三元镍钴锰前驱体制备方法的研究现状

材料导报

2022, Vol. 36

Issue (Z1): 21060186-9

金属与金属基复合材料

三元镍钴锰前驱体制备方法的研究现状

谢焕玲^1,2,3, 赵秋月^1,2,3, 张廷安^1,2,3, 李杨^1,2,3

1 东北大学冶金学院,沈阳 110819
2 东北大学多金属共生矿生态化冶金教育部重点实验室,沈阳 110819
3 有色金属冶金过程技术教育部工程研究中心,沈阳 110819

Research Status of Preparation Methods of Ternary Ni-Co-Mn Precursors

XIE Huanling^1,2,3, ZHAO Qiuyue^1,2,3, ZHANG Ting'an^1,2,3, LI Yang^1,2,3

1 School of Metallurgy, Northeastern University, Shenyang 110819, China
2 Key Laboratory for Ecological Metallurgy of Multimetallic Ores (Ministry of Education), Northeastern University, Shenyang 110819, China
3 Engineering Research Center of Ministry of Education of Non-ferrous Metals Metallurgical Process Technology, Shenyang 110819,China

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摘要三元镍钴锰前驱体的合成很大程度上决定了锂电池正极材料的理化性能,因此前驱体的研究越发受到重视。由于在前驱体合成过程中存在颗粒形态不一、粒径分布不均等现象,后续的锂化及所合成的锂电池的电化学性能都随之受到影响。因此近年来通过调节进料速率、物料浓度,添加有机溶剂、表面活性剂、金属离子等手段改善前驱体的理化性能。本文主要概述了三元镍钴锰前驱体合成方法的研究进展,分析并展望了前驱体发展趋势,以期对合成高容量、优异循环性能、长续航电池的制作提供思路。

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	谢焕玲
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关键词: 锂离子电池镍钴锰前驱体合成方法共沉淀法

Abstract: The physical and chemical properties of cathode materials are largely determined by the synthesis of ternary Ni-Co-Mn precursors. Therefore, the research of precursor is getting deeper and deeper. The results show that the particle morphology and size distribution of Ni-Co-Mn precursor are different during the synthesis process, which affect the subsequent lithiation and the electrochemical performance of the synthesized lithium battery. Therefore, research has been done to improve the physicochemical properties by adjusting feed rate, material concentration, adding organic solvents, surfactants and metal ions in the process of synthesizing precursor in recent years. In this paper, the synthesis methods of Ni-Co-Mn precursor are reviewed. Finally, the development trend of precursor in recent years was analyzed and prospected in order to provide ideas for the synthesis of lithium batteries with high capacity, excellent cycle performance and long-life.

Key words: lithium-ion battery nickel cobalt manganese precursor synthesis method co-precipitation method

出版日期: 2022-06-05 发布日期: 2022-06-08

ZTFLH:

TM912.9

基金资助: 国家自然科学基金(U1908225;U1903129)

通讯作者: zhaoqy@smm.neu.edu.cn

作者简介: 谢焕玲,2019年毕业于河南科技学院化学化工学院,获得学士学位。现为东北大学冶金学院硕士研究生,在赵秋月副教授和张廷安教授的指导下进行研究。主要研究方向为锂离子电池正极材料、前驱体方向。
赵秋月,东北大学冶金学院副教授,1997—2008年先后在东北大学热能专业与有色金属冶金专业获得学士、硕士、博士学位,并于美国普渡大学以访问学者身份交流一年。获得包括辽宁省科学技术奖在内的省部级奖项6项,主持和参加国家自然科学基金等国家级项目10余项。目前,主要从事冶金反应工程学及有色冶金反应器的优化与放大研究。

引用本文:

谢焕玲, 赵秋月, 张廷安, 李杨. 三元镍钴锰前驱体制备方法的研究现状[J]. 材料导报, 2022, 36(Z1): 21060186-9.
XIE Huanling, ZHAO Qiuyue, ZHANG Ting'an, LI Yang. Research Status of Preparation Methods of Ternary Ni-Co-Mn Precursors. Materials Reports, 2022, 36(Z1): 21060186-9.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2022/V36/IZ1/21060186

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