可见光宽波带减反超疏玻璃的制备工艺及结构探讨

doi:10.11896/cldb.22030191

材料导报

2023, Vol. 37

Issue (18): 22030191-7 https://doi.org/10.11896/cldb.22030191

无机非金属及其复合材料

可见光宽波带减反超疏玻璃的制备工艺及结构探讨

周子吉¹, 孙慧慧¹, 王群¹, 曹文¹, 周忠华^1,2,*, 黄悦^1,*

1 厦门大学材料学院, 福建厦门 361005
2 福建省先进材料重点实验室, 福建厦门 361005

Study on Engineering and Structure of a Wideband Visible Light Low Reflection and Superhydrophobic Glass

ZHOU Ziji¹, SUN Huihui¹, WANG Qun¹, CAO Wen¹, ZHOU Zhonghua^1,2,*, HUANG Yue^1,*

1 College of Materials, Xiamen University, Xiamen 361005, Fujian, China
2 Fujian Key Laboratory of Advanced Materials, Xiamen 361005, Fujian, China

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摘要高透射率和自洁净复合功能化是光伏玻璃研究热点。利用光伏玻璃原片,以乙二胺四乙酸二钠(EDTA-2Na)和乙二胺四乙酸四钠(EDTA-4Na)混合溶液为刻蚀液,通过水热刻蚀,再经十二烷基三乙氧基硅烷(DTES)疏水修饰,成功得到具有可见光宽波带(380~780 nm)减反超疏玻璃。探究了水热温度、反应时间、络合物混合比例、络合物添加量对膜层结构和光学性能的影响,以及疏水剂涂覆工艺和预处理时间对表面润湿性的影响。在160 ℃、8 h,刻蚀液中络合物为EDTA-2Na(40%,体积分数)与EDTA-4Na(60%,体积分数)、EDTA-nNa (0.34 mol/L)总添加量为4%(体积分数)时,所得玻璃的可见光380 ~ 780 nm各个波长的反射率小于1%;总反射率为0.45%,总透射率为98.85%,雾度为0%。采用旋涂法涂DTES进行表面疏水修饰,预水解时间为18 h时,可获得超疏水性能,水接触角为150.86°,滚动角为5.9°。表面疏水修饰对减反射性能影响很小。

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关键词: 减反射超疏水水热刻蚀乙二胺四乙酸钠盐(EDTA-nNa) 十二烷基三乙氧基硅烷(DTES) 光伏玻璃

Abstract: Multiple functionality including high transmittance and self-cleaning is one of the hotspots in current study of photovoltaic glass. Using photovoltaic glass as substrate and EDTA-2Na and EDTA-4Na mixing aqueous solution as etching solution, low reflective in a wideband visible light (380—780 nm) and superhydrophobic glass has been successfully prepared by hydrothermal etching and dodecyltriethoxysilane (DTES) hydrophobic modification. The effects of hydrothermal temperature, reaction time, mixing ratio and amount of complex on the etched glass's structure and optical properties, as well as coating process of hydrophobic agent and pretreatment time on the surface wettability were investigated. When the reaction conditions are 160 ℃ 8 h and the etching agent with EDTA-2Na∶EDTA-4Na = 40%∶60%, total EDTA-nNa(0.34 mol/L) added amount = 4vol%, the reflectance is <1% among 380—780 nm band of visible light, and the total reflectance, total transmittance, haze are 0.45%, 98.85%, 0%, respectively. After modified by DTES spin coating and when the prehydrolysis time is 18 h, the glass surface shows superhydrophobic property with a water contact angle 150.86° and a sliding angle 5.9°. The surface hydrophobic modification has little influence on the antireflection performance.

Key words: antireflection superhydrophobicity hydrothermal etching ethylenediaminetetraacetic acid sodium salt (EDTA-nNa) dodecyltriethoxysilane (DTES) photovoltaic glass

出版日期: 2023-09-25 发布日期: 2023-09-18

ZTFLH:

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基金资助: 福建省科技重大专项(2014HZ0005);厦门大学科技计划(XDHT2017415A)

通讯作者: *周忠华,厦门大学材料学院教授。1998年毕业于日本三重大学,无机材料科学专业博士。1998—2007年任日本东芝陶瓷株式会社开发研究所主任研究员。2007年至今任厦门大学材料学院教授,主要从事玻璃表面功能化、环境净化材料及其应用、纳米材料合成及其应用的研究。zzh@xmu.edu.cn
黄悦,厦门大学材料学院高级工程师。1990年学士毕业于武汉理工大学,材料科学专业。2002年硕士毕业于日本三重大学。2011年至今任厦门大学材料学院高级工程师。主要从事陶瓷材料、玻璃表面功能化、环境净化材料及其应用的研究。y.huang@xmu.edu.cn

作者简介: 周子吉,2019年6月于济南大学获得工学学士学位。现为厦门大学材料学院硕士研究生。目前主要研究领域为减反射玻璃。

引用本文:

周子吉, 孙慧慧, 王群, 曹文, 周忠华, 黄悦. 可见光宽波带减反超疏玻璃的制备工艺及结构探讨[J]. 材料导报, 2023, 37(18): 22030191-7.
ZHOU Ziji, SUN Huihui, WANG Qun, CAO Wen, ZHOU Zhonghua, HUANG Yue. Study on Engineering and Structure of a Wideband Visible Light Low Reflection and Superhydrophobic Glass. Materials Reports, 2023, 37(18): 22030191-7.

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http://www.mater-rep.com/CN/10.11896/cldb.22030191 或 http://www.mater-rep.com/CN/Y2023/V37/I18/22030191

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