Research Advances on Modified Titanium Dioxide for Photogenerated Cathodic Protection
LONG Wujian1,2, MING Gaolin1,2, DONG Biqin1,2, FU Xianzhu3, LUO Jingli3, SHI Shi1,2,*
1 College of Civil and Transportation Engineering, Shenzhen University, Shenzhen 518060, Guangdong, China 2 Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, Shenzhen 518060, Guangdong, China 3 College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, Guangdong, China
Abstract: The extensive application of metal materials has greatly promoted the social progress. However, the high-frequency metal corrosion causes huge losses and harm to human life and safety, which triggers a series of ecological problems as well. Generally, corrosion protection measures have been carried out, such as materials selection, coating, corrosion inhibitor and electrochemical protection. Cathodic protection, one of the electrochemical protection techniques, has been widely used in metal corrosion protection, yet there are some limitations for traditional cathodic protection technologies. As for traditional cathodic protection technologies, current-impressed cathodic protection requires regular maintenance, monitoring and complicated devices, while sacrificial anode cathodic protection with low output needs replacing anode metal regularly. In the past two decades, photogenerated cathodic protection, a novel approach of cathodic protection technology, has attracted a great deal of attention and confirmed to be truly efficient and eco-friendly, in which semiconductors serve as photoelectric center to transform solar radiation into electricity. The photoelectric conversion efficiency of semiconductor materials is focused on, as well as the ability of photogenerated electrons transferring and enriching onto the protected metal surface. TiO2 is a kind of photoelectric pollution-free semiconductor material, which shows good stability and excellent photocorrosion resistance. There are broad application prospects for TiO2 in the fields of photocatalytic activity, photoelectric conversion, photogenerated cathodic protection and others. However, the characteristics of wide band gap, poor photoresponse ability, high photocarrier recombination velocity and inefficient photoelectric conversion lead to insufficiency in offering sustained protection. Therefore, breaking through bottlenecks of TiO2 application in photogenerated cathodic protection by effective modification has recently received significant attention. Different modification methods for TiO2 to improve photoelectric conversion efficiency have been studied carefully. A great breakthrough in the substantiation of photogenerated cathodic protection in darkness has been performed. This review, proceeding from the mechanism of photogenerated cathodic protection, systematically introduces modification methods including metal deposition, ion doping, semiconductor compounding (g-C3N4, Bi2S3, graphene, etc.) and quantum dots sensitization. Advances of different modification methods of TiO2 in improving efficiency of photoelectric performance and photogenerated cathodic protection are emphatically discussed. The research advances and achievements of the author's team on photocatalytic materials and corrosion protection are reviewed. In addition, the feasibility of cathodic protection for reinforcement is demonstrated. Finally, future research direction and research emphases of photogenerated cathodic protection are proposed. This review provides new approaches for the wide application of modified TiO2 in photogenerated cathodic protection in a sustainable way.
作者简介: 龙武剑，深圳大学土木与交通工程学院教授、博士研究生导师。2002年8月本科毕业于法国国立图卢兹第三大学，2004年8月硕士毕业于法国高等师范大学，2008年7月于加拿大布鲁克大学取得土木工程博士学位。2009年9月进入深圳大学土木与交通工程学院，主要从事可持续土木工程材料-结构一体化的相关研究。近五年在Cement and Concrete Composites, Composites Part B-Engineering, ACI Materials Journal, Construction and Building Material 等权威期刊发表论文60余篇。 施诗，深圳大学土木与交通工程学院副研究员。2009年7月本科毕业于北京科技大学材料科学与工程学院材料化学系，2015年3月在日本北海道大学取得博士学位，2015至2019年分别在美国威斯康星大学麦迪逊分校工程物理系、南方科技大学机械与能源工程系进行研究工作。2019年进入深圳大学土木与交通工程学院，主要从事光电半导体材料及光电化学阴极保护方向的研究工作。近五年在Materials Science and Engineering A, Acta Materialia, Nature Communications等权威期刊上发表论文10余篇。
引用本文:
龙武剑, 明高林, 董必钦, 符显珠, 骆静利, 施诗. 改性TiO2的光生阴极保护研究进展[J]. 材料导报, 2022, 36(15): 20120025-9.
LONG Wujian, MING Gaolin, DONG Biqin, FU Xianzhu, LUO Jingli, SHI Shi. Research Advances on Modified Titanium Dioxide for Photogenerated Cathodic Protection. Materials Reports, 2022, 36(15): 20120025-9.
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2022, Vol. 36 
