巯基-双键点击反应制备光固化红光转光膜及其性能

材料导报

2020, Vol. 34

Issue (Z1): 111-115

无机非金属及其复合材料

巯基-双键点击反应制备光固化红光转光膜及其性能

吕展衡¹, 陈品鸿¹, 许冰¹, 罗颖^1,2, 周武艺^1,2, 董先明^1,2

1 华南农业大学材料与能源学院,生物质3D打印材料研究中心,广州 510642;
2 岭南现代农业科学与技术广东省实验室,广州 510642

Preparation and Properties of Light Curable Red Light Conversion Filmby Sulfhydryl-Double Bond Click Reaction

LYU Zhanheng¹, CHEN Pinhong¹, XU Bing¹, LUO Ying^{1, 2}, ZHOU Wuyi^1,2, DONG Xianming^1,2

1 Biomass 3D Printing Materials Research Center, College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China;
2 Guangdong Laboratory of Lingnan Modern Agricultural Science and Technology, Guangzhou 510642, China

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摘要本研究将不同含量的稀土转光剂与含巯基和双键单体共混制备了光固化树脂,然后经巯基-双键或双键-双键点击反应制备了两种农用转光膜,通过荧光光谱、UV光谱、SEM、拉伸性能测试等对转光膜的结构与性能进行表征。研究结果表明,添加0.5%(质量分数)稀土转光剂的转光膜能将波长为353 nm的紫外光转换为波长为613 nm和617 nm的红光,且该转光膜具有良好的透光性能和力学性能,拉伸强度达到12.72 MPa,在农业大棚、玻璃温室等方面具有良好的应用前景。

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关键词: 稀土转光剂光固化树脂农用转光膜转光性能力学性能

Abstract: In this paper, the light curing resin was prepared by blending rare earth light conversion agent with sulfhydryl and double bond monomers. Two kinds of agricultural light conversion films were prepared by sulfhydryl-double bond or double bond-double bond click reaction. The structure and properties of the films were characterized by fluorescence spectrum, UV spectrum, SEM and tensile propertytest. The results show that the UV light at 353 nm can be converted into red light at 613 nm and 617 nm by using light conversion film which have been prepared by adding 0.5% rare earth light conversion into light curing resin, sulfhydryl-double bond click reaction. The film has good light transmittance and light conversion performance, and mechanical properties with tensile strength of 12.72 MPa, which has good application in agricultural greenhouses, glass greenhouses and other aspects.

Key words: rare earth light conversion agent light curing resin agricultural light conversion film light conversion performance mechanical property

发布日期: 2020-07-01

ZTFLH:

TQ437

基金资助: 广东省科技计划项目应用型科技研发专项重点项目(2015B020237009)

作者简介: 吕展衡,硕士研究生。研究方向为光固化涂料及胶粘剂;董先明,博士,教授,硕士研究生导师。研究方向为聚合物基复合材料及功能材料。

引用本文:

吕展衡, 陈品鸿, 许冰, 罗颖, 周武艺, 董先明. 巯基-双键点击反应制备光固化红光转光膜及其性能[J]. 材料导报, 2020, 34(Z1): 111-115.
LYU Zhanheng, CHEN Pinhong, XU Bing, LUO Ying, ZHOU Wuyi, DONG Xianming. Preparation and Properties of Light Curable Red Light Conversion Filmby Sulfhydryl-Double Bond Click Reaction. Materials Reports, 2020, 34(Z1): 111-115.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2020/V34/IZ1/111

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