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材料导报  2023, Vol. 37 Issue (10): 22020161-1    https://doi.org/10.11896/cldb.22020161
  城市固废材料高效处理及资源化利用 |
全组分微纳化木质纤维素基聚磷酸铵阻燃剂的制备及在纸张中的应用
陆海梅1,2, 王超1,*, 王洪坤1,2, 张李佳琦1,2, 黄勇1, 吴敏1,2,*
1 中国科学院理化技术研究所,北京 100190
2 中国科学院大学材料科学与光电技术学院,北京100049
Preparation and Application in Paper of Micro-nano Lignocellulose-based Ammonium Polyphosphate Flame Retardant
LU Haimei1,2, WANG Chao1,*, WANG Hongkun1,2, ZHANG Lijiaqi1,2, HUANG Yong1, WU Min1,2,*
1 Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
2 College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China
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摘要 本工作以农业废弃秸秆经微纳化处理得到的全组分木质纤维素纳米纤维(LCNF)为原料,在水系条件下,通过机械球磨法将聚磷酸铵(APP)负载在LCNF上,制备出绿色高效的木质纤维素基阻燃剂(ALC),继而通过浆内添加,将该阻燃剂应用于纸张中,考察该阻燃剂的阻燃效果。结果表明,阻燃剂在纸张中均匀分散、不易析出。当阻燃剂ALC的添加量仅为10%(质量分数,下同)时,纸张具有离火自熄的效果,极限氧指数达到36.4%,最高热释放速率、总热释放量较纯纸分别降低了48.1%和77.1%,残炭量较纯纸增加了314.9%。更重要的是,在阻燃性能优化的同时,纸张的力学性能也有所提升。因此,本研究提出了一种可在纸张中均匀分散的木质纤维素基绿色阻燃剂的水系制备方法,为纤维素基阻燃剂的实际应用提供了一种绿色、简单、高效的思路。
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陆海梅
王超
王洪坤
张李佳琦
黄勇
吴敏
关键词:  木质纤维素纳米纤维  聚磷酸铵  阻燃剂  阻燃纸    
Abstract: In this work, a green and efficient lignocellulose-based flame retardant (ALC) was prepared by loading ammonium polyphosphate (APP) on the lignocellulose nanofibers (LCNF) obtained from agricultural waste straw by mechanical ball milling under water system conditions. The flame retardant was added into paper pulp to prepare retardant paper and the flame retardant effect of the paper was investigated. The results showed that ALC retardants could be uniformly dispersed in the paper, contrast to the serious aggregation of APP which was directly added into the paper pulp. With only 10wt% of ALC content, the ignited paper displayed a self-extinguishing phenomenon after moving away from the fire and turned into char. The ALC paper possessed a limiting oxygen index of 36.4%. Compared with the pure paper, the maximum heat release rate and total heat release of the ALC paper were reduced by 48.1% and 77.1%, respectively. The residual carbon content was increased by 314.9wt% as well owing to the existence of lignin components in LCNF. At the same time, the mechanical properties of paper were also enhanced because of the high aspect ratio of LCNF. In conclusion, this work proposed a facile method for preparing an efficient, green, flame retardant with great potential for practical applications in paper industry.
Key words:  lignocellulose nanofiber    ammonium polyphosphate    flame retardant    flame retardant paper
出版日期:  2023-05-25      发布日期:  2023-05-23
ZTFLH:  TS727  
基金资助: 国家自然科学基金(52073291;51733009);河北省自然科学基金-京津冀基础研究合作专项(B2021210008);中国博士后科学基金(52103132)
通讯作者:  *王超,中国科学院理化技术研究所副研究员、硕士研究生导师。2002年毕业于山东鲁东大学化学系,2002—2007年在中科院理化所‘油田化学与生物质能课题组'硕博连读,获得博士学位。主要从事纤维素与油脂共脱氧重整制备BTX及烷烃燃油、可再生碳资源热转化过程催化剂的制备与筛选、碳(石墨烯、碳纳米管)基半导体复合功能材料的制备、光电催化领域及锂电性能等方面的研究工作。在Journal of Materials Chemistry A、Carbohydrate Polymers、ACS Sustainable Chemistry & Engineering、Cellulose等国际期刊共发表论文40余篇,文章被引1 600余次。
吴敏,中国科学院理化技术研究所研究员、博士研究生导师。2002年3月毕业于(日本)名古屋工业大学物质工学专业,获工学博士学位; 2002年4月至2003年12月,日本国立产业技术综合研究所四国中心,博士后研究员; 2004年1月至2004年7月,东京大学,博士后研究员; 2004年8月至2006年7月,东京大学博士后,日本学术振兴会JSPS外国人特别研究员;2007年1月至2009年5月,中国科学院化学研究所,副研究员。目前主要从事环境友好纤维素基功能材料、纳米纤维素制备与功能化、无机/高分子纳米复合先进材料等方面的研究工作。在Journal of Materials Chemistry A、Carbohydrate Polymers、Green Chemistry、ACS Sustainable Chemistry & Engineering等国际期刊共发表论文70余篇,文章被引2 700余次。chwangipc@mail.ipc.ac.cn;wumin@mail.ipc.ac.cn   
作者简介:  陆海梅,2019年7月于华东理工大学获得工学学士学位。现为中国科学院理化技术研究所硕士研究生,在中国科学院理化技术研究所王超副研究员、吴敏研究员的指导下进行研究。目前主要研究领域为纤维素基功能材料。
引用本文:    
陆海梅, 王超, 王洪坤, 张李佳琦, 黄勇, 吴敏. 全组分微纳化木质纤维素基聚磷酸铵阻燃剂的制备及在纸张中的应用[J]. 材料导报, 2023, 37(10): 22020161-1.
LU Haimei, WANG Chao, WANG Hongkun, ZHANG Lijiaqi, HUANG Yong, WU Min. Preparation and Application in Paper of Micro-nano Lignocellulose-based Ammonium Polyphosphate Flame Retardant. Materials Reports, 2023, 37(10): 22020161-1.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22020161  或          http://www.mater-rep.com/CN/Y2023/V37/I10/22020161
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