Effect of Mg on the Microstructure and Properties of Sn-0.7Cu Solders
WANG Meng, ZHANG Guanxing, ZHONG Sujuan, CHENG Zhan, LI Wenbin
State Key Laboratory of Advanced Brazing Filler Metals and Technology, Zhengzhou Research Institute of Mechanical Engineering Co., Ltd., Zhengzhou 450001, China
Abstract: The effect of Mg element on the microstructure, melting characteristics, wettability and mechanical properties of Sn-0.7Cu eutectic solders were investigated. The results show that a proper addition of the Mg element refines the eutectic structure of the solders,while excessive addition results in the disappearance of the eutectic structure, and the transformation of Cu6Sn5 from fine particles to short rods. The melting point of the solders decreases significantly with the increasing addition of Mg element and it decreases to 222.58 ℃ with 1.0wt% Mg. The melting range increases and the degree of supercooling increases first and then decreases with the increasing addition of the Mg element. The wettability of sol-ders first increase and then decrease with the increase of Mg element. When the content of Mg element reaches to 0.1wt%, best wetting perfor-mance can be found with an spreading area of 85.74 mm2 and an increase by 4.37% compared with Sn-0.7Cu solder can be obtained. In addition, the microhardness of Sn-0.7Cu-xMg solder can significantly increase with the addition of the Mg element and reached the maximum value at 1.0wt% Mg, increasing by 17.2%.
1 Zhao M, Zhang L, Xiong M Y.Materials Report A:Review Papers, 2019, 33(8), 2467 (in Chinese). 赵猛, 张亮, 熊明月. 材料导报:综述篇, 2019, 33(8), 2467. 2 Liu Z Y. Effect of Co content on the microstructure and brazing property of Sn-0.7Cu lead-free solder. Master's Thesis, Zhengzhou University of Light Industry, China, 2019 (in Chinese). 刘占云.Co含量对Sn-0.7Cu无铅钎料合金组织和钎焊性能的影响. 硕士学位论文, 郑州轻工业大学, 2019. 3 Li G D, Shi Y W, Xia Z D, et al. Electronic Components and Materials, 2009, 28(2), 70 (in Chinese). 李广东, 史耀武, 夏志东,等. 电子元件与材料, 2009, 28(2), 70. 4 Yao Y, Long X, Leon M K.Applied Mechanics Reviews, 2017, 69, 040802. 5 Fan J L, Liu Z Y, Li Y W, et al.Materials Reports A:Review Papers, 2018, 32(11), 3774 (in Chinese). 樊江磊, 刘占云,李育文,等.材料导报:综述篇,2018, 32(11), 3774. 6 Hasnine M, Bozack M J.Journal of Electronic Materials, 2019, 48(6), 3970. 7 Li L F, Cheng Y K, Xu G L, et al. Materials & Design,2014, 64, 15. 8 Tian S, Li S, Zhou J, et al.Journal of Alloys and Compounds, 2018, 742, 835. 9 Tian S, Li S, Zhou J, et al. Journal of Materials Science:Materials in Electronics, 2017, 28(21), 16120. 10 Mahdavifard M H, Sabri M F M, Said S M, et al.Journal of Electronic Materials, 2016, 45(7), 3673. 11 Alam M E, Gupta M.Electronic Materials Letters. 2013, 9(5), 575. 12 Chen H Y, Savvides N, Dasgupta T, et al.Physica Status Solidi A-Applications and Materials Science,2010, 207(11), 2523. 13 Lu S, Luo F, Chen J, et al. In:International Conference on Electronic Packaging Technology & High Density Packaging. Shanghai, 2008, pp. 660. 14 Alam M E, Gupta M.Electronic Materials Letters. 2013, 9(5), 575. 15 Zhang Z F, Qin Z Y, Li Y, et al.Materials Reports A:Review Papers, 2019, 33(11), 3613 (in Chinese). 张正飞, 秦紫依, 李勇, 等. 材料导报:综述篇,2019, 33(11), 3613.