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材料导报  2018, Vol. 32 Issue (22): 3848-3852    https://doi.org/10.11896/j.issn.1005-023X.2018.22.003
  无机非金属及其复合材料 |
速溶高粘羧甲基纤维素钠对不同相变温度梯度芒硝基相变储能材料性能的影响
李秀丽, 铁生年
青海大学新能源光伏产业研究中心,西宁 810016
Effect of Quick-dissolving and High-viscosity Carboxymethyl Cellulose Sodium on Properties of Glauber’s Salt-based Composites Phase Change Energy Storage Materials with Different Phase Transition Temperature Gradient
LI Xiuli, TIE Shengnian
New Energy Photovoltaic Industry Research Center,Qinghai University,Xining 810016
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摘要 选取了四种不同粘性的羧甲基纤维素钠(CMC-Na),对其进行结构分析,选择速溶高粘羧甲基纤维素钠作为三种不同温度梯度芒硝基相变储能材料的增稠剂,确定CMC-Na的最佳复合比例,有效解决相变储能材料的相分层现象。探究了速溶高粘羧甲基纤维素钠的量对相变材料储能密度、导热性和过冷度性能的影响。试验结果表明:三种不同温度梯度芒硝基相变储能材料优化速溶高粘羧甲基纤维素钠比例分别为1.0%、1.0%、0.5%,制备出相变温度分别为7 ℃、14 ℃和22 ℃的芒硝基相变储能材料,其防止相分层的效果较好。材料的储能密度、导热系数以及过冷度分别为102.3 J/g、146.4 J/g、162.5 J/g、0.839 1 W/(m·K)、0.984 3 W/(m·K)、1.011 5 W/(m·K)以及2.3 ℃、0.5 ℃、0.8 ℃,这对提高对芒硝基相变材料的使用寿命具有重要的指导意义。
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李秀丽
铁生年
关键词:  羧甲基纤维素钠  芒硝  不同相变温度  相变储能材料  相分层    
Abstract: Selecting four kinds of carboxymethyl cellulose sodium (CMC-Na) with different viscidity properties analyzed them from structure, then choosed the quick-dissolving and high-viscosity CMC-Na as a thickener for three different temperature gradient Glauber’s salt phase change energy storage materials. Determined the best compound ratio of CMC-Na, solved the phase transition energy storage material phase stratification phenomenon effectively. The effects of the amount of instant carboxymethyl cellulose so-dium on the energy storage density, thermal conductivity and undercooling performance of phase change materials were investigated. The results demonstrated that the proportions of CMC-Na were 1.0%,1.0%,0.5%, respectively, three different temperature gra-dient of Glauber’s salt phase change energy storage materials were optimized, the phase transition temperature was 7 ℃,14 ℃ and 22 ℃, respectively, solved the phase stratification phenomenon effectively. The energy storage density, thermal conductivity and undercooling were 102.3 J/g,146.4 J/g,162.5 J/g,0.839 1 W/(m·K),0.984 3 W/(m·K),1.011 5 W/(m·K) and 2.3 ℃,0.5 ℃,0.8 ℃. It was meaningful to improve the service life of Glauber’s salt phase change material.
Key words:  carboxymethyl cellulose sodium    Glauber’s salt    different phase change temperature    phase change energy sto-rage materials    phase stratification
               出版日期:  2018-11-25      发布日期:  2018-12-21
ZTFLH:  TQ12  
  TB34  
基金资助: 青海海西州科技支撑计划项目(174610137100713);青海省国际合作项目(2014-HZ-820)
通讯作者:  铁生年:通信作者,男,教授,主要从事新能源材料的研究 E-mail:tieshengnian@163.com   
作者简介:  李秀丽:女,1992年生,硕士研究生,主要从事新能源材料研究 E-mail:lxlsdqdyjs@163.com
引用本文:    
李秀丽, 铁生年. 速溶高粘羧甲基纤维素钠对不同相变温度梯度芒硝基相变储能材料性能的影响[J]. 材料导报, 2018, 32(22): 3848-3852.
LI Xiuli, TIE Shengnian. Effect of Quick-dissolving and High-viscosity Carboxymethyl Cellulose Sodium on Properties of Glauber’s Salt-based Composites Phase Change Energy Storage Materials with Different Phase Transition Temperature Gradient. Materials Reports, 2018, 32(22): 3848-3852.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.22.003  或          http://www.mater-rep.com/CN/Y2018/V32/I22/3848
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