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材料导报  2023, Vol. 37 Issue (S1): 23040042-9    https://doi.org/10.11896/cldb.23040042
  无机非金属及其复合材料 |
烧结助剂MgO-Al2O3-SiO2-ZrO2提高管式支撑体的耐碱腐蚀性能研究
杨瑞强1, 汪永清1,2,*, 常启兵1,2, 周健儿1,2
1 景德镇陶瓷大学材料科学与工程学院,江西 景德镇 333403
2 江西省高校无机膜重点实验室,江西 景德镇 333001
Investigation of Improving the Alkali Corrosion Resistance of Tubular Support Using MgO-Al2O3-SiO2-ZrO2 as Sintering Aids
YANG Ruiqiang1, WANG Yongqing1,2,*, CHANG Qibing1,2, ZHOU Jian'er1,2
1 School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen 333403, Jiangxi, China
2 Key Laboratory of Jiangxi Universities of Inorganic membrane, Jingdezhen 333001, Jiangxi, China
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摘要 烧结助剂可以降低氧化铝支撑体的烧结温度从而实现陶瓷膜的低成本制备,但是会影响支撑体的耐碱腐蚀性能。本工作以MgO-Al2O3-SiO2-ZrO2为烧结助剂,通过挤出成型在1 600 ℃制备一种高铝管式支撑体,并对其耐碱腐蚀性能进行研究。结果表明:高温热碱将烧结助剂中的玻璃相腐蚀导致花瓣状MgAl2O4晶体裸露,且ZrSiO4晶体仍然钉扎在氧化铝颗粒表面和颈部,为支撑体提供了良好的耐碱腐蚀性能;静态腐蚀下的支撑体抗折强度衰减规律符合水平渐近线方程,长期腐蚀下无限接近51.94 MPa;在50 ℃碱液中以4.32 m/s的膜面流速对支撑体动态腐蚀36 h后,1 680 ℃煅烧的纯铝支撑体抗折强度仅有33.78 MPa,而高铝支撑体抗折强度仍有73.06 MPa,实现了低温制备耐碱腐蚀的高铝管式支撑体。
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杨瑞强
汪永清
常启兵
周健儿
关键词:  烧结助剂  氧化铝  管式支撑体  碱腐蚀  低成本    
Abstract: Sintering aids can reduce the sintering temperature and realize the low-cost fabrication of Al2O3 ceramic membrane, however, it will affect the alkali corrosion resistance of Al2O3 support. In this work, the high alumina tubular support was fabricated by extrusion forming, sintered at 1 600 ℃, using MgO-Al2O3-SiO2-ZrO2 as sintering aids and its alkali corrosion resistance was researched. The results show that the flower-like crystal of MgAl2O4 in the alumina surface is exposed due to the corrosion of the glass phase in the sintering aids by the alkali solution at high temperature, meanwhile, the ZrSiO4 is still nailed on the surface and neck of the alumina particle, those crystals provide good alkali corrosion resis-tance for the support. The attenuation relationship of the support bending strength under the static corrosion conforms to the horizontal asymptotic equation, the bending strength infinitely close to 51.94 MPa under long-term corrosion. The bending strength of pure alumina support sintered at 1 680 ℃ is only 33.78 MPa after dynamic corrosion for 36 h with a membrane surface velocity of 4.32 m/s of alkali solution at 50 ℃, while the high alumina support in this work is still 73.06 MPa, which realizes the preparation of the high aluminum tubular support with great alkali corrosion resistance at low temperature.
Key words:  sintering aids    alumina    tubular support    alkali corrosion    low-cost
发布日期:  2023-09-06
ZTFLH:  TQ174  
通讯作者:  *汪永清,景德镇陶瓷大学材料科学与工程学院教授、博士研究生导师。1985年9月到景德镇陶瓷大学工作至今,2005年华南理工大学材料科学与工程专业博士毕业。目前主要从事陶瓷膜产业化制备、陶瓷膜表面纳米修饰、低膨胀耐热陶瓷、稀土尾砂资源化利用、陶瓷固体废弃物处理及资源化利用等方面的研究工作。发表论文100余篇,申请专利32项。wyq8248@126.com   
作者简介:  杨瑞强,2015年6月、2018年12月分别于景德镇陶瓷大学获得工学学士学位和硕士学位。现为景德镇陶瓷大学材料科学与工程学院博士研究生,在汪永清教授的指导下进行研究。目前主要研究领域为无机陶瓷膜的制备及其在苛刻环境废水处理中的应用。
引用本文:    
杨瑞强, 汪永清, 常启兵, 周健儿. 烧结助剂MgO-Al2O3-SiO2-ZrO2提高管式支撑体的耐碱腐蚀性能研究[J]. 材料导报, 2023, 37(S1): 23040042-9.
YANG Ruiqiang, WANG Yongqing, CHANG Qibing, ZHOU Jian'er. Investigation of Improving the Alkali Corrosion Resistance of Tubular Support Using MgO-Al2O3-SiO2-ZrO2 as Sintering Aids. Materials Reports, 2023, 37(S1): 23040042-9.
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http://www.mater-rep.com/CN/10.11896/cldb.23040042  或          http://www.mater-rep.com/CN/Y2023/V37/IS1/23040042
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