Abstract: Sodium borohydride(NaBH4) has high hydrogen storage density, which could be stored and transported under normal pressure and temperature in alkaline solution. Simultaneously, sodium borohydride emerged as hydrogen storage candidate for proton exchange membrane fuel cell (PEMFC) and direct borohydride fuel cell (DBFC) system. But the development was constrained for the problems, such as the high cost of hydrogen production, the difficulty of regeneration and the need of noble metal catalyst. Many researchers have made many researches on the process of regenerating sodium borohydride, including industrial synthesis process and direct reduction process. The process of direct sodium borohydride reduction is an one-step synthesis method of heating sodium metaborate, magnesium hydride and magnesium in the presence of hydrogen or argon atmosphere. This is a fairly attractive process from the perspective of one-step reaction and high product yield, but there are some risks associated with high pressure, high temperature, and high energy consumption. In recent years, the process of mechanical-chemical reduction, especially high-energy ball milling process, has been studied too much. Sodium borohydride can be regenerated by ball milling at different speeds and ball milling time under normal temperature and pressure, and the regeneration process is convenient and economical. In addition, sodium borohydride can be synthesized by electrochemical reduction process with simple process and mild conditions, selecting appropriate electrode and electrolytic solution to product sodium borohydride in the electrolytic cell. However, the product yield obtained by this process is pretty low, furthermore, the mechanism had rarely studied. In this paper, the regeneration processes of sodium borohydride at home and abroad are reviewed. Industrial synthesis process, direct reduction process, mechanical-chemical reduction process and electrochemical reduction process are discussed. Meanwhile, the mechanism, process route and their relative merits of each method are summarized and analyzed.
作者简介: 付文英,2019年6月毕业于山东理工大学,获得理学学士学位。现为江苏师范大学物理与电子工程学院硕士研究生,在魏永生副教授的指导下进行研究。目前主要研究领域为电化学还原偏硼酸钠制备硼氢化钠。 魏永生,江苏师范大学物理与电子工程学院副教授、硕士研究生导师。2006年7月本科毕业于中国矿业大学化学工程与工艺专业,2011年7月在北京交通大学取得博士学位,2008—2009年在美国迈阿密大学进行博士研究工作。2013年于北京化工大学取得博士后学位。主要从事燃料电池、电解水制氢催化剂、电化学还原制备硼氢化钠的研究工作。先后主持国家自然科学基金青年项目、江苏省自然科学基金青年项目等科研课题,参与国家863项目、国际合作项目、国家自然科学基金面上项目等项目。迄今在Journal of Power Sources, International Journal of Hydrogen Energy, Phys. Chem. Chem. Phys等国内外学术期刊发表论文75篇,引用300余次。
引用本文:
付文英, 司司, 魏永生, 刘妍, 陈佳琪, 韦露, 赵新生. 硼氢化钠循环再生工艺的研究进展[J]. 材料导报, 2021, 35(15): 15017-15025.
FU Wenying, SI Si, WEI Yongsheng, LIU Yan, CHEN Jiaqi, WEI Lu, ZHAO Xinsheng. Research Progress of Sodium Borohydride Regeneration Process. Materials Reports, 2021, 35(15): 15017-15025.
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2021, Vol. 35 
