Application of Metal-Organic Framework in CO2 Photocatalytic Reduction
ZHANG Zhongwei1, GUO Ruitang1,2,3, QIN Yang1, GUO Deyu1, PAN Weiguo1,2,3
1 College of Energy and Mechanical Engineering, Shanghai University of Electric Power, Shanghai 200090, China 2 Shanghai Engineering Research Center of Power Generation Environment Protection, Shanghai 200090, China 3 Key Laboratory of Environmental Protection Technology for Clean Power Generation in Machinery Industry, Shanghai 200090, China
Abstract: Although human beings rely on fossil fuels to accelerate the development of modern society, the over-use of fossil fuels has raised a series of problems such as tough energy crisis and environmental exacerbation. Excessive depletion of fossil fuels leads to the sharp increase of CO2 content in the atmosphere, which is the main cause of the global greenhouse effect. Among the abundant technologies for reducing CO2 emissions, the photocatalytic reduction of CO2 technology not only reduces the CO2 content in the atmosphere, but also converts CO2 into valuable chemicals through solar energy, which is considered to be one of the most promising technologies. Metal-organic frameworks (MOFs), also known as porous coordination polymers, are three-dimensional porous materials with a periodic network structure composed of inorganic metal ions (or metal clusters) and organic ligands. MOFs are particularly promising materials due to large surface area, adjustable structure, unique electronic band structures and abundant catalytic active sites, which make it more and more favored by researchers in the photocatalytic reduction of CO2. At present, MOFs used for photocatalytic reduction of CO2 mainly include single MOFs photocatalyst and composite photocatalyst based on MOFs. The article lists specific examples to illustrate the advantages and uniqueness of MOF-based photocatalytic materials in the reduction of CO2 and modified methods to improve photocatalytic activity. This review summarizes recent research progresses in MOF-based photocatalysts for photocatalytic reduction of CO2. Besides, it discusses strategies in rational design of MOF-based photocatalysts (MOFs functionalization, semiconductor/MOFs, photosensitizer/MOFs and noble me-tal/MOFs) with enhanced performance on CO2 reduction. Moreover, challenges and outlook on using MOFs-based photocatalysts for CO2 reduction are also put forward.
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