高能球磨-盐辅助氮化低温合成α-Si3N4粉体

doi:10.11896/cldb.201905002

材料导报

2019, Vol. 33

Issue (5): 739-743 https://doi.org/10.11896/cldb.201905002

材料与可持续发展（二）——材料绿色制造与加工^*

高能球磨-盐辅助氮化低温合成α-Si₃N₄粉体

张晶^1,2, 李红霞¹, 刘国齐¹

1 中钢集团洛阳耐火材料研究院有限公司,先进耐火材料国家重点实验室,洛阳 471039;
2 中材高新氮化物陶瓷有限公司,淄博 255000

Low Temperature Synthesis of α-Si₃N₄ Powders via High-energy Ball MillingCombined with Salt-assisted Nitridation

ZHANG Jing^1,2, LI Hongxia¹, LIU Guoqi¹

1 State Key Laboratory of Advanced Refractories, Sinosteel Luoyang Institute of Refractories Research Co., Ltd, Luoyang 471039;
2 Sinoma Advanced Nitride Ceramics Co., Ltd, Zibo 255000

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摘要以硅粉为原料,NaCl-NaF复合盐为反应介质和稀释剂,采用高能球磨-盐辅助氮化法制备出α-Si₃N₄粉体。研究了氮化温度、保温时间、盐硅比及复合盐中NaF含量对合成α-Si₃N₄的影响。利用X射线衍射仪(XRD)和场发射扫描电子显微镜(FE-SEM)对产物的物相组成和显微结构进行了分析表征。结果表明:氮化温度为1 200 ℃、保温时间为4 h、盐硅比为2∶1、复合盐中NaF含量为10%时,硅粉完全氮化。合成的产物中存在大量的α-Si₃N₄晶须,晶须的直径为40~280 nm,长度为几微米到几十微米;晶须的生长机制为VC机制。

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关键词: α-Si₃N₄ 低温合成高能球磨盐辅助氮化晶须

Abstract: α-Si₃N₄ powders were synthesized by a method combined high-energy ball milling with salt-assisted nitridation using silicon powders as raw materials, and NaCl-NaF as reaction medium and diluents. The effects of nitridation temperature, holding time, salt/silicon ratio and NaF content (with in NaCl+NaF) on the formation of α-Si₃N₄ were investigated. The phase composition and microstructure of the samples were analysed and characterized by XRD and FE-SEM. The results showed that the complete nitridation of silicon powders can be achieved at salt/silicon ratio of 2∶1 and NaF content of 10% after a 1 200 ℃ and 4 h heat treatment. The formation of α-Si₃N₄ whiskers with 40—280 nm in diameter and several microns to tens of microns in length was observed in the final products. The crystal growth process of α-Si₃N₄ whiskers follows vapor-crystal (VC) mechanism.

Key words: α-Si₃N₄ low temperature synthesis high-energy ball milling salt-assisted nitridation whiskers

出版日期: 2019-03-10 发布日期: 2019-03-12

ZTFLH:

TQ174

基金资助: 国家自然科学基金(51372231;51772277)

作者简介: 李红霞,工学博士,教授级高工,博士生导师。现任先进耐火材料国家重点实验室主任,耐火材料国家工程研究中心主任,中国金属学会常务理事,中国金属学会耐火材料分会主任委员,全国耐火材料标准化技术委员会主任委员,中科院上海硅酸盐研究所、北京科技大学、郑州大学、天津大学特聘教授等。主要从事耐火材料基础理论、原始创新研究,新产品开发及工程化、产业化研究,获国家技术发明二等奖1项(排名第1),省部级科技进步一等奖5项(三项排名第1),授权发明专利27件,发表论文189篇,专著2部。lihongx0622@126.com。张晶,2018年6月毕业于中钢集团洛阳耐火材料研究院,获得工学硕士学位。研究方向为氮化硅粉体及氮化硅陶瓷制备。

引用本文:

张晶, 李红霞, 刘国齐. 高能球磨-盐辅助氮化低温合成α-Si₃N₄粉体[J]. 材料导报, 2019, 33(5): 739-743.
ZHANG Jing, LI Hongxia, LIU Guoqi. Low Temperature Synthesis of α-Si₃N₄ Powders via High-energy Ball MillingCombined with Salt-assisted Nitridation. Materials Reports, 2019, 33(5): 739-743.

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http://www.mater-rep.com/CN/10.11896/cldb.201905002 或 http://www.mater-rep.com/CN/Y2019/V33/I5/739

1 Riley F L. Journal of the American Ceramic Society,2000,83(2),245.
2 Klemm H. Journal of the American Ceramic Society,2010,93(6),1501.
3 Krstic Z, Krstic V D. Journal of Materials Science,2012,47(2),535.
4 Zhu X, Sakka Y. Science & Technology of Advanced Materials,2008,9(3),033001.
5 Li Yawei, Zang Xin, Tian Haibin, et al. Bulletin of the Chinese Ceramic Society,2003,22(1),30(in Chinese).
李亚伟,张忻,田海兵,等.硅酸盐通报,2003,22(1),30.
6 Vlasova M V, Bartnitskaya T S, Sukhikh L L, et al. Journal of Materials Science,1995,30(20),5263.
7 Chen Yixiang, Li Jiangtao, Du Jisheng. Materials Research Bulletin,2008,43(6),1598.
8 Bi Yuhui, Cheng Fei, Li Jun, et al. Journal of Wuhan University of Technology,2007,29(2),8(in Chinese).
毕玉惠,陈斐,李君,等.武汉理工大学学报,2007,29(2),8.
9 Kijima K, Setaka N, Tanaka H. Journal of Crystal Growth,1974,24(10),183.
10 Ding J, Deng C, Yuan W, et al. Ceramics International,2013,39(3),2995.
11 Ding J, Zhu H, Li G, et al. Ceramics International,2016,42(2),2892.
12 Chai Z, Ding J, Deng C, et al. Advanced Powder Technology,2016,27(4),1637.
13 Tian Lang, Liang Feng, Zhang Jiefeng, et al. Journal of Ceramics,2017,38(3),352(in Chinese).
田亮,梁峰,张杰峰,等.陶瓷学报,2017,38(3),352.
14 Liu J, Ding J, Zhu H, et al. Journal of the Ceramic Society of Japan,2017,125(3),155.
15 Kameshima Y, Irie M, Yasumori A, et al. Solid State Ionics,2004,172(1),185.
16 Ren K G, Chen K X, Zhou H P, et al. Key Engineering Materials,2008,368-372,862.
17 Liu Xinkuan, Ma Mingliang. Journal of the Chinese Ceramic Society,2000,28(5)468(in Chinese).
刘新宽,马明亮.硅酸盐学报,2000,28(5),468.
18 Huang Juntong, Zhang Shaowei, Huang Zhaohui, et al. Ceramics International,2014,40(7),11063.
19 Gu Y, Lu L, Zhang H, et al. Journal of the American Ceramic Society,2015,98(6),1762.
20 Campos-Loriz D, Howlett S P, Riley F L, et al. Journal of Materials Science,1979,14(10),2325.
21 Ge Y, Wang Q, Cui W, et al. Journal of the American Ceramic Society,2015,98(10),3398.

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