柔性锂硫电池电极材料的结构设计

doi:10.11896/cldb.21010030

材料导报

2022, Vol. 36

Issue (11): 21010030-11 https://doi.org/10.11896/cldb.21010030

无机非金属及其复合材料

柔性锂硫电池电极材料的结构设计

张苗¹, 魏志祥², 常晶晶¹

1 西安电子科技大学前沿交叉研究院,西安 710071
2 国家纳米科学中心纳米系统与多级次制造重点实验室,北京 100190

Structural Design of Electrode Materials for Flexible Lithium-Sulfur Batteries

ZHANG Miao¹, WEI Zhixiang², CHANG Jingjing¹

1 Academy of Advanced Interdisciplinary Research, Xidian University,Xi'an 710071, China
2 CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology, Beijing 100190, China

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摘要柔性电子设备自进入人们的视野以来就备受关注,而与之相适应的、具有更高能量密度的柔性储能器件是促进其发展的关键。在各种新型柔性储能装置中,锂-硫(Li-S)电池具备高能量密度和高理论比容量,是未来柔性电池体系的理想选择之一。近几年,虽然对Li-S电池进行了深入的研究,但是高性能与电极柔性之间的相互制约性阻碍了柔性Li-S电池的进一步发展。本文通过总结柔性Li-S电池的发展现状,以Li-S电池柔性化基底材料制备为主要切入点,对柔性硫正极、柔性锂负极和柔性电池三部分进行阐述。首先分析了构造柔性正极材料的基本方法,然后总结发展新型锂金属宿主材料对实现可变形锂硫电池负极的重要性,阐述柔性电池集成和测试方法对实现柔性Li-S电池未来应用的必要性,最后对柔性Li-S电池的前景进行了展望,分析探讨了其面临的问题及未来发展方向。

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关键词: 锂硫电池柔性正负极结构设计电池集成

Abstract: Flexible electronic devices have attracted much attention since they came into people's sight. Flexible energy storage device with high energy density is one of the key components to promote the development of flexible electronic devices. In a variety of new flexible energy storage devices, the lithium-sulfur battery with high energy density and theoretical specific capacity is an ideal choice for future flexible battery system. In recent years, lithium-sulfur batteries have been studied in depth; however, due to limitation between high energy density and electrode flexibility, the development of flexible lithium-sulfur batteries have been faced with serious constraints. In this paper, the design of flexible electrode, separators and lithium-sulfur batteries are briefly introduced. Specifically, the basic method of constructing flexible cathode and anode materials is analyzed, the necessity of integration and testing methods in flexible lithium-sulfur batteries for the future application is described, and perspectives regarding the development trend of flexible lithium-sulfur batteries have been discussed. It also includes a prospective discussion upon the challenges and future development trends.

Key words: lithium-sulfur battery flexible anode and cathode structural design battery integration

发布日期: 2022-06-09

ZTFLH:

TM912

基金资助: 中央高校基本科研业务费专项资金;陕西省自然科学基础研究计划青年项目(2021JQ-189)

通讯作者: jjingchang@xidian.edu.cn

作者简介: 张苗,西安电子科技大学前沿交叉研究院讲师,2019年6月毕业于西安交通大学,获得化学工程与技术专业博士学位,2014年7月至2019年5月在国家纳米科学中心联合培养,目前主要从事高能量密度锂硫电池电极材料研究及柔性储能器件的应用,主持陕西省自然科学基金等多项基金。
常晶晶,教授,博士研究生导师,国家高层次人才计划入选者,2010年6月在四川大学获得理学学士学位,之后在新加坡国立大学攻读博士学位,期间前往新加坡材料研究与工程研究所(IMRE)从事博士课题研究。2014年博士毕业后,继续在新加坡国立大学材料科学与工程系从事博士后研究员工作。2015年通过西安电子科技大学“华山学者菁英人才计划”加入微电子学院。中国科协青年人才托举工程入选者,主持参与国家自然科学基金、国家重点研发计划等项目20余项,包括技术成果转化3项。担任科技部重点研发计划、国家自然科学基金等的评审专家。近年来主要从事有机及金属氧化物半导体晶体管电子器件的制备及研究、柔性印刷器件工艺的优化、有机及钙钛矿太阳能电池的研究工作等。截至目前,在Advanced Mate-rials、Advanced Energy Materials、Advanced Science、ACS Energy Letters、Advanced Electronic Materials、Nano Energy等国际核心期刊上发表SCI论文150余篇,被引用3 000余次,其中中科院一区90余篇。

引用本文:

张苗, 魏志祥, 常晶晶. 柔性锂硫电池电极材料的结构设计[J]. 材料导报, 2022, 36(11): 21010030-11.
ZHANG Miao, WEI Zhixiang, CHANG Jingjing. Structural Design of Electrode Materials for Flexible Lithium-Sulfur Batteries. Materials Reports, 2022, 36(11): 21010030-11.

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http://www.mater-rep.com/CN/10.11896/cldb.21010030 或 http://www.mater-rep.com/CN/Y2022/V36/I11/21010030

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