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材料导报  2021, Vol. 35 Issue (10): 10158-10165    https://doi.org/10.11896/cldb.20040056
  金属与金属基复合材料 |
Ti-Mg-Al复合脱氧X70级抗酸海底管线钢氢捕获效率及HIC敏感性
肖虎1,2, 黄峰1,2, 彭志贤1,2, 戈方宇1,2, 刘静1,2
1 武汉科技大学省部共建耐火材料与冶金国家重点实验室,武汉 430081
2 武汉科技大学,湖北省海洋工程材料及服役安全工程技术研究中心,武汉 430081
Hydrogen Trapping Efficiency and HIC Sensitivity of Ti-Mg-Al Composite Deoxidized X70 Acid Resistant Submarine Pipeline Steel
XIAO Hu1,2, HUANG Feng1,2, PENG Zhixian1,2, GE Fangyu1,2, LIU Jing1,2
1 The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
2 Hubei Engineering Technology Research Centre of Marine Materials and Service Safety, Wuhan University of Science and Technology, Wuhan 430081, China
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摘要 采用NACE TM 0284-2016标准评估了一系列不同Al含量的Ti-Mg-Al复合脱氧X70级别抗酸海底管线试验钢的氢致开裂(HIC)敏感性,并通过测量氢扩散通量(J∞L)和有效氢扩散系数(Deff)研究了其氢捕获及扩散动力学行为。结果表明:Al的添加因能促进针状铁素体形成而显著提高试验钢的抗拉强度;随着Al含量增加,试验钢中的夹杂物不仅数量增加,成分也发生变化,由以均匀分布的单一Mn-S和Al-Ti-Mg-O-Mn-S复合夹杂物为主转向以带状分布的单一Al-O夹杂和Al-Ti-O-Mn-S型复合夹杂为主;当Al含量增加至0.03%时,试验钢的屈服强度降低,且[H]容易在脆性Al2O3夹杂物周围引发内部微裂纹,并产生表面氢鼓泡。Al的添加主要是通过影响钢中非金属夹杂物的特性,从而改变氢在钢中的捕获和扩散动力学行为,进而影响钢的HIC敏感性。在本实验范围内,Al的添加量不宜超过0.03%。
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肖虎
黄峰
彭志贤
戈方宇
刘静
关键词:  Ti-Mg-Al复合脱氧  X70 MOS管线钢  非金属夹杂物  HIC敏感性    
Abstract: NACE TM 0284-2016 standard was used to evaluate the hydrogen induced cracking (HIC) susceptibility of series of X70 grade anti-acid submarine Ti-Mg-Al composite deoxidization tested pipeline steels with different Al contents. The hydrogen diffusion kinetic behavior of X70 MOS pipeline steel was investigated through measuring the permeability (J∞L) and the apparent hydrogen diffusivity (Deff). The results indicated that the tensile strength of tested steels could be improved significantly due to the formation of acicular ferrite by the addition of Al. With increasing of Al contents, the amount of inclusions increased significantly, and single Mn-S and Al-Ti-Mg-O-Mn-S compound inclusions with uniform distribution changed into single Al-O and Al-Ti-O-Mn-S compound inclusions with chain distribution. When the content of Al was up to 0.03%, the yield strength of tested steel decreased, and H could be easily trapped around the brittle Al2O3 inclusions, and then caused internal microcracks and hydrogen bubbles on the surface of tested steel. The addition of Al for Ti-Mg composite deoxidization steel mainly made the characteristics of non-metallic inclusions happen, and then changed the dynamic behavior of hydrogen diffusion, finally affected the HIC susceptibility of tested steels. In this research range, the addition amount of Al should not exceed 0.03%.
Key words:  Ti-Mg-Al composite deoxidization    X70 MOS pipeline steel    non-metallic inclusions    HIC susceptibility
               出版日期:  2021-05-25      发布日期:  2021-06-04
ZTFLH:  TG142.1  
基金资助: 国家自然科学基金(51871172);湖北省中央引导地方科技发展专项(2018ZYYD026)
通讯作者:  huangfeng@wust.edu.cn   
作者简介:  肖虎,硕士研究生。2019年毕业于武汉科技大学,获得学士学位。2019年9月至今在武汉科技大学材料与冶金学院攻读硕士学位,主要从事高性能钢铁材料服役安全方面的研究。
黄峰,博士,武汉科技大学三级教授、博士研究生导师。中国腐蚀与防护学会理事、湖北省腐蚀与防护学会副理事长、中国腐蚀与防护学会腐蚀电化学与测试技术专业委员会和材料敏感断裂专业委员会委员。2003年获武汉大学理学博士学位,2013—2014年间赴美国密歇根州立大学交流访问。主要从事金属材料表面与界面、金属材料微观组织与耐蚀性、相微区电化学等方面的研究。主持和参加国家自然科学基金、科技部基础平台建设、湖北省自然科学基金、湖北省科技支撑计划等20余项项目。发表研究论文80余篇,其中SCI收录40余篇,单篇被引次数超过150余次,授权发明专利5项。
引用本文:    
肖虎, 黄峰, 彭志贤, 戈方宇, 刘静. Ti-Mg-Al复合脱氧X70级抗酸海底管线钢氢捕获效率及HIC敏感性[J]. 材料导报, 2021, 35(10): 10158-10165.
XIAO Hu, HUANG Feng, PENG Zhixian, GE Fangyu, LIU Jing. Hydrogen Trapping Efficiency and HIC Sensitivity of Ti-Mg-Al Composite Deoxidized X70 Acid Resistant Submarine Pipeline Steel. Materials Reports, 2021, 35(10): 10158-10165.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20040056  或          http://www.mater-rep.com/CN/Y2021/V35/I10/10158
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