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材料导报  2023, Vol. 37 Issue (13): 21080272-9    https://doi.org/10.11896/cldb.21080272
  无机非金属及其复合材料 |
石墨烯增强防腐涂层的研究进展
吴晨曦1,2, 郑文跃1,*, 王现中3,*, 熊道英3, 金少波4
1 北京科技大学国家材料服役安全科学中心,北京 100083
2 江苏核电有限公司,江苏 连云港 222000
3 国家石油天然气管网有限公司华南分公司,广州 510620
4 大厂金隅涂料有限责任公司,河北 廊坊 065000
Graphene-enhanced Anticorrosion Coatings:a Review
WU Chenxi1,2, ZHENG Wenyue1,*, WANG Xianzhong3,*, XIONG Daoying3, JIN Shaobo4
1 National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China
2 Jiangsu Nuclear Power Co., Ltd., Lianyungang 222000, Jiangsu, China
3 South China Branch, PipeChina Co., Ltd., Guangzhou 510620, China
4 Dachang BBMG Coatings Co., Ltd., Langfang 065000, Hebei, China
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摘要 石墨烯是一种二维片层结构材料,具有优良的抗渗透性能和化学惰性,在聚合物涂层中加入石墨烯可弥补这类涂层在服役过程中内部形成微裂纹等不足,有效延长涂层的服役寿命。本文综述了石墨烯的七种制备方法,总结对比了不同制备方法的特点,并且分析了石墨烯在防腐涂层中对腐蚀介质的屏蔽阻隔、局部导电性的改变以及作为具有慢性释放功能的缓释剂的微载体等增强涂层性能的作用。
在制备石墨烯增强聚合物涂层过程中,石墨烯容易发生团聚,影响涂层服役效果。本文首先分析了石墨烯团聚现象的原因,并从物理分散和化学分散两个角度,讨论了改善石墨烯分散性的几种方法,并总结了几种分散方式的优缺点,为今后制备性能更加优良的石墨烯聚合物涂层材料提供重要的参考。石墨烯作为一种新型材料逐渐在许多领域被应用,本文还描述了石墨烯复合涂层在输电塔、天然气管道、海洋船舶、航空航天等方面的应用。
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吴晨曦
郑文跃
王现中
熊道英
金少波
关键词:  防腐涂层  石墨烯  氧化石墨烯  腐蚀防护    
Abstract: Graphene is an ultrathin two-dimensional (2D) lamellar material with high permeability resistance and chemical stability. The addition of graphene to a polymer coating can effectively overcome aging-related degradation issues such as microcracking and may extend the overall service life of protective coatings. This paper reviews seven preparation methods for graphene and outlines their essential characteristics. The roles of graphene in shielding the corrodents and changing local conductivity as well as a potential micro-carrier of slow-releasing inhibitors for inhibitor-embedded coatings are examined.
When preparing graphene-polymer composite coatings, graphene is often prone to agglomeration and clustering, which affects the performance of coatings. The reasons for graphene agglomeration are discussed, and several physical and chemical options for graphene dispersion that can improve the uniformity of graphene in coatings are highlighted. Moreover, the pros and cons of the dispersion methods are briefly discussed, which may serve as reference information for directing future efforts toward the improvement of graphene-polymer coatings. Furthermore, because graphene is a relatively new material, this review also includes cases graphene how it is gradually being adapted in different coating applications, such as power transmission towers, natural gas pipelines, marine ships, and aerospace systems.
Key words:  anticorrosive coating    graphene    graphene oxide    corrosion resistance
发布日期:  2023-07-10
ZTFLH:  TG174  
基金资助: 北京市科技计划项目(Z201100004520011)
通讯作者:  *王现中,石油天然气储运工程学士,毕业于辽宁石油化工大学。现任国家石油天然气管网集团有限公司华南分公司副总经理。申请专利30余项,发表论文4篇。2013年获得中国石化集团公司“闵恩泽青年科技人才奖”称号;2019年、2020年分别获得省部级安全生产先进管理者称号。wangxz@pipechina.com.cn;
郑文跃,国家特聘专家,北京科技大学杰出学者,国家材料服役安全科学中心教授、博士研究生导师。1983年毕业于北京钢铁学院,1988年获得英国曼彻斯特大学博士学位。新金属材料国家重点实验室客座教授、CSTM标准委员会材料服役标准分委会会员。目前主要研究方向为能源装备材料的服役性能和新材料的研发和应用。著书5部,发表SCI、EI期刊论文等100余篇,非公开的商业报告30余篇。zheng_wenyue@ustb.edu.cn   
作者简介:  吴晨曦,2019年毕业于江苏科技大学获得工学学士学位,现为北京科技大学国家材料服役安全科学中心硕士研究生,在郑文跃教授指导下进行研究。主要研究方向是金属腐蚀与防护。
引用本文:    
吴晨曦, 郑文跃, 王现中, 熊道英, 金少波. 石墨烯增强防腐涂层的研究进展[J]. 材料导报, 2023, 37(13): 21080272-9.
WU Chenxi, ZHENG Wenyue, WANG Xianzhong, XIONG Daoying, JIN Shaobo. Graphene-enhanced Anticorrosion Coatings:a Review. Materials Reports, 2023, 37(13): 21080272-9.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21080272  或          http://www.mater-rep.com/CN/Y2023/V37/I13/21080272
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