碳纤维的电纺制备及结构表征

材料导报

2020, Vol. 34

Issue (Z1): 164-168

无机非金属及其复合材料

碳纤维的电纺制备及结构表征

黄青武¹, 吴越², 宋武林¹, 丁雨葵¹

1 华中科技大学分析测试中心,武汉 430074;
2 岛津企业管理(中国)有限公司,上海 200233

Electrospinning Preparation and Structural Characterization of Carbon Fibers

HUANG Qingwu¹, WU Yue², SONG Wulin¹, DING Yukui¹

1 Analytical and Testing Center, Huazhong University of Science and Technology, Wuhan 430074, China;
2 Shimadzu (China) Co. Ltd, Shanghai 200233, China

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摘要采用离子液体1, 3-二甲基咪唑磷酸二甲酯盐[MMIM]⁺[MMP]^-对纤维素进行溶解,并加入电解质得到不同导电性的纺丝液。利用静电纺丝工艺制备碳纤维,并对电纺碳纤维的表面结构、化学状态、热分解及其稳定性、表面形貌、导电特性等进行研究。结果表明,加入电解质能有改善碳纤维的表面化学状态、碳化产率、导电性及尺寸均匀性,最佳的LiCl添加量是1.2wt%,最佳的碳化温度是900 ℃。本研究为高质量碳纤维的大规模电纺制备提供了新的思路。

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关键词: 碳纤维 X射线光电子能谱(XPS) 静电纺丝离子液体纤维素碳化产率

Abstract: Cellulose was dissolved with ionic liquid 1,3-dimethylimidazole dimethyl phosphate [MMIM]⁺[MMP]^-, and added electrolyte to obtain spinning liquid with different conductivity. Carbon fiber was prepared by electrospinning method, and characterized detailedly to study the surface structure, chemical state, thermal decomposition and its stability, surface morphology, and conductivity properties. The results showed that the carbonization yield, conductivity, and dimensional uniformity were effectively improved by adding electrolyte, and the optimum adding amount of LiCl and carbonization temperature were 1.2wt% and 900 ℃, respectively. This study provides new solution to prepare high quality carbon fiber on a large scale by electrospinning method.

Key words: carbon fiber X-ray photoelectron spectroscopy (XPS) electrospinning ionic liquid cellulose carbonization yield

发布日期: 2020-07-01

ZTFLH:

TQ342⁺.742

基金资助: 国家973计划项目(2009CB939700);华中科技大学实验技术研究项目(201946;201757;201444)

作者简介: 黄青武,华中科技大学分析测试中心,工程师,2013年毕业于华中科技大学,获得材料学博士学位。主要从事材料表界面分析,石墨烯基纳米异质结材料的开发及气敏光催化应用。

引用本文:

黄青武, 吴越, 宋武林, 丁雨葵. 碳纤维的电纺制备及结构表征[J]. 材料导报, 2020, 34(Z1): 164-168.
HUANG Qingwu, WU Yue, SONG Wulin, DING Yukui. Electrospinning Preparation and Structural Characterization of Carbon Fibers. Materials Reports, 2020, 34(Z1): 164-168.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2020/V34/IZ1/164

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