地表臭氧分解用氧化锰研究进展

doi:10.11896/cldb.20070148

材料导报

2021, Vol. 35

Issue (21): 21050-21057 https://doi.org/10.11896/cldb.20070148

环境催化材料

地表臭氧分解用氧化锰研究进展

邱晶, 赵明, 王健礼, 陈耀强

四川大学化学学院绿色化学与技术教育部重点实验室,成都 610064

Research Progress of Manganese Dioxide Catalyst for Ozone Decomposition

QIU Jing, ZHAO Ming, WANG Jianli, CHEN Yaoqiang

Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China

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摘要近年来,过渡金属锰的氧化物因其结构变化呈现性能多样性,在臭氧分解等大气污染物净化领域展现出得天独厚的优势。地表臭氧是一种常见的大气污染物,臭氧不仅会造成光化学污染,其强氧化性还会对人体健康造成严重损害,因此降低地表臭氧浓度至关重要。地表臭氧处理方法包括催化分解、药液吸收、电磁波辐射、热分解等,其中催化分解法因具有耗能低、环境友好的特点而被广泛使用。从性能、价格和应用背景等因素考虑,锰氧化物是催化臭氧分解的主流,结构的差异能影响催化臭氧分解的能力,锰氧化物结构多样,具有深刻的研究意义。锰基催化剂具有良好的活性,但在实际使用过程中催化剂的性能还受到水汽的影响,相对湿度越高,催化剂失活越严重。制备出低温性能好、耐湿能力强、使用寿命长且适应高空速的锰基臭氧分解催化剂是目前学者们追求的目标。本文总结了近年来锰氧化物在臭氧催化分解中的进展,重点介绍了单组分锰基催化剂、复合氧化物锰基催化剂的研究,简述了碱性阳离子对锰基催化剂活性的影响,得出了水汽、载体选择、空速等因素都会影响催化剂活性的结论。最后,提出了锰氧化物在臭氧催化分解研究中存在的问题并对其发展前景做出了展望。

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关键词: 环境催化剂多相反应地表臭氧催化分解锰氧化物

Abstract: Manganese oxides show diversity of properties with the change of structure and show unique advantages in the field of purification of atmospheric pollutants for example ozone decomposition. Ground ozone is a common atmospheric pollutant. Ozone will not only cause photochemical pollution, but also cause serious damage to human health due to its strong oxidation. It is very important to reduce the concentration of ground ozone. Ozone treatment methods include catalytic decomposition, liquid absorption, electromagnetic radiation, thermal decomposition, etc. Catalytic decomposition method is widely used because of low energy consumption and environment-friendly characteristics. Considering the performance, price and application background, manganese oxides is the main stream of ozone catalytic decomposition. The difference in structure can affect ability of catalyze ozone decomposition. The structures of manganese oxides are various, which has profound research significance. However, the performance of manganese oxides is also affected by water vapor during actual use. The higher the relative humidity, the more serious the catalyst deactivation. It is the goal of scholars to prepare manganese-based catalyst with excellent performance at low temperature, high humidity and high space velocity. This review summarizes the progress of manganese oxides in ozone catalytic decomposition in recent years, and focuses on the progress of single component manganese-based catalysts and composite oxide manganese-based catalysts, and briefly describes the effect of basic cations on the activity of manganese-based catalyst, and summarizes water vapor, carrier selection, space velocity can affect catalyst activity. What's more, this review points out existing problems, key points and development trend of catalytic ozone decomposition.

Key words: environment catalyst multiphase reaction ground ozone catalytic decomposition manganese dioxides

出版日期: 2021-11-10 发布日期: 2021-11-30

ZTFLH:

X515

基金资助: 四川省重大科技专项(2019ZDX0025);国家自然科学基金(21972098)

通讯作者: wangjianli@scu.edu.cn

作者简介: 邱晶,2019年6月毕业于四川大学,获得理学学士学位。现为四川大学研究生,在王健礼教授的指导下进行研究。目前主要研究领域为地表臭氧催化分解。
王健礼,男,理学博士,教授、博导,任职于四川大学化学学院。四川省学术技术带头人后备人选,移动源污染控制国家工程实验室理事,移动源污染控制国家工程实验室技术委员会委员,教育部工程研究中心主任,主编编写本科生教材2部,出版专著1部,科研工作一直从事环境催化、催化材料、机动车尾气净化催化剂及裂解催化剂的研究。作为项目负责人负责国家科技部首批重点研发计划课题1项(2016YFC0204903),自然科学基金面上项目(21972097),国防科技重大专项3项等各类项目共计15项。目前已正式发表SCI论文60余篇(通讯作者或第一作者论文)。获四川省科技进步奖一等奖两项(2013,2017)。

引用本文:

邱晶, 赵明, 王健礼, 陈耀强. 地表臭氧分解用氧化锰研究进展[J]. 材料导报, 2021, 35(21): 21050-21057.
QIU Jing, ZHAO Ming, WANG Jianli, CHEN Yaoqiang. Research Progress of Manganese Dioxide Catalyst for Ozone Decomposition. Materials Reports, 2021, 35(21): 21050-21057.

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http://www.mater-rep.com/CN/10.11896/cldb.20070148 或 http://www.mater-rep.com/CN/Y2021/V35/I21/21050

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