Abstract: Aseries of hyperbranched polyimides with different terminated groups were prepared based on BPDA and 2,4,6-triaminopyrimidine (TAP) via a two-step polymerization. The obtained HBPIs’ structures and performance were characterized by Fourier transform infrared spectroscopy(FT-IR), gel permeation chromatography(GPC), thermal gravimetrie analysis(TGA), differential scanning calorimetry(DSC), and so on.The results show that the polyimides with the highest number average molecular weights (Mn) and inherent viscosities would be obtained when the molar ratio of TAP to BPDA was 2∶3. And the glass transition temperatures (Tg) and 5% weight loss temperatures of amine-terminated polyi-mides were higher than that of anhydride-terminated polyimides. All of the polyimides showed excellent solubility in strong polar solvents such as DMF and DMSO, and the solubility of anhydride-terminated polyimides were higher than that of amine-terminated polyimides
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