载体孔属性对多孔复合PCMs热性能的影响:综述

材料导报

2021, Vol. 35

Issue (Z1): 495-500

高分子与聚合物基复合材料

载体孔属性对多孔复合PCMs热性能的影响:综述

李伟培¹, 何世杰¹, 邱志明¹, 吴松平², 严玉蓉¹

1 华南理工大学材料科学与工程学院,广州 510640
2 华南理工大学化学与化工学院,广州 510640

Influence of Structure and Properties of Porous Carrier on Thermal Properties of Multi-scale Porous PCMs Composite: a Review

LI Weipei¹, HE Shijie¹, QIU Zhiming¹, WU Songping², YAN Yurong¹

1 School of Materials Science and Engineering, South China University of Technology, Guangdong 510640, China
2 School of Chemistry and Chemical Engineering, South China University of Technology, Guangdong 510640, China

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摘要相变储能技术是缓解能源供需矛盾的有效方法,在多种转变类型的相变材料(PCMs)中,固-液转变PCMs由于其较高的相变焓,较小的体积变化而最具实用性,但其在相变过程中存在液态PCMs容易泄漏的问题。以多孔材料为载体,实现PCMs的有效封装可有效缓解这类泄漏问题。本文就多孔载体的孔径尺寸、孔隙结构、孔表面与PCMs的相互作用等影响因素对多孔复合PCMs的热力学性能变化规律进行归纳,发现:微米尺寸的孔存在明显的PCMs泄漏,小尺寸介孔结构的局域性限制可导致PCMs相变行为减弱,结晶度降低。对于含有分级多孔结构的载体,微孔可以提供毛细管力,实现对PCMs分子的吸附,介孔提供PCMs的传输途径,大孔则作为PCMs的储存腔,使复合材料具有良好的综合性能。本文同时讨论了载体与PCMs间的相容性,氢键对复合材料吸附容量和相变焓的影响,并对多孔复合PCMs的研究方向进行展望。

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	李伟培
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关键词: 相变储能材料孔径孔表面热力学性能

Abstract: Phase change energy storage technology is an effective way to alleviate the contradiction between energy supply and demand. For phase change materials (PCMs), PCMs characterized by the solid-liquid transition are commonly used due to their higher phase change enthalpy and smaller volume change. However, the leakage of liquid PCMs during the phase change process is the key issue in actual application fields. Encapsulating of PCMs in porous materials has been fulfilled for the effectively alleviation of the leakage problem. Here, Influence of perspectives factors on the thermodynamic properties of porous composite PCMs were summarized, such as the of pore size of porous carrier, pore structure, the interaction between the pore surface and the PCMs. Results showed that micrometer-scale pores help the leakage of liquid PCMs. The small-sized mesoporous structure restricts the movement of PCMs molecules and reduces its crystallinity. For carrier with hierarchical porous structure, the micropores can provide capillary force to adsorb PCMs molecules, the macropores serving as a storage cavity to the PCMs, and acted as a bridge connecting small pores and macropores, thus the composite material has a good comprehensive performance. The effects of compatibility and hydrogen bonding between the carrier and PCMs on the adsorption capacity and phase transition enthalpy of the composite are discussed, and the research tendency of porous composite PCMs is prospected.

Key words: phase change energy storage material pore size pore surface thermodynamic properties

发布日期: 2021-07-16

ZTFLH:

TQ050.4

基金资助: 国家自然科学基金 (51873074)

作者简介: 李伟培,华南理工大学硕士在读研究生,主要研究方向为相变储能材料的封装研究和智能穿戴功能纤维的研究,参与多项国家、省部级课题及企业科研攻关项目,申请发明专利2项。严玉蓉,教授,博士研究生导师。2002.7月于华南理工大学获得博士学位,并留校任教至今。2005—2007年于广东新会美达锦纶股份有限公司从事博士后研究工作。2007年于美国Akron大学访问研究。2017年于瑞士联邦材料研究所(Empa)访问研究。现兼任教育部高等学校纺织类专业教学指导委员会纤维材料分教学指导委员会副主任委员、非织造材料分教学指导委员会委员、中国材料研究学会纤维材料改性与复合技术分会常务理事、中国化学纤维工业协会理事。主要研究领域:静电纺丝成形及微/纳米纤维在过滤、生物医用、高效催化、隔音、电池隔膜及电极材料等领域的应用基础研究;复合纺丝纤维成型机理研究;智能穿戴功能纤维研究;生物可降解高分子材料的改性、纤维成型及功能化研究;碱金属电池负极材料等研究等。先后主持和参与30余项国家、省部级课题及企业科研攻关项目,发表中、英论文160余篇,授权发明专利19件,实用新型专利17件。主编中文教材1部,参编中文专著6部,外文专著4部。获得省级科技进步三等奖3次,市级科技进步奖多次。

引用本文:

李伟培, 何世杰, 邱志明, 吴松平, 严玉蓉. 载体孔属性对多孔复合PCMs热性能的影响:综述[J]. 材料导报, 2021, 35(Z1): 495-500.
LI Weipei, HE Shijie, QIU Zhiming, WU Songping, YAN Yurong. Influence of Structure and Properties of Porous Carrier on Thermal Properties of Multi-scale Porous PCMs Composite: a Review. Materials Reports, 2021, 35(Z1): 495-500.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2021/V35/IZ1/495

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