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《材料导报》期刊社  2018, Vol. 32 Issue (2): 180-183    https://doi.org/10.11896/j.issn.1005-023X.2018.02.004
  物理   材料研究 |材料 |
回收制备烧结Nd-Fe-B磁体的磁性能与耐热性能
周头军1,李家节1,2,郭诚君1,丁云峰1,陈金水1
1 江西理工大学材料科学与工程学院,赣州 341000
2 江西理工大学工程研究院,赣州 341000
Magnetic Properties and Thermal Stability of Nd-Fe-B Magnets by Recycling Fabrication
Toujun ZHOU1,Jiajie LI1,2,Chengjun GUO1,Yunfeng DING1,Jinshui CHEN1
1 School of Material Science and Engineering, Jiangxi University of Science and Technology, Ganzhou 341000
2 Institute of Engineering and Research, Jiangxi University of Science and Technology, Ganzhou 341000
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摘要 

以废旧钕铁硼磁体为原料,采用短流程回收制备技术制备了烧结Nd-Fe-B磁体,通过添加镨钕混合稀土研究了磁体的磁性能和耐热性能。结果表明,在回收磁体中添加2%PrNd,制备的烧结Nd-Fe-B磁体的剩磁为1.31 T、矫顽力为1 474.86 kA/m、磁能积为353.90 kJ/m 3。与一次成品相比矫顽力恢复到102%,剩磁恢复到95%,磁能积恢复到90%。在293393 K范围内未掺杂PrNd磁体的矫顽力温度系数为-0.589 9%/K,掺杂2% PrNd磁体的矫顽力温度系数为-0.556 4%/K,提高了磁体在高温下的耐热性能。这是由于添加混合稀土PrNd增强了主相晶粒间的去磁交换耦合作用,提高了主相的磁晶各向异性场,从而提高了磁体的矫顽力和耐热性能。

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周头军
李家节
郭诚君
丁云峰
陈金水
关键词:  烧结Nd-Fe-B  回收制备  镨钕  耐热性能    
Abstract: 

The sintered Nd-Fe-B magnets were fabricated by short-circuit recycling process. The magnetic properties and thermal stability of the magnets with adding PrNd mixed rare earth were also investigated. The magnetic properties of the magnets with 2% PrNd addition were as follows: the remanence (Br) of 1.31 T, the coercivity (Hcj) of 1 474.86 kA/m, and the maximum energy product [(BH)max] of 353.90 kJ/m 3. Compared to the new qualified magnets, the Br, Hcj and (BH)max values of 95%, 102% and 90%, respectively, were recovered. The magnet thermal stability could be improved by PrNd addition. The temperature coefficient of the coercivity reduced from -0.589 9%/K to -0.556 4%/K in the range of 293—393 K. This is mainly because the addition of mixed rare earth PrNd enhances the demagnetization exchange coupling and the magnetocrystalline anisotropy field of the main phase. Thus the coercivity and thermal stability of the magnets are improved.

Key words:  sintered Nd-Fe-B    recycling fabrication    PrNd    thermal stability
               出版日期:  2018-01-25      发布日期:  2018-01-25
ZTFLH:  TM273  
基金资助: 国家自然科学基金(51561009);江西省高校科技落地计划项目(KJLD14043);江西省青年科学基金计划项目(20151BAB216005)
引用本文:    
周头军,李家节,郭诚君,丁云峰,陈金水. 回收制备烧结Nd-Fe-B磁体的磁性能与耐热性能[J]. 《材料导报》期刊社, 2018, 32(2): 180-183.
Toujun ZHOU,Jiajie LI,Chengjun GUO,Yunfeng DING,Jinshui CHEN. Magnetic Properties and Thermal Stability of Nd-Fe-B Magnets by Recycling Fabrication. Materials Reports, 2018, 32(2): 180-183.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.02.004  或          http://www.mater-rep.com/CN/Y2018/V32/I2/180
Samples
No.
Br
T
Hcj
kA/m
(BH)max
kJ/m3
Hk/Hcj
%
1# 1.38 1 447.01 353.90 94.5
2# 1.29 1 374.62 319.67 75.9
3# 1.32 1 436.67 325.09 63.9
4# 1.31 1 474.86 319.99 68.5
表1  烧结Nd-Fe-B磁体室温磁性能
图1  烧结Nd-Fe-B磁体室温退磁曲线(电子版为彩图)
图2  回收制备烧结Nd-Fe-B二次磁体表面的背散射图
Elements 1 2 3 4
Nd 21.68 68.22 21.44 72.23
Pr 3.08 12.54 6.02 11.54
Fe 66.85 0.98 66.57 0
O 0 9.47 0 10.70
C 2.12 6.15 1.71 5.54
表2  图2中1、2、3和4对应EDS分析结果(质量分数,%)
Samples Temperature
K
Br
T
Hcj
kA/m
(BH)max
kJ/m3
2# 293 1.29 1 374.62 319.67
323 1.27 1 092.22 311.40
353 1.24 847.21 292.13
373 1.21 698.21 276.05
393 1.18 563.77 254.48
4# 293 1.31 1 474.86 319.99
323 1.26 1 186.89 301.13
353 1.23 937.89 282.50
373 1.20 785.95 267.77
393 1.17 654.30 249.86
表3  烧结Nd-Fe-B磁体在293 K、323 K、353 K、373 K和393 K下的磁性能
图3  烧结Nd-Fe-B磁体磁性能随温度变化曲线(电子版为彩图)
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