Effect of Hf Content on the Microstructure and Superelasticity of Ti49-XNi44Cu6Y1HfX Shape Memory Alloys
ZHAO Guangwei1,2,*, LI Da2, CHEN Jian2, FAND Dong1,2, HUANG Caihua1,2, SHI Zengmin2, YE Yongsheng1,2
1 Hubei Engineering Research Center for Graphite Additive Manufacturing Technology and Equipment, China Three Gorges University, Yichang 443002, Hubei, China 2 College of Mechanical and Power Engineering, China Three Gorges University, Yichang 443002, Hubei, China
Abstract: Ti-Ni-Cu based shape memory alloy has excellent properties such as small phase transformation hysteresis, large recoverable strain and good thermal stability. The purpose of this work is to systematically investigate the effect of substituting Hf for Ti on the microstructure, phase transformation and superelasticity of Ti49-XNi44Cu6Y1HfX (X=0, 2, 6, 10) alloys. The results show that the main microstructure of the alloy at room temperature is B2 austenite and a small amount of compound phase. And one-step martensitic transformation of B2$\rightleftharpoons$B19' occurs during the loading and unloading processes. With the increase of Hf content, the martensitic transformation temperature decreases, the compressive strength and fracture strain of the alloy decrease, and the critical stress of stress-induced martensite increases. In the cycle compression tests with an increased compressive strain of 3%—11%, the alloy exhibits work hardening phenomenon, and the recoverable stress increases with the increase of prestress. The sample of 10%Hf has the largest recoverable strain of 7.9% when the compressive strain is 11%, and the superelasti-city strain is 5.2%.In the cycle compression tests with a constant compressive strain of 7%, the sample of 10%Hf has good cyclic stability and can be completely recovered.
赵光伟, 李达, 陈健, 方东, 黄才华, 石增敏, 叶永盛. Hf含量对Ti49-XNi44Cu6Y1HfX形状记忆合金的组织与超弹性的影响[J]. 材料导报, 2023, 37(9): 21010179-6.
ZHAO Guangwei, LI Da, CHEN Jian, FAND Dong, HUANG Caihua, SHI Zengmin, YE Yongsheng. Effect of Hf Content on the Microstructure and Superelasticity of Ti49-XNi44Cu6Y1HfX Shape Memory Alloys. Materials Reports, 2023, 37(9): 21010179-6.
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