Synthesis of Co-Ni-Mo Ternary Nanomaterials and Study on Their Catalytic Hydrogen Production from Ammonia Borane
LIN Luhe1, ZOU Aihua1,2,*, KANG Zhibing1, GUO Hao3, WANG Jie3
1 School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China 2 School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China 3 Jiangxi Hongdu Aviation Industry Group Company Ltd., Nanchang 330001, China
Abstract: Ammonia borane (AB: NH3BH3) is a new type of hydrogen storage material. Low cost and high efficiency catalyst is the key to the realization of hydrolytic hydrogen production using amborane as chemical hydrogen storage material. Co-Ni-Mo nanoparticles(NPs)was successfully prepared by one-step co-reduction method with sodium borohydride (NaBH4) as reducing agent without carrier, and its catalytic performance for hydrogen production from NH3BH3 hydrolysis was studied. The results showed that (Co0.5Ni0.5) 0.9Mo0.1NPs had the best catalytic effect, and the TOF value was 7.94 mol(H2)·mol(metal)-1min-1, and the activation energy was 46.91 kJ/mol, which was lower than the reported activation energy of non-noble metal catalyst. Since Co and Ni are magnetic materials, magnets can be used to separate the catalyst from the solution, so as to facilitate recycling. After five cycles of testing, the catalytic activity of Co-Ni-Mo NPs reaches 68% of the initial activity, which has good stability and can be conducive to practical application.
林路贺, 邹爱华, 康志兵, 郭浩, 汪杰. Co-Ni-Mo三元纳米材料的合成及催化氨硼烷制氢的研究[J]. 材料导报, 2023, 37(16): 21120005-6.
LIN Luhe, ZOU Aihua, KANG Zhibing, GUO Hao, WANG Jie. Synthesis of Co-Ni-Mo Ternary Nanomaterials and Study on Their Catalytic Hydrogen Production from Ammonia Borane. Materials Reports, 2023, 37(16): 21120005-6.
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2023, Vol. 37 
