Please wait a minute...
材料导报  2023, Vol. 37 Issue (23): 22060183-8    https://doi.org/10.11896/cldb.22060183
  金属与金属基复合材料 |
原位反应在钎焊中的应用
乔瑞林1, 龙伟民1,*, 钟素娟1, 廖志谦2, 樊喜刚3, 魏永强4
1 郑州机械研究所有限公司新型钎焊材料与技术国家重点实验室,郑州 450001
2 洛阳船舶材料研究所,河南 洛阳 471039
3 北京星航机电装备有限公司,北京 100074
4 郑州航空工业管理学院航空宇航学院,郑州 450046
Application of in Situ Reactions in Brazing
QIAO Ruilin1, LONG Weimin1,*, ZHONG Sujuan1, LIAO Zhiqian2, FAN Xigang3, WEI Yongqiang4
1 State Key Laboratory of Advanced Brazing Filler & Technology, Zhengzhou Research Institute of Mechanical Engineering Co., Ltd., Zhengzhou 450001, China
2 Luoyang Ship Material Research Institute, Luoyang 471039, Henan, China
3 Beijing Xinghang Electro-mechnical Equipment Co., Ltd., Beijing 100074, China
4 School of Aerospace Engineering, Zhengzhou University of Aeronautics, Zhengzhou 450046, China
下载:  全 文 ( PDF ) ( 7910KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 作为一种新型复合材料制备技术,原位合成法凭借其操作简单、成本低、与其他工艺的兼容性较好和便于推广等优势,成为近年来研究的热点。将原位反应引入钎焊领域,可以有效解决钎料在制备及使用过程中存在的成形性能差、接头残余应力大、难以润湿母材等问题。本文综合评述了目前关于原位反应在钎料合成中的应用,首先介绍了通过改变成形工艺来原位熔合低熔点高强韧钎料的相关研究,归纳了常见的成形工艺,如层状复合式、挤压复合式、添加金属粉芯及表面镀覆等,之后介绍了利用原位反应生成复合钎料增强相来实现异种材料有效连接的研究进展,最后指出现阶段利用原位反应合成钎料时所存在的问题,并对未来的研究方向进行了展望。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
乔瑞林
龙伟民
钟素娟
廖志谦
樊喜刚
魏永强
关键词:  原位反应  钎料  增强相  异种材料连接    
Abstract: As a new composite material preparation technology, in situ synthesis has become a research hotspot in recent years due to its simple operation, low cost, good compatibility with other processes and easy promotion.The adoption of in situ reaction in brazing technology has also been widely studied, and found to be able to effectively solve the problems such as poor forming performance, large residual stress and difficult wetting of base metal during the preparation and use of brazing filler metal. In this paper, the current application of in situ reaction in brazing filler metal synthesis is reviewed. Firstly, the research on in situ fusion of low melting point and high strength brazing filler metal by changing the forming process is introduced, and the common forming processes, such as layered composite, extrusion composite, adding metal powder core and surface plating, are summarized. After that, the research on effective connection of dissimilar materials by using in situ reaction to generate composite filler metal reinforcement phase is introduced, Finally, the existing problems of in situ synthesis of brazing filler metal at the emerging stage are pointed out, and the future research directions are prospected.
Key words:  in situ reaction    brazing filler metal    reinforcement phase    dissimilar material joining
出版日期:  2023-12-10      发布日期:  2023-12-08
ZTFLH:  TG454  
基金资助: 国家重点研发计划项目(2021YFB3401101)
通讯作者:  * 龙伟民,博士、研究员、博士研究生导师、国家“万人计划”专家、新型钎焊材料与技术国家重点实验室主任。主要从事新型钎焊材料及其生产技术、钎焊工艺与设备研发及应用研究,在国内外学术期刊上发表论文320余篇,出版专著18部,授权发明专利96项,作为第一完成人获国家科技进步二等奖1项,荣获全国创新争先奖。brazelong@163.com   
作者简介:  乔瑞林,硕士研究生,于2021年9月在中国机械科学研究总院郑州机械研究所学习,主要从事新型钎焊工艺开发。
引用本文:    
乔瑞林, 龙伟民, 钟素娟, 廖志谦, 樊喜刚, 魏永强. 原位反应在钎焊中的应用[J]. 材料导报, 2023, 37(23): 22060183-8.
QIAO Ruilin, LONG Weimin, ZHONG Sujuan, LIAO Zhiqian, FAN Xigang, WEI Yongqiang. Application of in Situ Reactions in Brazing. Materials Reports, 2023, 37(23): 22060183-8.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22060183  或          http://www.mater-rep.com/CN/Y2023/V37/I23/22060183
1 Li Y X, Chen C, Yi R X, et al. Journal of Manufacturing Processes, 2020, 60, 608.
2 Matthew W, Jack W, Russell G. International Materials Reviews, 2020, 65(5), 257.
3 Ahn B. Metals, 2021, 11(7), 1037.
4 Zhang Y, Wang X M, Ge Y X, et al. Hot Working Technology, 2014, 43(24), 23 (in Chinese).
张宇, 王小美, 葛禹锡, 等. 热加工工艺, 2014, 43(24), 23.
5 Wang Z Y, Ba J, Ma Q, et al. Journal of Netshape Forming Engineering, 2018, 10(1), 82 (in Chinese).
王泽宇, 霸金, 马蔷, 等. 精密成形工程, 2018, 10(1), 82.
6 Chen B M, Zhang Z Y, Wang M X, et al. Advanced Materials Research, 2010, 160, 35.
7 Lin K Y, Wang W H, Jing R S, et al. Chemicals & Chemistry, 2017, 88, 887.
8 Zhang H, Zhu H G. In: 2nd Annual International Conference on Advanced Material Engineering (AME 2016). Wuhan, 2016,pp. 131.
9 Popov V A, Burghammer M, Rosenthal M, et al. Composites Part B, 2018, 145, 57.
10 Long W M, Zhang G X, Zhang Q K, et al. Welding & Joining, 2015(7), 6 (in Chinese).
龙伟民, 张冠星, 张青科, 等. 焊接, 2015(7), 6.
11 Long W M, Zhang G X, Zhang Q K. Scripta Materialia, 2015, 110, 41.
12 Long W M, Zhang G X, Zhang Q K, et al. Transactions of the China Welding Institution, 2015, 36(11), 1 (in Chinese).
龙伟民, 张冠星, 张青科, 等. 焊接学报, 2015, 36(11), 1.
13 Long W M, Dong B W, Zhang Q K, et al. Transactions of the China Welding Institution, 2017, 38(1), 1 (in Chinese).
龙伟民, 董博文, 张青科, 等. 焊接学报, 2017, 38(1), 1.
14 Long W M, Lu Q B, He P, et al. Journal of Materials Engineering, 2016, 44(6), 17 (in Chinese).
龙伟民, 路全彬, 何鹏, 等.材料工程, 2016, 44(6), 17.
15 Wang M, Zhang G X, Zhong S J, et al. Rare Metal Materials and Engineering, 2021, 50(8), 2859 (in Chinese).
王蒙, 张冠星, 钟素娟, 等. 稀有金属材料与工程, 2021, 50(8), 2859.
16 Wang M. Study on the brazing process and brazing seam performance of CuSn and Ni powder to flux-cored silver solder.Master's Thesis, Academy of Machinery Science and Technology, China, 2021 (in Chinese).
王蒙. CuSn、Ni粉对药芯银钎料钎焊工艺及钎缝性能研究. 硕士学位论文, 机械科学研究总院, 2021.
17 Dong B W, Deng X J, He P. Welding & Joining, 2015(7), 34 (in Chinese).
董博文, 邓小君, 何鹏. 焊接, 2015(7), 34.
18 Dong B W, Zhong S J, Pei Y Y, et al. Rare Metal Materials and Engineering, 2021, 50(10), 3527.
19 Peng F. Inner Mongolia Petrochemical Industry, 2011, 37(2), 112 (in Chinese).
彭芳. 内蒙古石油化工, 2011, 37(2), 112.
20 Song Y Y. Research on the process and mechanism of GNPs-enhanced composite brazing filler metals for brazing SiC ceramics and GH99.Master's Thesis, Harbin Institute of Technology, China, 2018 (in Chinese).
宋延宇. GNPs增强复合钎料钎焊SiC陶瓷与GH99的工艺及机理研究. 硕士学位论文, 哈尔滨工业大学, 2018.
21 Yi R X, Chen C, Shi C, et al. Ceramics International, 2021, 47(15), 20807.
22 Li J, Wang F C, Shi C S, et al. Materials Science & Engineering A, 2021, 799, 140127.
23 Li C. Study on self-whisker connection of Al2O3 ceramics and its brazing with TC4 titanium alloy. Master's Thesis, Harbin Institute of Technology, China, 2013 (in Chinese).
李淳. Al2O3陶瓷的自身晶须连接及其与TC4钛合金的钎焊研究. 硕士学位论文, 哈尔滨工业大学, 2013.
24 Yang M X, Lin T S, He P, et al. Materials Science & Engineering A, 2011, 528(9), 3520.
25 Yang M X, He P, Lin T S. Journal of Materials Science & Technology, 2013, 29(10), 961.
26 Yang M X, Lin T S, He P, et al. Ceramics International, 2011, 37(8), 3029.
27 Yang M X. Microstructure and properties of in-situ TiB whiskers reinforced Al2O3/TC4 brazed joints. Ph.D. Thesis, Harbin Institute of Technology, China, 2012 (in Chinese).
杨敏旋. 原位自生TiB晶须增强Al2O3/TC4钎焊接头组织结构及性能研究. 博士学位论文, 哈尔滨工业大学, 2012.
28 Yang M X, Lin T S, He P. Journal of Alloys and Compounds, 2012, 512(1), 282.
29 Niu G B, Wang D P, Yang Z W,et al. Journal of Technology & Science, 2017, 43(1), 439.
30 Niu G B.Al2O3 Study on vacuum active brazing process and mechanism of ceramics and TiAl alloy. Master's Thesis, Tianjin University, China, 2017 (in Chinese).
牛国宾. Al2O3陶瓷与TiAl合金真空活性钎焊工艺与机理研究. 硕士学位论文, 天津大学, 2017.
31 Wang Y, Yang Z W, Zhang L X, et al. Materials & Design, 2015, 86, 328.
32 Bai D, Yan J Z, Li N, et al. Hot Working Technology, DOI: 10.14158/j.cnki.1001-3814.20211604 (in Chinese).
白冬, 颜家振, 李宁, 等. 热加工工艺, DOI: 10.14158/j.cnki.1001-3814.20211604.
33 Lin G B, Huang J H, Zhang J G, et al. The Chinses Journal of Nonferrous Metals, 2005, 15(9), 1327 (in Chinese).
林国标, 黄继华, 张建纲, 等. 中国有色金属学报, 2005, 15(9), 1327.
34 Song Y Y, Liu D, Song X G, et al. Journal of the American Ceramic So-ciety, 2019, 102(11), 6529.
35 Song Y Y, Liu D, Hu S P, et al. Ceramics International, 2019, 45(7), 8962.
36 Chen Z. Research on the process and mechanism of composite brazing of SiC and Nb.Master's Thesis, Harbin Institute of Technology, China, 2015 (in Chinese).
陈哲. 复合钎料钎焊SiC与Nb的工艺和机理研究. 硕士学位论文, 哈尔滨工业大学, 2015.
37 Song Y Y, Liu D, Hu S P, et al. Journal of the European Ceramic Society, 2018, 39(4), 696.
38 Yang Z W, Zhang L X, He P, et al. Materials Science & Engineering A, 2011, 532, 471.
39 Yang Z W, Zhang L X, Tian X Y, et al. Materials Characterization, 2013, 79, 52.
40 Lin G B, Huang J H. Powder Metallurgy, 2006, 49(4), 345.
41 Lin G B, Huang J H, Zhang H, et al. Materials Transactions, 2006, 47(4), 1261.
42 Xiong J H, Huang J H, Wang Z P, et al. Materials Science and Technology, 2010, 26(3), 356.
43 Ban Y H, Huang J H, Zhang H, et al. Rare Metal Materials and Engineering, 2009, 38(4), 713 (in Chinese).
班永华, 黄继华, 张华, 等. 稀有金属材料与工程, 2009, 38(4), 713.
44 Wang Z P, Huang J H, Ban Y H, et al. Journal of Materials Enginee-ring, 2008(9), 36 (in Chinese).
王志平, 黄继华, 班永华, 等. 材料工程, 2008(9), 36.
45 Xue X Y, Xiong J H, Huang J H, et al. Journal of Materials Enginee-ring, 2010(5), 68 (in Chinese).
薛行雁, 熊进辉, 黄继华, 等. 材料工程, 2010(5), 68.
46 Gao L L, Cai C, Xiong J H, et al. Transactions of the China Welding Institution, 2011, 32(7), 35 (in Chinese).
高玲玲, 蔡创, 熊进辉, 等. 焊接学报, 2011, 32(7), 35.
47 Ba J, Zhang X H, Ning R, et al. Journal of Technology & Science, 2018, 44(9), 10210.
48 Ba J. Study on surface structure control assisted brazing of SiO2-BN Ceramics and TC4 titanium alloy. Master's Thesis, Harbin Institute of Technology, China, 2018 (in Chinese).
霸金. 表面结构调控辅助钎焊SiO2-BN陶瓷与TC4钛合金工艺研究. 硕士学位论文, 哈尔滨工业大学, 2018.
49 Ba J, Li H, Ren B X, et al. Journal of Technology & Science, 2019, 45(6), 8054.
50 Qi J L, Lin J H, Wan Y H, et al. RSC Advances, 2014, 4(109), 64238.
51 Wan Y H. Study on the mechanism of brazing SiO2-BN ceramics and Nb with CNTs reinforced TiNi composite solder. Master's Thesis, Harbin Institute of Technology, China, 2014 (in Chinese).
万禹含. CNTs增强TiNi复合钎料钎焊SiO2-BN陶瓷与Nb的机理研究. 硕士学位论文, 哈尔滨工业大学, 2014.
52 Yang Z W. Design of SiO2-BN ceramic and Invar alloy brazing interlayer and formation mechanism of interface structure. Master's Thesis, Harbin Institute of Technology, China, 2013 (in Chinese).
杨振文. SiO2-BN陶瓷与Invar合金钎焊中间层设计及界面结构形成机理. 硕士学位论文, 哈尔滨工业大学, 2013.
53 Mao Y W, Yu S, Zhang Y Z, et al. Fusion Engineering and Design, 2015, 100, 152.
54 Mao Y W, Wang S, Peng L X, et al. Journal of Materials Science, 2016, 51(4),1671.
55 Guo B B. In situ reaction to generate a reinforcing phase for carbon/copper bonding.Master's Thesis, Wuhan Institute of Technology, China, 2015 (in Chinese).
郭贝贝. 原位反应生成增强相用于碳/铜连接的研究. 硕士学位论文, 武汉工程大学, 2015.
56 Wang S. Study on the role of reinforcing phase in C/Cu connection in composite solder.Master's Thesis, Wuhan Institute of Technology, China, 2017 (in Chinese).
汪盛. 复合钎料中增强相在C/Cu连接中的作用研究. 硕士学位论文, 武汉工程大学, 2017.
57 Mao Y W, Peng L X, Wang S, et al. Journal of Alloys and Compounds, 2017, 716, 81.
58 Mao Y W, Yu S, Deng Q R, et al. Journal of Materials Engineering, 2016, 25(12), 5262.
59 Long W M, Li S N, Shen Y X, et al. Rare Metal Materials and Enginee-ring, 2020, 49(8), 2683.
60 Li K Z, Shen X T, Li H J, et al. Carbon, 2010, 49(4), 1208.
61 Wang Y L, Wang W L, Huang J H, et al. Materials Science & Enginee-ring A, 2019, 759, 303.
62 Wang Y L, Wang W L, Huang J H, et al. Journal of Materials Processing Technology, 2021, 288, 116886.
63 Lin T S, Yang M X, He P, et al. Materials & Design, 2011, 32(8-9), 4553.
64 Shi S F, Cho S H, Goto T, et al. Journal of the American Ceramic Society, 2021, 104(6), 2753.
65 Song X R, Li H J, Zeng X R. Journal of Alloys and Compounds, 2016, 664, 175.
[1] 张冠星, 董宏伟, 钟素娟, 薛行雁, 刘晓芳, 常云峰. BAg30CuZnSn退火过程中组织性能演变[J]. 材料导报, 2023, 37(6): 21070103-4.
[2] 陈晨, 张亮, 王曦, 李木兰. Zn-Al系钎焊材料的研究进展[J]. 材料导报, 2023, 37(22): 22010081-13.
[3] 刘国齐, 李红霞, 杨文刚, 钱凡, 李勇. 镁铝尖晶石原位生成及其对耐火材料结构、性能的影响[J]. 材料导报, 2023, 37(20): 22040125-5.
[4] 郭建新, 周芸, 汪天尧, 闫敬明, 郭路, 左孝青. Al2O3/FeCrNi复合蜂窝载体材料的制备及性能[J]. 材料导报, 2022, 36(9): 20120112-6.
[5] 蔡雨晨, 冯可芹, 周博芳, 陈思潭. Nb对Zr基钎料及钎焊连接SiC陶瓷的影响[J]. 材料导报, 2022, 36(3): 20090283-5.
[6] 李萧, 胡水平, 蔡钰. 固溶温度对碳烯/6061铝基复合材料轧制薄板组织与力学性能的影响[J]. 材料导报, 2022, 36(18): 21010123-6.
[7] 李芳, 李才巨, 彭巨擘, 易健宏, 高鹏, 张家涛, 关洪达, 关一凡. 锡锌系无铅钎料合金化研究进展[J]. 材料导报, 2022, 36(13): 20010038-10.
[8] 杨佳行, 韩永典, 徐连勇. 瞬态电流键合对Sn-Ag-Cu钎料焊点界面反应的影响[J]. 材料导报, 2022, 36(1): 20100132-5.
[9] 司浩, 秦建, 钟素娟, 龙伟民, 王自东, 沈元勋, 董显. 钎涂技术的研究进展[J]. 材料导报, 2021, 35(z2): 333-340.
[10] 汪冲, 朱晓云, 龙晋明. 掺杂导电增强相对铝电极性能的影响[J]. 材料导报, 2021, 35(8): 8082-8087.
[11] 浦娟, 薛松柏, 张雷, 吴铭方, 龙伟民, 王水庆, 钱似舰, 林铁松. CeO2对Ag30CuZnSn药芯银钎料润湿性能及钎焊接头组织与性能的影响[J]. 材料导报, 2021, 35(8): 8134-8139.
[12] 李木兰, 张亮, 姜楠, 孙磊, 熊明月. 纳米颗粒对无铅钎料改性的研究进展[J]. 材料导报, 2021, 35(5): 5130-5139.
[13] 楚军龙, 高增, 王振江, 牛济泰, 陶星空. 低温玻璃钎料钎焊高体积分数SiCp/Al复合材料与电子玻璃的工艺及性能研究[J]. 材料导报, 2021, 35(24): 24062-24067.
[14] 杨平, 毛育青, 李芊芃, 何良刚, 柯黎明. 合金元素对Cu/Sn-/Cu回流焊焊点界面微观结构及剪切性能的影响[J]. 材料导报, 2021, 35(14): 14156-14160.
[15] 杨波, 王启扬, 杨肖, 杨冬梅. 原位反应制备陶瓷基复合相变材料及其工艺研究[J]. 材料导报, 2020, 34(Z1): 128-131.
[1] Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO2/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[2] Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[3] Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[4] Lijing YANG,Zhengxian LI,Chunliang HUANG,Pei WANG,Jianhua YAO. Producing Hard Material Coatings by Laser-assisted Cold Spray:a Technological Review[J]. Materials Reports, 2018, 32(3): 412 -417 .
[5] Zhiqiang QIAN,Zhijian WU,Shidong WANG,Huifang ZHANG,Haining LIU,Xiushen YE,Quan LI. Research Progress in Preparation of Superhydrophobic Coatings on Magnesium Alloys and Its Application[J]. Materials Reports, 2018, 32(1): 102 -109 .
[6] Wen XI,Zheng CHEN,Shi HU. Research Progress of Deformation Induced Localized Solid-state Amorphization in Nanocrystalline Materials[J]. Materials Reports, 2018, 32(1): 116 -121 .
[7] Xing LIANG, Guohua GAO, Guangming WU. Research Development of Vanadium Oxide Serving as Cathode Materials for Lithium Ion Batteries[J]. Materials Reports, 2018, 32(1): 12 -33 .
[8] Hao ZHANG,Yongde HUANG,Yue GUO,Qingsong LU. Technological and Process Advances in Robotic Friction Stir Welding[J]. Materials Reports, 2018, 32(1): 128 -134 .
[9] Laima LUO, Mengyao XU, Xiang ZAN, Xiaoyong ZHU, Ping LI, Jigui CHENG, Yucheng WU. Progress in Irradiation Damage of Tungsten and Tungsten AlloysUnder Different Irradiation Particles[J]. Materials Reports, 2018, 32(1): 41 -46 .
[10] Fengsen MA,Yan YU,Jie ZHANG,Haibo CHEN. A State-of-the-art Review of Cytotoxicity Evaluation of Biomaterials[J]. Materials Reports, 2018, 32(1): 76 -85 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed