发表SCI论文400余篇,获授权发明专利140余项,已转化21项。主持国家科技部、国家自科基金委、中央军委科技委、华阳集团、德国博世、联合利华等项目40余项;获美国纤维学会“杰出成就奖”、上海市科技进步一等奖、中纺联科技进步一等奖、中国纺织工程学会纺织学术大奖、桑麻学者等10余项奖励及荣誉。
李召岭,东华大学纺织学院研究员、博士研究生导师。2016年获东华大学纺织工程博士学位,2013年11月—2015年6月在美国佐治亚理工学院进行博士联合培养。2019年荣获上海市青年科技启明星,2020年荣获上海市人才发展基金,2022年荣获国家万人计划青年拔尖人才。主要研究方向为智能纤维、生物质纤维及功能纺织品。迄今已发表SCI期刊论文70余篇,研究成果被引用5 700余次,H指数37;参编英文书籍2部,授权中国发明专利21项,主持国家自然科学基金等科研项目20余项。binding@dhu.edu.cn;zli@dhu.edu.cn   
作者简介:  黄勇,2021年7月于西安工程大学获得工学学士学位。现为东华大学纺织学院硕士研究生,在李召岭教授的指导下进行研究。目前主要研究领域为化纤织物疏水疏油功能整理。
引用本文:    
黄勇, 李俊越, 张栋葛, 韩津春, 郁崇文, 俞建勇, 丁彬, 李召岭. 化纤织物疏水疏油功能整理的发展概况[J]. 材料导报, 2024, 38(4): 22090167-14.
HUANG Yong, LI Junyue, ZHANG Dongge, HAN Jinchun, YU Chongwen, YU Jianyong, DING Bin, LI Zhaoling. Development of Hydrophobic and Oleophobic Functional Finishing of Chemical Fiber Fabrics. Materials Reports, 2024, 38(4): 22090167-14.
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http://www.mater-rep.com/CN/10.11896/cldb.22090167  或          http://www.mater-rep.com/CN/Y2024/V38/I4/22090167
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